Chemistry:1,5-Bis(diphenylphosphino)pentane
From HandWiki
pentane.svg)
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| Other names
DPPP
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| Identifiers | |
3D model (JSmol)
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| Abbreviations | dpppe |
| ChEMBL | |
| ChemSpider | |
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PubChem CID
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| Properties | |
| C29H30P2 | |
| Molar mass | 440.507 g·mol−1 |
| Appearance | White solid |
| Melting point | 41-44 oC[1] |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Warning |
| H315, H319, H335 | |
| P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P280, P302+352, P304+340, P305+351+338, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
1,5-Bis(diphenylphosphino)pentane is an organophosphorus compound with the formula C29H30P2. It can be prepared by reacting 1,5-dibromopentane with lithium diphenylphosphide,[3] or diphenylphosphine in presence of caesium hydroxide.[4] It reacts with copper(I) iodide to give a luminescent dinuclear complex [CuIPh2P(CH2)5PPh2]2.[5]
References
- ↑ Shatunov, V.V.; Korlyukov, A.A.; Lebedev, A.V.; Sheludyakov, V.D.; Kozyrkin, B.I.; Orlov, V.Yu. (2011). "The synthesis and deep purification of GaEt3. Reversible complexation of adducts MAlk3 (M = Al, Ga, In; Alk = Me, Et) with phenylphosphines". Journal of Organometallic Chemistry (Elsevier BV) 696 (10): 2238–2251. doi:10.1016/j.jorganchem.2010.11.044. ISSN 0022-328X.
- ↑ "1,5-Bis(diphenylphosphino)pentane" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/2733414#section=Safety-and-Hazards.
- ↑ Chou, Ta Shue; Yuan, Jeh Jing; Tsao, Chung Huang (1985). "Ultrasonic acceleration of the reductive cleavage of phosphorus-carbon bonds with lithium metal. A simple preparation of tertiary phosphines". Journal of Chemical Research, Synopses (1): 18–19. ISSN 0308-2342..
- ↑ Honaker, Matthew T.; Salvatore, Ralph Nicholas (February 1, 2004). "A MILD AND EFFICIENT CsOH-PROMOTED SYNTHESIS OF DITERTIARY PHOSPHINES". Phosphorus, Sulfur, and Silicon and the Related Elements (Informa UK Limited) 179 (2): 277–283. doi:10.1080/10426500490262261. ISSN 1042-6507.
- ↑ Zhang, Xiayi; Song, Li; Hong, Mingwei; Shi, Hongsheng; Xu, Kaijie; Lin, Qizhong; Zhao, Yi; Tian, Yuan et al. (2014). "Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations". Polyhedron (Elsevier BV) 81: 687–694. doi:10.1016/j.poly.2014.07.034. ISSN 0277-5387.
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