Chemistry:Polyoxymethylene dimethyl ethers

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Polyoxymethylene dimethyl ethers
Polyoxymethylene dimethyl ether.svg
Identifiers
3D model (JSmol)
ChemSpider
Properties
H3CO(CH2O)nCH3
Molar mass Variable
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Polyoxymethylene dimethyl ethers (PODE or DMMn) are a class of chemical compounds with the molecular formula H3CO(CH2O)nCH3 where n is typically about 3 to 8.

PODE can be produced from methylal and formaldehyde or a formaldehyde equivalent such as paraformaldehyde[1] or trioxane.[2]

PODE is used as a diesel fuel additive[3] and as a solvent.

References

  1. Arvidson M., Fakley M.E., Spencer M.S. (1987). "Lithium halide-assisted formation of polyoxymethylene dimethyl ethers from dimethoxymethane and formaldehyde". Journal of Molecular Catalysis 41 (3): 391–393. doi:10.1016/0304-5102(87)80118-9. 
  2. Qi Zhao; Hui Wang; Zhang-feng Qin; Zhi-wei Wu; Jian-bing Wu; Wei-bin Fan; Jian-guo Wang (2011). "Synthesis of polyoxymethylene dimethyl ethers from methanol and trioxymethylene with molecular sieves as catalysts". Journal of Fuel Chemistry and Technology 39 (12): 918–923. doi:10.1016/S1872-5813(12)60003-6. 
  3. Pellegrini, L., Marchionna, M., Patrini, R., and Florio, S. (2013). "Emission Performance of Neat and Blended Polyoxymethylene Dimethyl Ethers in an Old Light-Duty Diesel Car". SAE Technical Paper Series. 1. doi:10.4271/2013-01-1035.