Chemistry:Marialite
| Marialite | |
|---|---|
 | |
| General | |
| Category | Tectosilicate |
| Formula (repeating unit) | Na 4Al 3Si 9O 24Cl |
| Strunz classification | 9.FB.15 |
| Crystal system | Tetragonal |
| Crystal class | Dipyramidal (4/m) (same H-M symbol) |
| Space group | I4/m |
| Unit cell | a = 12.06 Å, c = 7.572(3) Å; Z = 2 |
| Identification | |
| Color | Colorless, white, grey; pink, violet, blue, yellow, brown, orange-brown, pale green or reddish |
| Crystal habit | Typically flat, pyramidal striated crystals; massive, granular |
| Cleavage | Distinct on {100} and {110} |
| Fracture | Uneven to conchoidal |
| Tenacity | Brittle |
| Mohs scale hardness | 5 1⁄2–6 |
| |re|er}} | Vitreous, pearly, resinous |
| Streak | White |
| Diaphaneity | Transparent to opaque |
| Specific gravity | 2.55–2.74 |
| Density | 2.5–2.62 g/cm3 |
| Optical properties | Uniaxial (−) |
| Refractive index | nω = 1.539–1.550 nε = 1.532–1.541 |
| Birefringence | δ = 0.007 – 0.009 |
| References | [1][2][3][4][5] |
Marialite is a silicate mineral with a chemical formula of Na
4Al
3Si
9O
24Cl[4][5] if a pure endmember or Na
4(AlSi
3O
8)
3(Cl
2,CO
3,SO
4) with increasing meionite content.[2] Marialite is a member of the scapolite group and a solid solution exists between marialite and meionite, the calcium endmember.[2] It is a rare mineral usually used as a collector's stone.
Crystallography
Marialite has tetragonal crystallography and a 4/m crystal class. It has a 4 fold rotation with 90° mirror planes. Crystals are usually prismatic with prominent forms of prisms and dipyramids.[7]
Marialite belongs to a uniaxial negative optical class which means it has one circular section and a principal section shaped like an oblate sphenoid.
Discovery and occurrence
Marialite was first described in 1866 for an occurrence in the Phlegrean Volcanic complex, Campania, Italy. It was named by German mineralogist Gerhard vom Rath for his wife, Maria Rosa vom Rath.[3][4]
Marialite occurs in regional and contact metamorphism: marble, calcareous gneiss, granulite and greenschist. It also occurs in skarn, pegmatite and hydrothermally altered volcanic rocks.[3][4] This means that Marialite is formed in high pressure and/or high temperature environments.
References
- ↑ Mineralienatlas
- ↑ 2.0 2.1 2.2 Klein, C., and Dutrow, B. (2007) The 23rd Edition of the Manual of Mineral Science, 675 p. John Wiley and Sons, Inc. Hoboken, New Jersey, U.S.A.
- ↑ 3.0 3.1 3.2 Handbook of Mineralogy
- ↑ 4.0 4.1 4.2 4.3 Mindat.org
- ↑ 5.0 5.1 Webmineral data
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Johnsen, O. (2000) Photographic Guide to Minerals of the World. 439 p. Oxford University Press, Great Clarendon Street, Oxford
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