Chemistry:Ammonium phosphinate
From HandWiki
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| Names | |||
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| Other names
Ammonium hypophosphite
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| Identifiers | |||
3D model (JSmol)
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| EC Number |
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| Properties | |||
| H6NO2P | |||
| Molar mass | 83.027 g·mol−1 | ||
| Appearance | colorless crystals | ||
| Density | 1.634 g/cm3 | ||
| Melting point | 200 | ||
| soluble | |||
| Hazards | |||
| GHS pictograms |  [1]
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| GHS Signal word | Warning | ||
| HH315Script error: No such module "Preview warning".Category:GHS errors, HH319Script error: No such module "Preview warning".Category:GHS errors, HH335Script error: No such module "Preview warning".Category:GHS errors[2] | |||
| PP261Script error: No such module "Preview warning".Category:GHS errors, PP305Script error: No such module "Preview warning".Category:GHS errors, PP351Script error: No such module "Preview warning".Category:GHS errors, PP338Script error: No such module "Preview warning".Category:GHS errors[2] | |||
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |||
| Infobox references | |||
Ammonium phosphinate is a chemical compound with the chemical formula NH
4PH
2O
2.[3][4] This is a salt of ammonium and phosphinic acid.
Synthesis
Synthesis of ammonium phosphinate may be achieved by the effect of ammonia solution on phosphinic acid solution:
- HPH
2O
2 + NH
3 → NH
4PH
2O
2
- HPH
Physical properties
Ammonium phosphonate forms colorless crystals of the orthorhombic system, space group Cmma, cell parameters a = 0.757 nm, b = 1.147 nm, c = 0.398 nm, Z = 4.[5]
The compound is soluble in water and ethanol, but insoluble in acetone.[6]
Uses
The compound is usually used as a catalyst for the production of polyamide.[2]
References
- ↑ "Ammonium hypophosphite". Sigma Aldrich. https://www.sigmaaldrich.com/RU/en/product/sigald/04401.
- ↑ 2.0 2.1 2.2 "Ammonium phosphinate | 7803-65-8, Ammonium phosphinate Formula" (in en). ECHEMI. https://www.echemi.com/products/pid_Rock22946-ammoniumhypophosphite.html.
- ↑ (in en) Russian Chemical Reviews. Russian Academy of Sciences, The Royal Society of Chemistry and Turpion Limited. 1980. p. 49. https://books.google.com/books?id=9ynzAAAAMAAJ&q=%22Ammonium+phosphinate%22. Retrieved 2 December 2024.
- ↑ (in en) Emergency Planning and Community RightToKnow Act section 313 reporting guidance for the textile processing industry. DIANE Publishing. p. C-14. ISBN 978-1-4289-0164-3. https://books.google.com/books?id=rkvNRwX85ywC&dq=%22Ammonium+phosphinate%22&pg=SL3-PA14. Retrieved 2 December 2024.
- ↑ Weakley, T. J. R. (18 August 2011). "The Crystal Structures of Ammonium Phosphinate (Hypophosphite) and Guanidinium Phosphinate, and the Cell Parameters of Hydrazinium(2+) Phosphinate". Journal of the Chemical Society of Pakistan 1 (2): 37. https://jcsp.org.pk/issueDetail.aspx?aid=c52791e9-67c5-486f-93d9-33494898e517. Retrieved 2 December 2024.
- ↑ Armarego, W. L. F. (27 August 2022) (in en). Purification of Laboratory Chemicals: Part 2 Inorganic Chemicals, Catalysts, Biochemicals, Physiologically Active Chemicals, Nanomaterials. Butterworth-Heinemann. p. 8. ISBN 978-0-323-95828-8. https://books.google.com/books?id=bN5sEAAAQBAJ&dq=%22Ammonium+phosphinate%22&pg=PA7. Retrieved 2 December 2024.
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