Chemistry:N-Butylmercuric chloride
From HandWiki
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| Names | |
|---|---|
| IUPAC name
butyl(chloro)mercury
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| Identifiers | |
3D model (JSmol)
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| Abbreviations | BMC |
| ChemSpider | |
| EC Number |
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PubChem CID
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| RTECS number |
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| UNII | |
| UN number | 2810 |
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| Properties | |
| C4H9ClHg | |
| Molar mass | 293.16 g·mol−1 |
| Appearance | Liquid |
| Boiling point | 130 °C (266 °F; 403 K) |
| log P | 2.4411 |
| Hazards | |
| GHS pictograms |   
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| GHS Signal word | Danger |
| H300, H310, H330, H373, H410 | |
| P260, P262, P264, P270, P271, P273, P280, P284, P302+352, P304+340, P320, P321, P330, P361+364Script error: No such module "Preview warning".Category:GHS errors, P391, P403+233, P405, P501 | |
| Lethal dose or concentration (LD, LC): | |
LD50 (median dose)
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73 mg/kg (rat subcutaneous) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
n-Butylmercuric chloride is an organic mercury salt that is used as a catalyst and a precursor to other oganomercuric compounds.[1]
Preparation
n-Butylmercuric chloride is made by reacting n-butylmagnesium bromide with mercury chloride.[1]
It can also be prepared by reacting 1-butene with mercury acetate.[2]
References
- ↑ 1.0 1.1 Ito, Hiroshi; Trinque, Brian; Kasai, Paul (January 22, 2008). "Penultimate effect in radical copolymerization of 2-trifluoromethylacrylates". Journal of Polymer Science Part A: Polymer Chemistry 46 (5): 1559–1565. doi:10.1002/pola.22467. Bibcode: 2008JPoSA..46.1559I. https://onlinelibrary.wiley.com/doi/10.1002/pola.22467.
- ↑ Larock, Richard C.; Brown, Herbert Charles (1970-04-01). "Organoboranes. X. Fast reaction of organoboranes with mercuric acetate. Convenient procedure for the conversion of terminal olefins into alkylmercuric salts via hydroboration-mercuration". Journal of the American Chemical Society 92 (8): 2467–2471. doi:10.1021/ja00711a043. ISSN 0002-7863. https://doi.org/10.1021/ja00711a043.
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