Chemistry:Smelling salts

Short description: Ammonium carbonate used in the past to restore consciousness after fainting

Two capsules of smelling salts from a first-aid kit. A thin inner glass tube contains alcohol and ammonia; the outer layer is cotton and netting. When crushed, the liquid is released into the cotton, while the glass shards are retained inside. The ammonia-soaked cotton is waved in front of the nose for the treatment of fainting.

Smelling salts, also known as ammonia inhalants, spirit of hartshorn or sal volatile, are chemical compounds used as stimulants to restore consciousness after fainting.

Usage

The usual active compound is ammonium carbonate—a colorless-to-white, crystalline solid ((NH₄)₂CO₃). Because most modern solutions are mixed with water, they should properly be called "aromatic spirits of ammonia". Modern solutions may also contain other products to perfume or act in conjunction with the ammonia, such as lavender oil or eucalyptus oil.

Historically, smelling salts have been used on people feeling faint, or who have fainted. They are usually administered by others but may be self-administered.

Smelling salts are often used on athletes (particularly boxers) who have been dazed or knocked unconscious to restore consciousness and mental alertness. Smelling salts are now banned in most boxing competitions.

They are also used as a form of stimulant in athletic competitions (such as powerlifting, strong man, rugby and ice hockey) to "wake up" competitors to perform better. In 2005, Michael Strahan estimated that 70–80% of National Football League players were using smelling salts as stimulants.

History

Flask with smelling salts, used for reviving dental patients after a procedure. French, 18th century.

Smelling salts have been used since Roman times and are mentioned in the writings of Pliny as Hammoniacus sal. Evidence exists of use in the 13th century by alchemists as sal ammoniac. In the 14th-century "The Canon's Yeoman's Tale" one of Chaucer's The Canterbury Tales, an alchemist purports to use sal armonyak. In the 17th century, the distillation of an ammonia solution from shavings of harts' (deer) horns and hooves led to the alternative name for smelling salts as spirit or salt of hartshorn.

They were widely used in Victorian Britain to revive fainting women, and in some areas, constables would carry a container of them for the purpose. During this time, smelling salts were commonly dissolved with perfume in vinegar or alcohol and soaked onto a sponge, which was then carried on the person in a decorative container called a vinaigrette. The sal volatile appears several times in Dickens' novel Nicholas Nickleby.

The use of smelling salts was widely recommended during the Second World War, with all workplaces advised by the British Red Cross and St. John Ambulance to keep smelling salts in their first aid boxes.

Physiological action

Rembrandt's Unconscious Patient (Allegory of Smell) shows a woman using smelling salts to revive a man who has fainted at the hands of a barber-surgeon.

Solid ammonium carbonate and ammonium bicarbonate salts partly dissociate to form NH₃, CO₂ and H₂O vapour as follows:

[math]\ce{ (NH4)2CO3 -> 2 NH3 + CO2 + H2O }[/math]

[math]\ce{ NH4HCO3 -> NH3 + CO2 + H2O }[/math]

The smelling salts release ammonia (NH₃) gas, which triggers an inhalation reflex. It causes the muscles that control breathing to work faster by irritating the mucous membranes of the nose and lungs.

Fainting can be caused by excessive parasympathetic and vagal activity that slows the heart and decreases perfusion of the brain. The sympathetic irritant effect is exploited to counteract these vagal parasympathetic effects and thereby reverse the faint.

Risks

Ammonia gas is toxic in large concentrations for prolonged periods and can be fatal. If a high concentration of ammonia is inhaled too close to the nostril, it might burn the nasal or oral mucosa. The suggested distance is 10–15 centimetres (4–6 in).

The use of ammonia smelling salts to revive people injured during sport is not recommended because it may inhibit or delay a proper and thorough neurological assessment by a healthcare professional, such as after concussions when hospitalization may be advisable, and some governing bodies recommend specifically against it. The irritant nature of smelling salts means that they can exacerbate any pre-existing cervical spine injury by causing reflex withdrawal away from them, although this has been found to be a result of holding the smelling salts closer to the nose than recommended.