Chemistry:Mosquito coil

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Short description: Incense coil designed to repel mosquitoes
Mosquito coil
Mosquito coil

A mosquito coil is a mosquito-repelling incense, usually made into a spiral, and typically made using dried paste of pyrethrum powder. The coil is usually held at the center of the spiral, suspending it in the air, or wedged by two pieces of fireproof netting to allow continuous smoldering. Burning usually begins at the outer end of the spiral and progresses slowly toward the center of the spiral, producing a mosquito-repellent smoke.[1] A typical mosquito coil measures around 15 centimetres (6 in) in diameter and lasts around seven to twelve hours. Mosquito coils are widely used in Asia, Africa, South America, Canada, Mexico and Australia.[2]

Invention

Pyrethrum was used for centuries as an insecticide in Persia and Europe,[3] being developed into a mosquito coil in the late 1800s by a Japanese couple: Yuki and Eiichiro Ueyama (ja). At that time in Japan, pyrethrum powder was mixed with sawdust and burned to repel mosquitoes. Ueyama initially created incense sticks mixed from starch powder, dried mandarin orange skin powder, and pyrethrum powder, burning in around 40 minutes. In 1895, Yuki proposed making the sticks thicker and longer, and curling them in spirals, in order to make them last longer. In 1902, after a series of trials and errors, Eiichiro achieved an incense burning effect with a spiral shape. The method included cutting thick incense bars to a set length and manually winding them into a spiral. This method was used until 1957, when mass production was made possible through machine punching.[4][5] After the Second World War, his company, Dainihon Jochugiku Co. Ltd, established joint-venture firms in various countries, including China and Thailand, to produce mosquito-repelling products based on local conditions.[5]

Ingredients

Active ingredients found in mosquito coils may include:[6]

  • Pyrethrum: a natural, powdered material from a kind of chrysanthemum plant.
  • Pyrethrins: an extract of the insecticidal chemicals in pyrethrum.
  • Allethrin: sometimes d-trans-allethrin, the first synthetic pyrethroid.
  • Esbiothrin: a form of allethrin.
  • Dimefluthrin: a novel fluorinated pyrethroid pesticide.
  • Meperfluthrin: a fluorinated pyrethroid ester[7]
  • Metofluthrin: a fluorinated pyrethroid insecticide which is highly effective against mosquitoes. Also used in most mosquito repellants like candles, patches and mini fans.
  • Butylated hydroxytoluene (BHT): an optional additive used to prevent pyrethroid from oxidizing during burning.
  • Piperonyl butoxide (PBO): an optional additive to improve the effectiveness of pyrethroid.
  • N-Octyl bicycloheptene dicarboximide (MGK 264): an optional additive to improve the effectiveness of a pyrethroid.

Disadvantages

Mosquito coils can be fire hazards. Their use has resulted in numerous accidental fires. In 1999, a fire in a South Korean three-story dormitory caused the death of 23 people when a mosquito coil was left unattended.[8]

The strong smell from the smoke may also linger, permeating fabric and furniture.

The health risk of mosquito coils are still being researched with some studies highlighting connections with lung cancer and exposure to mosquito coil smoke.[9][10][11] Coils sold in China and Malaysia were found to produce as much smoke PM2.5 as 75–137 burning cigarettes and formaldehyde emission levels in line with 51 burning cigarettes.[2] Other studies in rats conclude that mosquito coils are not a significant health risk, although some organisms may experience temporary sensory irritation like that caused by smoke from the combustion of organic materials such as logs. In one study, rats were directly exposed to a coil's smoke for six hours a day, five days a week for thirteen weeks. They showed signs of sensory irritation from the high smoke concentration, but there were no adverse effects on other parts of the body. The study concluded that, with normal use, mosquito coils are unlikely to be a health risk.[12]

See also

References

  1. ↑ McKean, Erin, ed (2005). "Mosquito Coil". The New Oxford American Dictionary. Oxford University Press. pp. 1105. 
  2. ↑ 2.0 2.1 Liu, Weili; Zhang, Junfeng; Hashim, Jamal H.; Jalaludin, Juliana; Hashim, Zailina; Goldstein, Bernard D. (September 2003). "Mosquito Coil Emissions and Health Implications". Environmental Health Perspectives 111 (12): 1454–1460. doi:10.1289/ehp.6286. PMID 12948883. 
  3. ↑ "Aromatica: History of pyrethrum". Bioaromatica Ltd. http://www.aromatica.hr/eng/page.asp?id=buhac&sub=buhac3. 
  4. ↑ Debboun, Mustapha; Frances, Stephen P.; Strickman, Daniel (2007). Insect repellents: principles, methods, and uses. Boca Raton: CRC Press. pp. 6. ISBN 978-0-8493-7196-7. https://archive.org/details/insectrepellents00debb. 
  5. ↑ 5.0 5.1 International Business Organization of Osaka, Inc (2004). "Great People of Osaka: Eiichiro Ueyama - Developing and promoting insecticide together with pyrethrum". Osaka Business Update 4. http://www.ibo.or.jp/en/2004_4/ud03.html. Retrieved 31 October 2009. 
  6. ↑ Strickman, Daniel; Frances, Stephen P.; Debboun, Mustapha (2009). Prevention of Bug Bites, Stings, and Disease. New York: Oxford University Press. pp. 117. ISBN 978-0-19-536577-1. https://archive.org/details/preventionbugbit00stri. 
  7. ↑ "IUPAC: global availability of information on agrochemicals : meperfluthrin". University of Hertfordshire. http://sitem.herts.ac.uk/aeru/iupac/Reports/2918.htm. 
  8. ↑ Trumbull, Charles P., ed (2000). "Disasters". Britannica Book of the Year. 2000. Encyclopædia Britannica, Inc. pp. 161. 
  9. ↑ Shu-Chen, Chen; Ruey-Hong, Wong; Li-Jie, Shiu; Ming-Chih, Chiou; Huei, Lee (2008). "Exposure to Mosquito Coil Smoke May be a Risk Factor for Lung Cancer in Taiwan". Journal of Epidemiology 18 (1): 19–25. doi:10.2188/jea.18.19. PMID 18305363. PMC 4771599. https://www.jstage.jst.go.jp/article/jea/18/1/18_1_19/_article/-char/ja/. 
  10. ↑ Zhang, Jie; Qi, Hui-Wei; Sun, Yu-Ping; Xie, Hui-Kang; Zhou, Cai-Cun (2015-04-01). "Mosquito coil exposure associated with small cell lung cancer: A report of three cases". Oncology Letters 9 (4): 1667–1671. doi:10.3892/ol.2015.2922. ISSN 1792-1074. PMID 25789020. 
  11. ↑ Tang, Li; Lim, Wei-Yen; Eng, Philip; Leong, Swan Swan; Lim, Tow Keang; Ng, Alan W.K.; Tee, Augustine; Seow, Adeline (2010-09-01). "Lung Cancer in Chinese Women: Evidence for an Interaction between Tobacco Smoking and Exposure to Inhalants in the Indoor Environment" (in en). Environmental Health Perspectives 118 (9): 1257–1260. doi:10.1289/ehp.0901587. ISSN 0091-6765. PMID 20472525. 
  12. ↑ Pauluhn, J; Mohr, U (May 2006). "Mosquito coil smoke inhalation toxicity. Part II: subchronic nose-only inhalation study in rats.". Journal of Applied Toxicology 26 (3): 279–92. doi:10.1002/jat.1139. PMID 16552726. 

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