Chemistry:Belakovskiite
| Belakovskiite | |
|---|---|
| General | |
| Category | Sulfate mineral |
| Formula (repeating unit) | Na7(UO2)(SO4)4(SO3OH)(H2O)3 |
| Crystal system | Triclinic |
| Crystal class | Pinacoidal (1) (same H-M symbol) |
| Space group | P1 |
| Unit cell | a = 5.46, b = 11.33, c = 18.42 [Å], α = 104.77°, β = 90.09°, γ = 96.77° (approximated); Z = 2 |
| Identification | |
| Color | Yellow-green |
| Crystal habit | fibrous |
| Cleavage | None |
| Tenacity | Brittle |
| Mohs scale hardness | 2 |
| |re|er}} | Vitreous |
| Streak | White |
| Diaphaneity | Transparent |
| Density | 3.31 (calculated); 3.23 (measured) |
| Optical properties | Biaxal (+) |
| Refractive index | nα=1.50, nβ=1.51, nγ=1.52 (approximated) |
| Pleochroism | None |
| 2V angle | 88o (calculated) |
| Other characteristics |  Radioactive |
| References | [1][2][3] |
Belakovskiite is a very rare uranium mineral with the formula Na7(UO2)(SO4)4(SO3OH)(H2O)3.[1][2] It is interesting in being a natural uranyl salt with hydrosulfate anion, a feature shared with meisserite.[5] Other chemically related minerals include fermiite, oppenheimerite, natrozippeite and plášilite.[6][7][8][9] Most of these uranyl sulfate minerals was originally found in the Blue Lizard mine, San Juan County, Utah, US.[10] The mineral is named after Russian mineralogist Dmitry Ilych Belakovskiy.[1]
Association
Belakovskiite is associated with other sulfate minerals: meisserite, blödite, ferrinatrite, kröhnkite, and metavoltine.[1] This association is found as efflorescences on a sandstone associated with uranium mineralization.[3]
Crystal structure
The framework of belakovskiite crystal structure is a hexavalent cluster with composition (UO2)(SO4)4(H2O). Such clusters are connected via Na-O and hydrogen bonds.[1]
References
- ↑ 1.0 1.1 1.2 1.3 1.4 Kampf, A.R., Plášil, J., Kasatkin, A.V., and Marty, J., 2014. Belakovskiite, Na7(UO2)(SO4)4(SO3OH)(H2O)3, a new uranyl sulfate mineral from the Blue Lizard mine, San Juan County, Utah, USA. Mineralogical Magazine 78(3), 639-649
- ↑ 2.0 2.1 "Belakovskiite: Belakovskiite mineral information and data". http://www.mindat.org/min-45960.html. Retrieved 2016-03-10.
- ↑ 3.0 3.1 "Belakovskiite - Handbook of Mineralogy". http://www.handbookofmineralogy.org/pdfs/belakovskiite.pdf. Retrieved 2016-03-10.
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ "Meisserite: Meisserite mineral information and data". http://www.mindat.org/min-43905.html. Retrieved 2016-03-10.
- ↑ "Fermiite: Fermiite mineral information and data". http://www.mindat.org/min-46506.html. Retrieved 2016-03-10.
- ↑ "Oppenheimerite: Oppenheimerite mineral information and data". http://www.mindat.org/min-46514.html. Retrieved 2016-03-10.
- ↑ "Natrozippeite: Natrozippeite mineral information and data". http://www.mindat.org/min-3694.html. Retrieved 2016-03-10.
- ↑ "Plášilite: Plášilite mineral information and data". http://www.mindat.org/min-46145.html. Retrieved 2016-03-10.
- ↑ "Blue Lizard Mine, Chocolate Drop, Red Canyon, White Canyon District, San Juan Co., Utah, USA - Mindat.org". http://www.mindat.org/loc-38665.html. Retrieved 2016-03-10.
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