Chemistry:Lutetium–yttrium oxyorthosilicate

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Lutetium–yttrium oxyorthosilicate
Identifiers
Properties
Lu2(1-x)Y2xSiO5
Density Between 4.44 g/cm3 [1] and 7.4 g/cm3,[2] depending on Y/Lu ratio
Melting point 2,047 °C (3,717 °F; 2,320 K)
1.82
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Lutetium–yttrium oxyorthosilicate, also known as LYSO, is an inorganic chemical compound with main use as a scintillator crystal for gamma radiation detection.[3] Its chemical formula is Lu2(1-x)Y2xSiO5. The percentage of yttrium varies considerably, with values in the literature ranging from 5% to 70%.[4] It is commonly used to build screens and electromagnetic calorimeters in particle physics. LYSO crystals have the advantages of high light output and density, quick decay time, excellent energy resolution.[5] The crystals are often grown in boules using the Czochralski process, and cutting or polishing can be challenging because LYSO is brittle and hard.[6]

Density (g/cm3) 4.44 to 7.4
Effective Atomic Number 66
Radiation length (cm) 1.14
Decay Constant (ns) 40-44
Peak Emission (nm) 428
Light Yield (Relative BGO=100%) 190
Index of Refraction 1.82
Peak excitation (nm) 375
Radiation Hardness (rad) >106
Melting Point (°C) 2050
Hardness (Mohs) 5.8

References

  1. "Yttrium Orthosilicate - Y2SiO5 | Scientific Materials | YSO LASER Materials". https://www.scientificmaterials.com/products/yso_Y2SiO5_yttrium-orthosilicate.php. 
  2. Daghighian, F.; Shenderov, P.; Pentlow, K.S.; Graham, M.C.; Eshaghian, B.; Melcher, C.L.; Schweitzer, J.S. (August 1993). "Evaluation of cerium doped lutetium oxyorthosilicate (LSO) scintillation crystals for PET" (in en-US). IEEE Transactions on Nuclear Science 40 (4): 1045–1047. doi:10.1109/23.256710. Bibcode1993ITNS...40.1045D. https://www.desy.de/~garutti/LECTURES/BioMedical/JournalClub/LSOcrystals.pdf. Retrieved 18 November 2022. 
  3. Lowdon, Matthew; Martin, Peter G.; Hubbard, M.W.J.; Taggart, M.P.; Connor, Dean T.; Verbelen, Yannick; Sellins, P.J.; Scott, Thomas B. (2019). "Evaluation of Scintillator Detection Materials for Application within Airborne Environmental Radiation Monitoring". Sensors 18 (8): 13. doi:10.3390/s19183828. PMID 31487922. Bibcode2019Senso..19.3828L. 
  4. Radiation Detection and Measurement, p. 249, at Google Books
  5. Chen, Jianming; Mao, Rihua; Zhang, Liyuan; Zhu, Ren-Yuan (2007). "Large Size LSO and LYSO Crystals for Future High Energy Physics Experiments". IEEE Transactions on Nuclear Science 4 (3): 718–724. doi:10.1109/TNS.2007.897823. Bibcode2007ITNS...54..718C. https://authors.library.caltech.edu/8520/1/CHEieeetns07b.pdf. 
  6. Shang, Xi; Xie, Qiangqiang; Xie, Siwei; Yu, Xin; Xu, Jianfeng; Peng, Qiyu (2021). "A Novel Portable Gamma Radiation Sensor Based on a Monolithic Lutetium-Yttrium Oxyorthosilicate Ring". Sensors 21 (10): 16. doi:10.3390/s21103376. PMID 34066224. Bibcode2021Senso..21.3376Z.