Chemistry:Lutetium acetylacetonate
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| File:Tris(acetylacetonato)lutetium.png | |
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3D model (JSmol)
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| Properties | |
| C15H21LuO6 | |
| Molar mass | 472.294 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Lutetium acetylacetonate is a coordination compound with the chemical formula Lu(C5H7O2)3, or Lu(acac)3 for short. It is isomorphic to ytterbium acetylacetonate.[1] It can be prepared by the reaction of trialkoxylutetium and acetylacetone.[2]
Its dihydrate and 1,10-phenanthroline (phen) or 2,2'-bipyridine (dipy) are refluxed in ethanol solution to obtain mixed ligand complexes Lu(acac)3(phen) and Lu(acac)3(dipy).[3]
References
- ↑ Trembovetskii, G. V.; Martynenko, L. I.; Murav'eva, I. A.; Spitsyn, V. I. Synthesis and study of volatile rare earth acetylacetonates(in Russian). Doklady Akademii Nauk SSSR, 1984. 277 (6): 1411-1414. ISSN 0002-3264.
- ↑ Gavrilenko, V. V.; Chekulaeva, L. A.; Savitskaya, I. A.; Garbuzova, I. A. Synthesis of yttrium, lanthanum, neodymium, praseodymium and lutetium alkoxides and acetylacetonates(in Russian). Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992. 11: 2490-2493. ISSN 1026-3500.
- ↑ Andrey Yu. Rogachev, Andrey V. Mironov, Sergey I. Troyanov, Natalia P. Kuzmina, Alexander V. Nemukhin (May 2006). "Synthesis, crystal structures and theoretical study of mixed ligand complexes of lanthanides acetylacetonates with o-phenanthroline and 2,2′-dipyridyl: The unexpected inverted electrostatic trend in stability" (in en). Journal of Molecular Structure 789 (1–3): 187–194. doi:10.1016/j.molstruc.2005.12.026. https://linkinghub.elsevier.com/retrieve/pii/S0022286006000391. Retrieved 2021-09-20.
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