Chemistry:Sudoite

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Short description: Mineral of the chlorite group
Sudoite
General
CategoryChlorite group
Formula
(repeating unit)
Mg2Al3(Si3Al)O10)(OH)8
Crystal systemMonoclinic
Identification
ColorWhite to light green
Mohs scale hardness2.5–3.5
|re|er}}pearly, dull
Refractive indexnα = 1.581 à 1.583
nβ = 1.584 à 1.589
nγ = 1.591 à 1.601
Birefringencebiaxial (-) ; δ = 0.010 to 0.018
2V = 64 to 70° (measured)
2V = 68 to 72° (calculated)
References.[1][2]

Sudoite is a mineral from the chlorite group. It was named after Toshio Sudo (1911-2000), professor of mineralogy at the University of Tokyo, in Japan , and a pioneer of clay science.[3] The mineral tosudite also wears his name. It was approved as a valid species by the International Mineralogical Association in 1966.

Caracteristics

Sudoite is a clay mineral with chemical formula defined as Mg2Al3(Si3Al)O10)(OH)8. it has a monoclinic crystal system. Its hardness on the Mohs scale is comprised between 2.5 and 3.5.

Classification

Following the Nickel–Strunz classification, it is contained in the "09.EC.55" group:

Members of the 9.EC.55 group
Mineral Formula Symmetry group Space group
Baileychlore (Zn,Al)3[Fe2Al][Si3AlO10](OH)8 1 or 1 C1 or C1
Borocookeite Li1+3xAl4-x(BSi3)O10(OH,F)8 (x ≤ 0,33) 2/m C2/m
Chamosite (Fe,Mg,Fe)5Al(Si3Al)O10(OH,O)8 2/m C2/m
Clinochlore (Mg,Fe)5Al(Si3Al)O10(OH)8 2/m C2/m
Cookeite LiAl4(Si3Al)O10(OH)8 1, 2 or 2/m C1, C2 or Cc
Donbassite Al2[Al2,33][Si3AlO10](OH)8 2/m C2/m
Franklinfurnaceite Ca(Fe,Al)Mn4Zn2Si2O10(OH)8 2 C2
Glagolevite NaMg6[Si3AlO10](OH,O)8·H2O 1 C1
Gonyerite Mn3[Mn3Fe][(Si,Fe)4O10](OH,O)8 unknown
Nimite (Ni,Mg,Fe)5Al(Si3Al)O10(OH)8 2/m C2/m
Odinite (Fe,Mg,Al,Fe,Ti,Mn)2,5(Si,Al)2O5(OH)4 m Cm
Orthochamosite (Fe,Mg,Fe)5Al(Si3Al)O10(OH,O)8 unknown
Pennantite Mn5Al(Si3Al)O10(OH)8 2/m C2/m
Sudoite Mg2(Al,Fe)3Si3AlO10(OH)8 2/m C2/m

Formation

It has been first discovered in the Knollenberg Keuper formation, in the village of Plochingen, Stuttgart Region (Baden-Württemberg, Germany ).[4] Despite being an unlikely mineral, it has been described in every continent but Antarctica and Oceania. It is found mainly in hydrothermal or high-pressure/low-temperature (HP/LT) metamorphism contexts[5][6][7]

Use

This mineral has been used as gemstone for the production of personal ornaments, beads and pendants, during the Early Ceramic Age (500 BC – 500 AD), in the Lesser Antilles.[8] The precise source of such formation of sudoite allowing to carve artifacts in rather large blocks remain unknown.

References

  1. Sudoite mineral information and data Mindat
  2. Sudoite Mineral Data Webmineral
  3. Kohyama, Norihiko (2000). "In memory of Prof. Toshio Sudo". Clay Science 11 (2): 103–105. doi:10.11362/jcssjclayscience1960.11.103. 
  4. v. Engelhardt, W.; Müller, Germ; Kromer, H. (1962). "Dioktaedrischer Chlorit ("Sudoit") in Sedimenten des Mittleren Keupers von Plochingen (Württ.)". Naturwissenschaften 49 (9): 205–206. doi:10.1007/BF00633957. ISSN 1432-1904. Bibcode1962NW.....49..205V. 
  5. Fransolet, André-Mathieu; Bourguignon, P. (1978). "Di/trioctahedral chlorite in quartz veins from the Ardenne, Belgium". The Canadian Mineralogist 16 (3): 365–373. 
  6. Goffé, Bruno; Michard, André; Kienast, Jean Robert; Le Mer, Olivier (1988). "A case of obduction-related high-pressure, low-temperature metamorphism in upper crustal nappes, Arabian continental margin, Oman: P-T paths and kinematic interpretation". Tectonophysics. The Ophiolites of Man 151 (1): 363–386. doi:10.1016/0040-1951(88)90253-3. ISSN 0040-1951. Bibcode1988Tectp.151..363G. 
  7. Ruiz Cruz, María Dolores; de Galdeano, Carlos Sanz (2005). "Compositional and structural variation of sudoite from the Betic Cordillera (Spain): a TEM/AEM study". Clays and Clay Minerals 53 (6): 639–652. doi:10.1346/CCMN.2005.0530610. Bibcode2005CCM....53..639C. http://openurl.ingenta.com/content/xref?genre=article&issn=0009-8604&volume=53&issue=6&spage=639. Retrieved 2018-10-20. 
  8. Queffelec, Alain; Bellot-Gurlet, Ludovic; Foy, Eddy; Lefrais, Yannick; Fritsch, Emmanuel (2021). "First identification of sudoite in the Caribbean Ceramic Age lapidary craftsmanship". Gems and Gemology 57 (3): 206–226. doi:10.5741/GEMS.57.3.206. 


attribution translated from :fr:Sudoïte