Chemistry:Gersdorffite

From HandWiki
Revision as of 04:54, 6 February 2024 by MedAI (talk | contribs) (url)
(diff) ← Older revision | Latest revision (diff) | Newer revision → (diff)
Short description: Nickel arsenide-sulfide (NiAsS) mineral
Gersdorffite
Gersdorffit - Lobenstein, Vogtland.jpg
Gersdorffite
General
CategoryMineral
Formula
(repeating unit)
NiAsS
Strunz classification2.EB.25
Crystal systemP213 polytype: cubic
Pa3 polytype: cubic
Pca21 polytype: orthorhombic
Identification
Colorsilver white to steel gray
Mohs scale hardness5–5.5
Streakgrayish black
Specific gravity5.6–6.2

Gersdorffite or Nickel glance (trivial name) is a nickel arsenic sulfide mineral with formula NiAsS. It crystallizes in the isometric system showing diploidal symmetry. It occurs as euhedral to massive opaque, metallic grey-black to silver white forms. Gersdorffite belongs to a solid solution series with cobaltite, CoAsS. Antimony freely substitutes also leading to ullmannite, NiSbS. It has a Mohs hardness of 5.5 and a specific gravity of 5.9 to 6.33.

Gersdorffite has three crystallisation forms: Gersdorffite-P213 (NiAsS), Gersdorffite-Pa3 (Ni(As,S)2) and Gersdorffite-Pca21 (NiAsS).[1] Gersdorffite occurs as a hydrothermal vein mineral along with other nickel sulfides. Associated minerals include nickeline, nickel-skutterudite, cobaltite, ullmannite, maucherite, löllingite, platinum-group minerals, millerite, pyrite, marcasite, and chalcopyrite.

Gersdorffite was first described in 1843 and named in 1845 for Johann von Gersdorff (1781–1849), owner of the nickel mine at Schladming, Austria the type locality.

References

  1. Bayliss P (1982) A further crystal structure refinement of gersdorffite, American Mineralogist 67, 1058–1064