Chemistry:Borate phosphate

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Borate phosphate
Identifiers
3D model (JSmol)
ChemSpider
Properties
BO7P−6
Molar mass 153.78 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Borate phosphates are mixed anion compounds containing separate borate and phosphate anions. They are distinct from the borophosphates where the borate is linked to a phosphate via a common oxygen atom. The borate phosphates have a higher ratio of cations to number of borates and phosphates, as compared to the borophosphates.[1]

There are also organic esters of both borate and phosphate, e.g. NADH-borate.[2]

Production

In the high temperature method, ingredients are heated together at atmospheric pressure. Products are anhydrous, and production or borophosphates is likely.[3]

The boron flux method involves dissolving ingredients such as an ammonium phosphate and metal carbonate in an excess of molten boric acid.[3]

Use

Borate phosphates are of research interest for their optical, electrooptical or magnetic properties.[3]

List

chem mw crystal system space group unit cell Å volume density comment references
Be3(BO3)(PO4) hexagonal SHG [1][4]
α-Mg3[BPO7] orthorhombic Immm a=8·495, b=4·886, c=12·565 Z=4 [5]
Mg3[BPO7] monoclinic Cm [3]
Mg3[BPO7] hexagonal P6_2m [3]
Lüneburgite Mg3[B2(OH)6](PO4)2 · 6H2O triclinic 2.05 Biaxial (-) nα = 1.520 – 1.522 nβ = 1.540 – 1.541 nγ = 1.545 – 1.548

2V 52° to 60°

Max birefringence δ = 0.025 – 0.026

[6][7]
Ca3[BPO7] monoclinic a=8.602 b=4.891 c=12.806 β=102.30 [5]
Seamanite Mn2+3[B(OH)4](PO4)(OH)2 orthorhombic Pbnm a = 7.81 Å, b = 15.11 Å, c = 6.69 Å Z=4 789.48 3.08 Biaxial (+) nα = 1.640 nβ = 1.663 nγ = 1.665

2V 40°

Max birefringence δ = 0.025

[8][9]
Laptevite-(Ce) Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11 trigonal R3m a = 10.804, c = 27.726 Z=3 2802.6 4.61 Uniaxial (-) nω = 1.741 nε = 1.720

Max birefringence δ = 0.021

[10]
(CoPO4)4, B5O6(OH)4N(CH3)4(CH3NH3) 1036.10 orthorhombic I222 a=6.7601 b=7.5422 c=34.822 Z=2 1775.4 1.938 red [11]
Co3[BPO7] monoclinic Cm a=9.774, b=12.688, c=4.9057, β=119.749°; Z=4 528.2 purple [3]
α-Zn3[BPO7] 349.89 orthorhombic a=8.438 b=4.884 c=12.558 [5]
α-Zn3[BPO7] 349.89 monoclinic Cm a=9.725 b=12.720 c=4.874 β=119.80 Z=4 [3][12]
β-Zn3[BPO7] 349.89 hexagonal P-6 a=8.4624 c=13.0690 Z=6 810.51 4.301 colourless [3][13]
α-Sr3[BPO7] orthorhombic a=9.0561, b=9.7984, c=13.9531 [14]
Sr10[(PO4)5.5(BO4)0.5](BO2) P3_ a=9.7973, c=7.3056, Z=1 607.29 [15]
SrCo2(BO3)(PO4) 359.26 monoclinic P21/c a=6.485 b=9.270 c=10.066 β=111.14 Z=4 548.7 4.349 red [1][16]
Byzantievite Ba5(Ca,REE,Y)22(Ti,Nb)18(SiO4)4[(PO4, SiO4)]4(BO3)9O22[(OH),F]43(H2O)1.5 trigonal R3 a = 9.1202, c = 102.145 7,357.9 4.10 Uniaxial (-) nω = 1.940 nε = 1.860

