Chemistry:2-Methyl-2-butene

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2-Methyl-2-butene[1][2][3]
Structural formula of 2-methyl-2-butene.svg
2-Methyl-2-butene-3D-balls.png
Names
Preferred IUPAC name
2-Methylbut-2-ene
Other names
β-Isoamylene
Trimethylethylene
2-Methyl-2-butene
Isoamylene
Identifiers
3D model (JSmol)
ChemSpider
UNII
UN number 2460
Properties
C5H10
Molar mass 70.1329 g/mol
Appearance Colorless liquid
Odor Sweet
Density 0.662 g/cm3
Melting point −134 °C (−209 °F; 139 K)
Boiling point 39 °C (102 °F; 312 K)
Slightly soluble
Solubility in alcohols, ether Miscible
-54.14·10−6 cm3/mol
1.385
Hazards
Main hazards Mildly toxic
Flash point < −45 °C (−49 °F; 228 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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2-Methyl-2-butene, 2m2b, 2-methylbut-2-ene, also beta-isoamylene is an alkene hydrocarbon with the molecular formula C5H10.

Used as a free radical scavenger in trichloromethane (chloroform) and dichloromethane (methylene chloride). It is also used to scavenge hypochlorous acid (HOCl) in the Pinnick oxidation.

John Snow, the English physician, experimented with it in the 1840s as an anesthetic, but stopped using it for unknown reasons.[4]

See also

References

  1. Dean's Handbook of Organic Chemistry, 2nd Edition.
  2. "Safety (MSDS) data for 2-methyl-2-butene". http://msds.chem.ox.ac.uk/ME/2-methyl-2-butene.html. 
  3. PubChem
  4. Caton, Donald (2000). "John Snow's practice of obstetric anesthesia". Anesthesiology: The Journal of the American Society of Anesthesiologists 92 (1): 247–252. doi:10.1097/00000542-200001000-00037. PMID 10638922.