Chemistry:Chimyl alcohol
From HandWiki
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| IUPAC name
3-hexadecoxypropane-1,2-diol
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| Other names
chimylic alcohol, 1-O-hexadecyl glycerol
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3D model (JSmol)
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PubChem CID
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| Properties | |
| C19H40O3 | |
| Molar mass | 316.526 g·mol−1 |
| Appearance | colorless solid |
| Melting point | 62.5–63.5 °C (144.5–146.3 °F; 335.6–336.6 K) |
| Boiling point | 445 °C (833 °F; 718 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Chimyl alcohol is an organic compound with the formula HOCH
2CH(OH)CH
2OC
16H
33. It is a colorless solid. Chimyl alcohol is a monoether formed by condensation of cetyl alcohol with one of the two primary alcohol sites of glycerol. Together with S-selachyl alcohol and S-batyl alcohol, S-chimyl alcohol is a component of some lipid membranes.[1] It is found in the liver of the shark Centrophorus squamosus.[2] The name chimyl is derived from a classification of ratfish, order Chimaeriformes. Like other glyceryl ethers, those derived from chimyl alcohol are not saponifiable.[3]
References
- ↑ Sutter, Marc; Silva, Eric Da; Duguet, Nicolas; Raoul, Yann; Métay, Estelle; Lemaire, Marc (2015). "Glycerol Ether Synthesis: A Bench Test for Green Chemistry Concepts and Technologies". Chemical Reviews 115 (16): 8609–8651. doi:10.1021/cr5004002. PMID 26196761. https://hal.archives-ouvertes.fr/hal-01312971/file/ChemRev_2015_115_8609-8651.pdf.
- ↑ Bordier, Catherine G.; Sellier, Nicole; Foucault, Alain P.; Le Goffic, François (1996). "Purification and characterization of deep sea shark Centrophorus squamosus liver oil 1- O -aklylglycerol ether lipids". Lipids 31 (5): 521–528. doi:10.1007/bf02522646. PMID 8727645.
- ↑ Taguchi, Hiroyasu; Armarego, Wilfred L. F. (1998). "Glyceryl-Ether Monooxygenase [EC 1.14.16.5]. A Microsomal Enzyme of Ether Lipid Metabolism". Medicinal Research Reviews 18 (1): 43–89. doi:10.1002/(SICI)1098-1128(199801)18:1<43::AID-MED3>3.0.CO;2-S. PMID 9436181.
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