Max birefringence δ = 0.080

16 different layers in structure

[17][18]
Rhabdoborite Mg12(V5+,Mo6+,W6+)1 · 5O6{[BO3]6-x[(P,As)O4]xF2-x} (x < 1) hexagonal P63 a = 10.6314, c = 4.5661 446.95 [19]
CsNa2Y2(BO3)(PO4)2 605.46 orthorhombic Cmcm a=6.9491 b=14.907 c=10.6201 Z=4 1100.2 3.655 colourless [20]
CsNa2Sm2(BO3)(PO4)2 728.34 orthorhombic Cmcm a=7.0631 b=15.288 c=10.725 Z=4 1158.1 4.177 colourless [21]
CsNa2Ho2(BO3)(PO4)2 [22]
CsNa2Er2(BO3)(PO4)2 [22]
CsNa2Tm2(BO3)(PO4)2 [22]
CsNa2Yb2(BO3)(PO4)2 [22]
CsZn4(BO3)(PO4)2 679.30 orthorhombic Pbca a=14.49 b=10.02 c=16.45 Z=8 2388 3.779 colourless [23]
Ba3(BO3)(PO4) hexagonal P63mc a=5.4898, c=14.7551, Z=2 [1][24]
Ba3(BO3)(PO4) monoclinic P2/m a = 11.7947, b = 9.6135, c = 12.9548, β= 111.25° 1369.08 [25]
Ba11B26O44(PO4)2(OH)6 monoclinic P21/c a=6.891, b=13.629, c=25.851, β=90.04° [26]
Ba3(ZnB5O10)PO4 786.41 orthorhombic Pnm21 a = 10.399 b = 7.064 c = 8.204 Z=2 602.6 4.334 [27]
La7O6(BO3)(PO4)2 monoclinic a=7.019 b=17.915 c=12.653 β=97.52 1577.27 [1][28]
Pr7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.8939 b=17.662 c=12.442 β=97.24 Z=4 1502.9 green [1][29]
Nd7O6(BO3)(PO4)2 monoclinic a=6.862 b=17.591 c=12.375 β=97.18 1482.12 [1][28]
Sm7O6(BO3)(PO4)2 monoclinic P121/n1 a=6.778 b=17.396 c=12.218 β=96.96 Z=4 1430.0 yellow [1][29]
Gd7O6(BO3)(PO4)2 monoclinic a=6.704 b=17.299 c=12.100 β=96.94 1393.11 [1][28]
Dy7O6(BO3)(PO4)2 monoclinic a=6.623 b=17.172 c=11.960 β=96.76 1350.84 [1][28]
K3Yb[OB(OH)2]2[HOPO3]2 R3_ a=5.6809, c=36.594 Z=3 1022.8 [1][30]
K3Lu[OB(OH)2]2[HOPO3]2 R3_ a=5.6668, c=36.692 Z=3 1020.4 [1][30]
Pb4O(BO3)(PO4) 998.54 monoclinic P21/c a=10.202 b=7.005 c=12.92 β=113.057 Z=4 849.6 7.807 colourless [31]
LiPb4(BO3)(PO4)2 1084.85 orthorhombic Pbca a=12.613 b=6.551 c=25.63 Z=8 2095 6.875 colourless [1]
Bi4O3(BO3)(PO4) 1037.70 orthorhombic Pbca a=5.536 b=14.10 c=22.62 Z=8 1766 7.807 colourless [31]
Th2[BO4][PO4] monoclinic P21/c a=8.4665, b=7.9552, c=8.2297, β= 103.746° Z = 4 [32]
Ba5[(UO2)(PO4)3(B5O9)]·nH2O interlocking nanotubes; absorbs water from air [33]
U2[BO4][PO4] 645.84 monoclinic P21/c a = 8.546, b = 7.753, c = 8.163 β = 102.52° Z=4 528.0 8.12 generated at 12.5 GPa + 1000 °C; emerald green [34]
[Sr8(PO4)2][(UO2)(PO4)2(B5O9)2] 1746.97 monoclinic P21/n a = 6.5014, b =22.4302, c =9.7964 β = 90.241° Z=2 1428.57 4.061 orange [35]

