Chemistry:Cuprite

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Cuprite
CupriteUSGOV.jpg
Cuprite from Morenci, Arizona
General
CategoryOxide mineral
Formula
(repeating unit)
Cu2O
Strunz classification4.AA.10
Dana classification4.1.1.1
Crystal systemCubic
Crystal classHexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space groupPn3m
Unit cella = 4.2685 Å; V = 77.77 Å3; Z = 2
Identification
ColorDark red to conchineal red, sometimes almost black
Crystal habitCubic, octahedral, and dodecahedral crystals; as hairlike capillary forms, earthy, compact granular and massive
TwinningPenetration twins
CleavageFair in four directions forming octahedrons
FractureConchoidal to uneven
TenacityBrittle
Mohs scale hardness3.5 to 4
|re|er}}Adamantine, sub-metallic, earthy
StreakShining metallic brownish-red
DiaphaneityTransparent, translucent
Specific gravity6.14
Optical propertiesIsotropic
Refractive indexn = 2.849
PleochroismVisible
References[1][2][3]

Cuprite is an oxide mineral composed of copper(I) oxide Cu2O, and is a minor ore of copper.[5]

Cuprite from Tsumeb Mine (size:2.3 x 2.1 x 1.2 cm

Its dark crystals with red internal reflections are in the isometric system hexoctahedral class, appearing as cubic, octahedral, or dodecahedral forms, or in combinations. Penetration twins frequently occur. In spite of its nice color, it is rarely used for jewelry because of its low Mohs hardness of 3.5 to 4. It has a relatively high specific gravity of 6.1, imperfect cleavage and is brittle to conchoidal fracture. The luster is sub-metallic to brilliant adamantine. The "chalcotrichite" (from Ancient Greek:, "plush copper ore")[5] variety typically shows greatly elongated (parallel to [001]) capillary or needle like crystals forms.

Chalcotrichite from Ray, Arizona

It is a secondary mineral which forms in the oxidized zone of copper sulfide deposits. It frequently occurs in association with native copper, azurite, chrysocolla, malachite, tenorite and a variety of iron oxide minerals.[6] It is known as ruby copper due to its distinctive red color.

Cuprite was first described by Wilhelm Karl Ritter von Haidinger in 1845 and the name derives from the Latin cuprum for its copper content.[5][2]

Cuprite is found in the Ural Mountains, Altai Mountains, and Sardinia, and in more isolated locations in Cornwall, France , Arizona, Chile , Bolivia, and Namibia.[7]

As a gemstone

Though almost all crystals of cuprite are far too small to yield faceted gemstones, one unique deposit from Onganja in Seeis, Namibia, which was discovered in the 1970s, has produced crystals which were both large and gem quality. Virtually every faceted stone over one carat (0.2 g) in weight is from this single deposit, which has long since been mined out. The number of faceted gems over two carats (0.4 g) is difficult to estimate, but according to Joel Arem, one-time curator for the Smithsonian National Gem and Mineral Collection in Washington, D.C., faceted cuprite of any size is considered one of the most collectible and spectacular gems in existence, with its deep garnet coloring and higher brilliance than a diamond. Only the gem's soft nature prevents it from being among the most valuable jewelry stones.

See also

References

  1. "Cuprite". Mindat. http://www.mindat.org/min-1172.html. Retrieved 2010-07-10. 
  2. 2.0 2.1 "Cuprite". Webmineral data. http://www.webmineral.com/data/Cuprite.shtml. Retrieved 2010-07-10. 
  3. Handbook of Mineralogy
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 5.2 Spencer, Leonard James (1911). "Cuprite". in Chisholm, Hugh. Encyclopædia Britannica. 12 (11th ed.). Cambridge University Press. p. 635. 
  6. Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., Wiley, p. 299-300 ISBN:0-471-80580-7
  7. Joel E. Arem, Ph.D., F.G.A., Color Encyclopedia of Gemstones, 1977, Van Nostrand Reinhold Company