Chemistry:Spinochrome D
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| Preferred IUPAC name
2,3,5,6,8-Pentahydroxynaphthalene-1,4-dione | |
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3D model (JSmol)
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| Properties | |
| C10H6O7 | |
| Molar mass | 238.151 g·mol−1 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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| Infobox references | |
Spinochrome D (2,3,5,6,8-pentahydroxy-1,4-naphthoquinone) is an organic compound with formula C10H6O5, formally derived from 1,4-naphthoquinone through the replacement of five hydrogen atoms by hydroxyl (OH) groups.
Spinochrome D occurs naturally as a brownish red pigment in the shell and spines of sea urchins such as the Japanese aka-uni (Pseudocentrotus depressus).[1] It is soluble in diethyl ether and crystallizes as brownish red needles that sublime at 285−295 °C.[1]
The compound gives a yellowish brown solution when treated with sodium hydroxide, a bluish green solution with ferric chloride, and a violet precipitate with lead acetate. It forms a five-fold acetate ester, C10HO2(CH3COO)5, that crystallizes from methanol as yellow needles that melt at 185−186 °C.[1]
See also
- Spinochrome B
- Spinochrome E
References
- ↑ 1.0 1.1 1.2 Chika KURODA and Masae OKAJIMA (1967), Studies on the Derivatives of Naphthoquinones, XVIII. The pigments of sea urchins, XIII. Proc. Japan Acad., volume 43, pages 41--44. Online version accessed on 2010-02-01.
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