References

  1. ↑ 1.00 1.01 1.02 1.03 1.04 1.05 1.06 1.07 1.08 1.09 1.10 1.11 1.12 Huang, Shengshi; Yu, Hongwei; Han, Jian; Pan, Shilie; Jing, Qun; Wang, Ying; Dong, Lingyun; Wu, Hongping et al. (August 2014). "The Effect of the Ratio of [M/(B+P) on the Configuration of Anionic Groups: Synthesis of the Borate-Phosphate LiPb 4 (BO 3 )(PO 4 ) 2"] (in en). European Journal of Inorganic Chemistry 2014 (22): 3467–3473. doi:10.1002/ejic.201402389. http://doi.wiley.com/10.1002/ejic.201402389. 
  2. ↑ Kim, Danny H.; Marbois, Beth N.; Faull, Kym F.; Eckhert, Curtis D. (June 2003). "Esterification of borate with NAD+ and NADH as studied by electrospray ionization mass spectrometry and11B NMR spectroscopy". Journal of Mass Spectrometry 38 (6): 632–640. doi:10.1002/jms.476. PMID 12827632. Bibcode: 2003JMSp...38..632K. 
  3. ↑ 3.0 3.1 3.2 3.3 3.4 3.5 3.6 3.7 Yilmaz, Aysen; Bu, Xianhui; Kizilyalli, Meral; Kniep, Rudiger; Stucky, Galen D. (February 2001). "Cobalt Borate Phosphate, Co3[BPO7, Synthesis and Characterization"] (in en). Journal of Solid State Chemistry 156 (2): 281–285. doi:10.1006/jssc.2000.8963. Bibcode: 2001JSSCh.156..281Y. https://linkinghub.elsevier.com/retrieve/pii/S0022459600989631. 
  4. ↑ He, Zhangzhen; Moriyama, Hiroshi (2003). "A Model of New VUV NLO Materials Based on Borate: A Novel Noncentrosymmetric Borophosphate Compound Be 3 BPO 7" (in en). MRS Proceedings 788: L8.23. doi:10.1557/PROC-788-L8.23. ISSN 0272-9172. http://link.springer.com/10.1557/PROC-788-L8.23. 
  5. ↑ 5.0 5.1 5.2 Gözel, G.; Baykal, A.; Kizilyalli, M.; Kniep, R. (December 1998). "Solid-State Synthesis, X-ray Powder Investigation and IR Study of α-Mg3[BPO7"] (in en). Journal of the European Ceramic Society 18 (14): 2241–2246. doi:10.1016/S0955-2219(98)00152-6. https://linkinghub.elsevier.com/retrieve/pii/S0955221998001526. 
  6. ↑ "Lüneburgite". https://www.mindat.org/min-2458.html. 
  7. ↑ Korybska-Sadło, Iwona; Sitarz, Maciej; Król, Magdalena; Gunia, Piotr (2016-10-20). "Vibrational spectroscopic characterization of the magnesium borate-phosphate mineral lüneburgite" (in en). Spectroscopy Letters 49 (9): 606–612. doi:10.1080/00387010.2016.1236819. ISSN 0038-7010. Bibcode: 2016SpecL..49..606K. https://www.tandfonline.com/doi/full/10.1080/00387010.2016.1236819. 
  8. ↑ "Seamanite". https://www.mindat.org/min-3599.html. 
  9. ↑ Ewald, Bastian; Huang, Ya-Xi; Kniep, Rüdiger (August 2007). "Structural Chemistry of Borophosphates, Metalloborophosphates, and Related Compounds" (in de). Zeitschrift für anorganische und allgemeine Chemie 633 (10): 1517–1540. doi:10.1002/zaac.200700232. http://doi.wiley.com/10.1002/zaac.200700232. 
  10. ↑ "Laptevite-(Ce)". https://www.mindat.org/min-42866.html. 
