Chemistry:Hydrogen assisted magnesiothermic reduction
The hydrogen assisted magnesiothermic reduction ("HAMR") process is a thermochemical process to obtain titanium metal from titanium oxides.[1][2] A technical challenge in the production of titanium metal is the formation of oxide impurities. The Kroll process, which is widely used commercially, addresses this challenge by converting titanium ore (an oxide) into titanium tetrachloride (TiCl4). This intermediate is readily purified. It is reduced to titanium metal with magnesium. This technology is both capital, energy, and carbon-intensive. One advantage of the Kroll process, and several like it, is that it starts with titanium ores (e.g., illmenite), not a purified dioxide.
The HAMR technology also entails a two step process, starting with TiO2 under an atmosphere of hydrogen gas. The product TiH2 can be further processed to titanium metal through standard methods. The reduction of titanium oxides to titanium metal using magnesium does not occur. The novelty of the HAMR process is the inclusion of hydrogen.[3]
References
- ↑ Xia, Yang; Fang, Z. Zak; Zhang, Ying; Lefler, Hyrum; Zhang, Tuoyang; Sun, Pei; Huang, Zhe (2017). "Hydrogen Assisted Magnesiothermic Reduction (HAMR) of Commercial TiO2 to Produce Titanium Powder with Controlled Morphology and Particle Size". Materials Transactions 58 (3): 355–360. doi:10.2320/matertrans.MK201628.
- ↑ Xia, Yang; Lefler, Hyrum D.; Zhang, Ying; Sun, Pei; Fang, Zhigang Zak (2020). "Hydrogen Assisted Magnesiothermic Reduction (HAMR) of TiO2 to Produce Titanium Metal Powder". Extractive Metallurgy of Titanium. pp. 165–179. doi:10.1016/b978-0-12-817200-1.00009-0. ISBN 9780128172001.
- ↑ "asx.com.au, "TAO TO EXPLORE COMMERCIALIZATION OF LOW-CARBON, LOW-COST TITANIUM METAL POWDER IN THE USA"". https://cdn-api.markitdigital.com/apiman-gateway/ASX/asx-research/1.0/file/2924-02341038-6A1020211?access_token=83ff96335c2d45a094df02a206a39ff4.
- "HAMR Process for Titanium Production Powder Research Lab - Department of Metallurgical Engineering - The University of Utah". https://powder.metallurgy.utah.edu/research/hamr.php.
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