Chemistry:Lepersonnite-(Gd)

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Lepersonnite-(Gd)
Lepersonnite-(Gd)-Studtite-Curite-201138.jpg
Lepersonnite-(Gd) (flat crystals) intergrown in the yellow studtite clusters (needles) and orange curite.
General
CategoryCarbonate mineral
Formula
(repeating unit)
Ca(Gd,Dy)
2
(UO
2
)
24
(SiO
4
)
4
(CO
3
)
8
(OH)
24
 · 48H2O
Strunz classification5.EG.10 (10 ed)
8/B.38-10 (8 ed)
Dana classification17.1.12.1
Crystal systemOrthorhombic
Crystal classPyramidal (mm2) and dipyramidal (mmm)
Space groupPnnm or Pnn2
Identification
ColorYellow (bright)
Crystal habitNeedle-like crystals in crusts (mammilary) or spherules
Specific gravityFass
Density3.97 (measured)
Optical propertiesBiaxal (-)
Refractive indexnα = 1.638, nβ = 1.666, nγ = 1.682
2V angle73° (calculated)
Other characteristicsRadioactive.svg Radioactive
References[1][2][3]

Lepersonnite-(Gd) is a very rare-earth element and uranium mineral with the chemical formula Ca(Gd,Dy)
2
(UO
2
)
24
(SiO
4
)
4
(CO
3
)
8
(OH)
24
 · 48H2O
. It occurs with bijvoetite-(Y) in the Shinkolobwe deposit in the Democratic Republic of the Congo, famous for rare uranium minerals. It is the only confirmed mineral with essential gadolinium[1][3][5] and is named after the Belgian geologist Jacques Lepersonne.

References

  1. 1.0 1.1 Deliens, M., and Piret, P., 1982. Bijvoetite et lepersonnite, carbonates hydrates d'uranyle et des terres rares de Shinkolobwe, Zaïre. Canadian Mineralogist 20, 231–238.
  2. "Lepersonnite-(Gd) - Handbook of Mineralogy". http://www.handbookofmineralogy.org/pdfs/lepersonnite-(Gd).pdf. Retrieved 2016-03-08. 
  3. 3.0 3.1 "Lepersonnite-(Gd): Lepersonnite-(Gd) mineral information and data". http://www.mindat.org/min-2378.html. Retrieved 2016-03-04. 
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. Gadolinium: The mineralogy of gadolinium - Mindat. org [1]