Chemistry:1,1'-Dihydroxydicyclohexyl peroxide

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1,1-Dihydroxydicyclohexyl peroxide
Dihydroxydicyclohexyl peroxide.svg
Names
IUPAC name
1-(1-hydroxycyclohexyl)peroxycyclohexan-1-ol
Other names
Bis(1-hydroxycyclohexyl) peroxide
Identifiers
3D model (JSmol)
EC Number
  • 219-306-2
UNII
UN number 3106
Properties
C12H22O4
Molar mass 230.304 g·mol−1
Appearance white solid
Melting point 66–68 °C (151–154 °F; 339–341 K)
Hazards
GHS pictograms GHS01: ExplosiveGHS05: CorrosiveGHS07: Harmful
GHS Signal word Danger
H240, H302, H314
P210, P220, P234, P260, P264, P270, P280, P301+312, P301+330+331, P303+361+353, P304+340, P305+351+338, P310, P321, P330, P363, P370+378, P370+380+375, P403+235, P405, P411, P420, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

1,1-Dihydroxydicyclohexyl peroxide is an organic compound with the formula (C6H10OH)2O2. It is one of the peroxides derived from the reaction of cyclohexanone and hydrogen peroxide. Upon treatment with acid and additional peroxide, it converts to the cyclic diperoxide, bis(cyclohexylidene peroxide), (C6H10)2(O2)2.[1][2]

1,1-Dihydroxydicyclohexyl peroxide is a catalyst for radical-initiated vulcanization.

References

  1. Story, Paul R.; Lee, Bunge; Bishop, Clyde E.; Denson, Donald D.; Busch, Peter (1970). "Macrocyclic Synthesis. II. Cyclohexanone Peroxides". The Journal of Organic Chemistry 35 (9): 3059–3062. doi:10.1021/jo00834a042. 
  2. McCullough, Kevin J.; Morgan, Alistair R.; Nonhebel, Derek C.; Pauson, Peter L.; White, Graham J. (1980). "Ketone-Derived Peroxides. Part 1. Synthetic Methods". Journal of Chemical Research, Synopses: 34.