  11. ↑ Lin, Zhuojia; Wragg, David S.; Lightfoot, Philip; Morris, Russell E. (2009). "A novel non-centrosymmetric metallophosphate-borate compound via ionothermal synthesis" (in en). Dalton Transactions (27): 5287–9. doi:10.1039/b904450g. ISSN 1477-9226. PMID 19565080. http://xlink.rsc.org/?DOI=b904450g. 
  12. ↑ Bluhm, K.; Park, C. H. (1997-01-01). "Die Synthese und Kristallstruktur des Borat-Phosphats: α -Zn3(BO3)(PO4) / Synthesis and Crystal Structure of the Borate-Phosphate: α-Zn3(BO3)( PO4)". Zeitschrift für Naturforschung B 52 (1): 102–106. doi:10.1515/znb-1997-0120. ISSN 1865-7117. https://www.degruyter.com/document/doi/10.1515/znb-1997-0120/html. 
  13. ↑ Zhang, Erpan; Zhao, Sangen; Zhang, Jianxiu; Fu, Peizhen; Yao, Jiyong (2011-01-15). "The β-modification of trizinc borate phosphate, Zn 3 (BO 3 )(PO 4 )". Acta Crystallographica Section E 67 (1): i3. doi:10.1107/S1600536810051871. ISSN 1600-5368. PMID 21522511. PMC 3050272. Bibcode: 2011AcCrE..67I...3Z. http://scripts.iucr.org/cgi-bin/paper?S1600536810051871. 
  14. ↑ Tekin, Berna (August 2007). "Bazi Metal İçeren Boratli, Fosfatli ve Borfosfatli Bi̇leşi̇kleri̇n Sentezi̇ ve Yapisal Karakteri̇zasyonu". http://dspace.balikesir.edu.tr/xmlui/bitstream/handle/20.500.12462/1562/Berna_Tekin.pdf?sequence=1&isAllowed=y. 
  15. ↑ Chen, Shuang; Hoffmann, Stefan; Carrillo-Cabrera, Wilder; Akselrud, Lev G.; Prots, Yurii; Schwarz, Ulrich; Zhao, Jing-Tai; Kniep, Rüdiger (March 2010). "Sr10[(PO4)5.5(BO4)0.5(BO2): Growth and crystal structure of a strontium phosphate orthoborate metaborate closely related to the apatite-type crystal structure"] (in en). Journal of Solid State Chemistry 183 (3): 658–661. doi:10.1016/j.jssc.2009.12.026. Bibcode: 2010JSSCh.183..658C. https://linkinghub.elsevier.com/retrieve/pii/S0022459609005982. 
  16. ↑ Gou, Wenbin; He, Zhangzhen; Yang, Ming; Zhang, Weilong; Cheng, Wendan (2013-03-04). "Synthesis and Magnetic Properties of a New Borophosphate SrCo 2 BPO 7 with a Four-Column Ribbon Structure" (in en). Inorganic Chemistry 52 (5): 2492–2496. doi:10.1021/ic3023979. ISSN 0020-1669. PMID 23406089. https://pubs.acs.org/doi/10.1021/ic3023979. 
  17. ↑ "Byzantievite". https://www.mindat.org/min-37645.html. 
  18. ↑ Sokolova, E.; Hawthorne, F. C.; Pautov, L. A.; Agakhanov, A. A. (April 2010). "Byzantievite, Ba 5 (Ca, REE ,Y) 22 (Ti,Nb) 18 (SiO 4 ) 4 [(PO 4 ),(SiO 4 ) 4 (BO 3 ) 9 O 21 [(OH),F] 43 (H 2 O) 1.5 : the crystal structure and crystal chemistry of the only known mineral with the oxyanions (BO 3 ), (SiO 4 ) and (PO 4 )"] (in en). Mineralogical Magazine 74 (2): 285–308. doi:10.1180/minmag.2010.074.2.285. ISSN 0026-461X. Bibcode: 2010MinM...74..285S. https://www.cambridge.org/core/product/identifier/S0026461X00055985/type/journal_article. 
  19. ↑ "Rhabdoborite-(V)". https://www.mindat.org/min-52886.html. 
