Chemistry:1,1,1-Trichloroacetone

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1,1,1-Trichloroacetone
1,1,1-Trichloroacetone.png
Names
Preferred IUPAC name
1,1,1-Trichloropropan-2-one
Other names
1,1,1-Trichloroacetone
1,1,1-Trichloropropanone
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
EC Number
  • 620-529-6
UNII
Properties
C3H3Cl3O
Molar mass 161.41 g·mol−1
Appearance Colourless liquid
Density 1.475 g/cm3
Boiling point 134 °C (273 °F; 407 K)[1]
slightly soluble
Solubility Soluble in ethanol and diethyl ether
Hazards
Main hazards Irritant
GHS pictograms GHS07: Harmful
GHS Signal word Warning
H315, H319, H335
P261, P264, P271, P280, P302+352, P304+340, P305+351+338, P312, P321, P332+313, P337+313, P362, P403+233, P405, P501
Flash point 64 °C (147 °F; 337 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

1,1,1-Trichloroacetone is a chlorinated analogue of acetone with the chemical formula CH3COCCl3. It is a colourless liquid. 1,1,1-Trichloroacetone can be synthesised from chlorination of chloroacetone (1,1,3-trichloroacetone is formed as a by-product). An alternative synthesis involves the transfer of a trichloromethyl group from trichloroacetate onto acetyl chloride.[2]

See also

References

  1. "1,1,1-TRICHLOROACETONE CAS#: 918-00-3". https://m.chemicalbook.com/ProductChemicalPropertiesCB9175765_EN.htm. 
  2. Taschner, Michael J. (2001). "Sodium Trichloroacetate". e-EROS Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rs113. ISBN 0471936235.