Chemistry:Nitroapocynin
From HandWiki
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| Names | |
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| Preferred IUPAC name
1-(4-Hydroxy-3-methoxy-5-nitrophenyl)ethan-1-one | |
| Other names
1-(4-hydroxy-3-methoxy-5-nitrophenyl)ethanone
4'-Hydroxy-3'-methoxy-5'-nitroacetophenone Nitroapocynin 5-Nitroapocynin | |
| Identifiers | |
3D model (JSmol)
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PubChem CID
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| Properties | |
| C9H9NO5 | |
| Molar mass | 211.173 g·mol−1 |
| Appearance | Yellow powder |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Nitroapocynin is a mono-nitrated form of apocynin.
Synthesis
Apocynin can be nitrated with sodium nitrate and acidic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate in acetonitrile solvent.[1][2]
References
- ↑ Tajik, H.; Niknam, K.; Parsa, F. (2009). "Using acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate in selective nitration of phenols under mild conditions". Journal of the Iranian Chemical Society 6: 159–164. doi:10.1007/BF03246515.
- ↑ Babu, Sainath; Raghavamenon, Achuthan C.; Fronczek, Frank R.; Uppu, Rao M. (2009). "4-Hydroxy-3-methoxy-5-nitroacetophenone (5-nitroapocynin)". Acta Crystallographica Section E 65 (9): o2292-3. doi:10.1107/S160053680903390X. PMID 21577684.
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