  20. ↑ Zhao, Dan; Xue, Yali; Zhang, Ruijuan; Fan, Yanping; Liu, Baozhong; Li, Yanan; Zhang, Shirui (2020). "Design, synthesis, crystal structure and luminescent properties introduced by Eu 3+ of a new type of rare-earth borophosphate CsNa 2 REE 2 (BO 3 )(PO 4 ) 2 (REE = Y, Gd)" (in en). Dalton Transactions 49 (29): 10104–10113. doi:10.1039/D0DT00389A. ISSN 1477-9226. PMID 32662492. http://xlink.rsc.org/?DOI=D0DT00389A. 
  21. ↑ Zhao, Dan; Shi, Lin-Ying; Zhang, Rui-Juan; Xue, Ya-Li (2020-12-01). "Synthesis, crystal structure and luminescence properties of a new samarium borate phosphate, CsNa 2 Sm 2 (BO 3 )(PO 4 ) 2". Acta Crystallographica Section C: Structural Chemistry 76 (12): 1068–1075. doi:10.1107/S2053229620014576. ISSN 2053-2296. PMID 33273144. https://scripts.iucr.org/cgi-bin/paper?S2053229620014576. 
  22. ↑ 22.0 22.1 22.2 22.3 Zhao, Dan; Xue, Ya-Li; Fan, Yun-Chang; Zhang, Rui-Juan; Zhang, Shi-Rui (June 2021). "A new series of rare-earth borate-phosphate family CsNa2Ln2(BO3)(PO4)2 (Ln = Ho, Er, Tm, Yb): Tunnel structure, upconversion luminescence and optical thermometry properties" (in en). Journal of Alloys and Compounds 866: 158801. doi:10.1016/j.jallcom.2021.158801. https://linkinghub.elsevier.com/retrieve/pii/S0925838821002085. 
  23. ↑ Guo, Fengjiao; Hu, Cong; Wang, Ying; Han, Jian; Yang, Zhihua; Pan, Shilie (2018). "Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 chains and two new phosphates"] (in en). Inorganic Chemistry Frontiers 5 (2): 327–334. doi:10.1039/C7QI00548B. ISSN 2052-1553. http://xlink.rsc.org/?DOI=C7QI00548B. 
  24. ↑ Ma, H.W.; Liang, J.K.; Wu, L.; Liu, G.Y.; Rao, G.H.; Chen, X.L. (October 2004). "Ab initio structure determination of new compound Ba3(BO3)(PO4)" (in en). Journal of Solid State Chemistry 177 (10): 3454–3459. doi:10.1016/j.jssc.2003.12.027. Bibcode: 2004JSSCh.177.3454M. https://linkinghub.elsevier.com/retrieve/pii/S0022459603006777. 
  25. ↑ Gözel, Güller (1993). "Preparation and structural investigation of alkaline-earth metal borophosphates – Tez Arşivi". https://tezarsivi.com/preparation-and-structural-investigation-of-alkaline-earth-metal-borophosphates. 
  26. ↑ Heyward, Carla; McMillen, Colin D.; Kolis, Joseph (July 2013). "Hydrothermal synthesis and structural analysis of new mixed oxyanion borates: Ba11B26O44(PO4)2(OH)6, Li9BaB15O27(CO3) and Ba3Si2B6O16" (in en). Journal of Solid State Chemistry 203: 166–173. doi:10.1016/j.jssc.2013.04.022. Bibcode: 2013JSSCh.203..166H. https://linkinghub.elsevier.com/retrieve/pii/S0022459613002168. 
  27. ↑ Yu, Hongwei; Zhang, Weiguo; Young, Joshua; Rondinelli, James M.; Halasyamani, P. Shiv (December 2015). "Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba 3 (ZnB 5 O 10 )PO 4" (in en). Advanced Materials 27 (45): 7380–7385. doi:10.1002/adma.201503951. PMID 26459262. Bibcode: 2015AdM....27.7380Y. http://doi.wiley.com/10.1002/adma.201503951. 
