Chemistry:Naphthol Green B

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Naphthol Green B
NaphtholGreenB.svg
Names
IUPAC name
trisodium; iron(3+); 5-nitroso-6-oxidonaphthalene-2-sulfonate
Other names
Acid Green 1; C.I. 10020
Identifiers
3D model (JSmol)
ChEBI
EC Number
  • 243-010-2
UNII
Properties
C30H15FeN3Na3O15S3
Molar mass 878.45 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Naphthol Green B is a coordination complex of iron that is used as a dye.[1] The ligand is a sulfonated derivative of 1-nitroso-2-naphthol.

Structure

Naphthol Green B is the sodium salt of Naphthol Green Y (C.I. 10005). The organic ligands each bind to iron as bidentate ligands through the nitrogen and the anionic phenoxide groups. Three ligands are bound to the iron.[2]

Applications

Its absorption maximum is 714 nm in water.[3] It is water-soluble.

Naphthol Green B is used in histology to stain collagen.[4] Moreover, it is used for polychrome stains with animal tissue. For industry purposes Naphthol Green B is used for staining wool, nylon, paper, anoxidized aluminium and soap.[3]

References

  1. Raue, Roderich; Corbett, John F. (2000). "Ullmann's Encyclopedia of Industrial Chemistry". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a17_383. 
  2. Wang, Xiao; Zhang, Tianyong; Li, Bin; Yang, Qiusheng; Jiang, Shuang (2014). "Efficient Hydroxylation of Aromatic Compounds Catalyzed by an Iron(II) Complex with H2 O2". Applied Organometallic Chemistry 28 (9): 666–672. doi:10.1002/aoc.3178. 
  3. 3.0 3.1 Horobin, RW. und Kiernan, JA. (2002): Conn's Biological Stains: A Handbook of Dyes, Stains and Fluorochromes for Use in Biology and Medicine. BIOS Scientific Publ., 10th edition; ISBN:1-85996-099-5; page 101 and 102
  4. Histological and Histochemical Methods: Theory and Practice, 4th edition, J. A. Kiernan

External links