Chemistry:Tetradecanedioic acid
From HandWiki
| |
| Names | |
|---|---|
| Other names
Tetradecane-1,14-dioic acid
| |
| Identifiers | |
3D model (JSmol)
|
|
| ChEBI | |
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| UNII | |
| |
| |
| Properties | |
| C14H26O4 | |
| Molar mass | 258.358 g·mol−1 |
| Density | 1.04 g/cm3 |
| Melting point | 127 °C (261 °F; 400 K) |
| Hazards | |
| GHS pictograms |  
|
| GHS Signal word | Danger |
| HH315Script error: No such module "Preview warning".Category:GHS errors, H318, H319, H335 | |
| P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P280, P302+352, P304+340, P305+351+338, P305+354+338Script error: No such module "Preview warning".Category:GHS errors, P317Script error: No such module "Preview warning".Category:GHS errors, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Tracking categories (test):
Tetradecanedioic acid is an organic compound with the formula (CH
2)
12(CO
2H)
2. It is a colorless solid. As a 14-carbon dicarboxylic acid, it is a potential precursor to polyesters.[1]
The compound is of historic interest in the context of the Leopold Ružička's synthesis of large ring ketones. It was first prepared by hydrolysis of the dinitrile (CH
2)
12(CN)
2, which was in turn obtained from 1,12-dibromododecane.[2] It was subsequently synthesized from dihydroresorcinol (1,3-cyclohexanedione).[3]
References
- ↑ Sullivan, Kevin P.; Werner, Allison Z.; Ramirez, Kelsey J.; Ellis, Lucas D.; Bussard, Jeremy R.; Black, Brenna A.; Brandner, David G.; Bratti, Felicia et al. (2022). "Mixed plastics waste valorization through tandem chemical oxidation and biological funneling". Science 378 (6616): 207–211. doi:10.1126/science.abo4626. PMID 36227984.
- ↑ Chuit, Philippe (1926). "Préparation d'acides polyméthylène-dicarboniques de 11 à 19 atomes de carbone et de quelques-uns de leurs dérivés". Helvetica Chimica Acta 9: 264–278. doi:10.1002/hlca.19260090131.
- ↑ Stetter, Hermann; Dierichs, Wolfgang (1953). "Eine neue Methode zur Darstellung langkettiger Carbonsäuren, V. Mitteil.: Darstellung einiger langkettiger Dicarbonsäuren". Chemische Berichte 86 (6): 693–696. doi:10.1002/cber.19530860606.
 |  |