  28. ↑ 28.0 28.1 28.2 28.3 Shi, Ying; Liang, Jingkui; Zhang, Hao; Yang, Jinling; Zhuang, Weidong; Rao, Guanghui (February 1997). "X-Ray Powder Diffraction and Vibrational Spectra Studies of Rare Earth Borophosphates,Ln7O6(BO3)(PO4)2(Ln=La, Nd, Gd, and Dy)" (in en). Journal of Solid State Chemistry 129 (1): 45–52. doi:10.1006/jssc.1996.7227. Bibcode: 1997JSSCh.129...45S. https://linkinghub.elsevier.com/retrieve/pii/S0022459696972278. 
  29. ↑ 29.0 29.1 Ewald, B.; Prots, Yu.; Kniep, R. (April 2004). "Refinement of the crystal structures of praseodymium- and samariumoxoborate- bis(oxophosphate)-oxide, Ln7O6[BO3][PO4]2, (Ln = Pr, Sm)". Zeitschrift für Kristallographie – New Crystal Structures 219 (1–4): 233–235. doi:10.1524/ncrs.2004.219.14.233. ISSN 2197-4578. 
  30. ↑ 30.0 30.1 Zhou, Yan; Hoffmann, Stefan; Huang, Ya-Xi; Prots, Yurii; Schnelle, Walter; Menezes, Prashanth W.; Carrillo-Cabrera, Wilder; Sichelschmidt, Jörg et al. (June 2011). "K3Ln[OB(OH)22[HOPO3]2 (Ln=Yb, Lu): Layered rare-earth dihydrogen borate monohydrogen phosphates"] (in en). Journal of Solid State Chemistry 184 (6): 1517–1522. doi:10.1016/j.jssc.2011.04.023. Bibcode: 2011JSSCh.184.1517Z. https://linkinghub.elsevier.com/retrieve/pii/S0022459611001915. 
  31. ↑ 31.0 31.1 Wang, Ying; Pan, Shilie; Huang, Shengshi; Dong, Lingyun; Zhang, Min; Han, Shujuan; Wang, Xian (2014). "Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )" (in en). Dalton Trans. 43 (34): 12886–12893. doi:10.1039/C4DT01199F. ISSN 1477-9226. PMID 25020047. http://xlink.rsc.org/?DOI=C4DT01199F. 
  32. ↑ Lipp, C.; Burns, P. C. (2011-10-01). "Th2[BO4[PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE"] (in en). The Canadian Mineralogist 49 (5): 1211–1220. doi:10.3749/canmin.49.5.1211. ISSN 0008-4476. Bibcode: 2011CaMin..49.1211L. http://www.canmin.org/cgi/doi/10.3749/canmin.49.5.1211. 
  33. ↑ Wu, Shijun; Wang, Shuao; Diwu, Juan; Depmeier, Wulf; Malcherek, Thomas; Alekseev, Evgeny V.; Albrecht-Schmitt, Thomas E. (2012). "Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate" (in en). Chemical Communications 48 (29): 3479–81. doi:10.1039/c2cc17517g. ISSN 1359-7345. PMID 22267020. http://xlink.rsc.org/?DOI=c2cc17517g. 
  34. ↑ Hinteregger, Ernst; Wurst, Klaus; Perfler, Lukas; Kraus, Florian; Huppertz, Hubert (2013-10-14). "High-Pressure Synthesis and Characterization of the Actinide Borate Phosphate U 2 [BO 4 [PO 4 ]: High-Pressure Synthesis and Characterization of U 2 [BO 4 ][PO 4 ]"] (in en). European Journal of Inorganic Chemistry 2013 (30): 5247–5252. doi:10.1002/ejic.201300662. PMID 24611029. 
  35. ↑ Hao, Yucheng (2017). "New Insight into the Crystal Chemistry of Uranium and Thorium Borates, Borophosphates and Borate-phosphates". p. 109. https://d-nb.info/1169830692/34. 



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