Chemistry:Glucose 1,6-bisphosphate

Glucose 1,6-bisphosphate
	File:Glucose 1,6-bisphosphate 2D.svg; α anomer
Names
	IUPAC name 1,6-Di-O-phosphono-D-glucopyranose
	Systematic IUPAC name [(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(phosphonooxymethyl)oxan-2-yl] dihydrogen phosphate
	Other names Glucose 1,6-diphosphate
Identifiers
CAS Number	305-58-8 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:18148 ;
ChemSpider	8580400 unspecified anomer ; 74362 alpha anomer ; 394563 beta anomer ;
KEGG	C01231;
PubChem CID	82400;
	InChI InChI=1S/C6H14O12P2/c7-3-2(1-16-19(10,11)12)17-6(5(9)4(3)8)18-20(13,14)15/h2-9H,1H2,(H2,10,11,12)(H2,13,14,15)/t2-,3-,4+,5-,6-/m1/s1 Key: RWHOZGRAXYWRNX-VFUOTHLCSA-N ;
	SMILES O=P(O)(O)OC[C@H]1O[C@H](OP(=O)(O)O)[C@H](O)[C@@H](O)[C@@H]1O;
Properties
Chemical formula	C6H14O12P2
Molar mass	340.114 g·mol−1
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
	Infobox references

Glucose 1,6-bisphosphate is a derivative of glucose 1-phosphate. In the glycogenesis metabolic pathway, glucose 1,6-bisphosphate is an intermediate in the conversion of glucose 6-phosphate into glucose 1-phosphate by the enzyme glucose-1,6-bisphosphate synthase.^[1] It can be produced by phosphoglucokinase, which converts glucose 1-phosphate into glucose 1,6-bisphosphate.^[2]

References

↑ Ray, W.J.; Peck, E.J. (1972). 12 Phosphomutases. The Enzymes. 6. pp. 407–477. doi:10.1016/S1874-6047(08)60047-5. ISBN 9780121227067.
↑ "The enzymatic synthesis of glucose-1,6-diphosphate". Archives of Biochemistry 23 (1): 55–66. August 1949. PMID 18135764.

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Names
File:Glucose 1,6-bisphosphate 2D.svg α anomer
IUPAC name 1,6-Di-O-phosphono-D-glucopyranose
Systematic IUPAC name [(3R,4S,5S,6R)-3,4,5-trihydroxy-6-(phosphonooxymethyl)oxan-2-yl] dihydrogen phosphate
Other names Glucose 1,6-diphosphate
Identifiers
CAS Number	305-58-8^Y
3D model (JSmol)	Interactive image
ChEBI	CHEBI:18148^Y
ChemSpider	8580400 unspecified anomer^Y 74362 alpha anomer^Y 394563 beta anomer^Y
KEGG	C01231
PubChem CID	82400
InChI InChI=1S/C6H14O12P2/c7-3-2(1-16-19(10,11)12)17-6(5(9)4(3)8)18-20(13,14)15/h2-9H,1H2,(H2,10,11,12)(H2,13,14,15)/t2-,3-,4+,5-,6-/m1/s1^Y Key: RWHOZGRAXYWRNX-VFUOTHLCSA-N^Y
SMILES O=P(O)(O)OC[C@H]1O[C@H](OP(=O)(O)O)[C@H](O)[C@@H](O)[C@@H]1O
Properties
Chemical formula	C₆H₁₄O₁₂P₂
Molar mass	340.114 g·mol⁻¹
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references