Chemistry:Ammonium tetrathioarsenate

From HandWiki
Ammonium tetrathioarsenate
Names
Other names
Ammonium tetrathioarsenate(V)
Identifiers
3D model (JSmol)
Properties
AsH12N3S4
Molar mass 257.28 g·mol−1
Appearance colorless crystals
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Ammonium tetrathioarsenate is a chemical compound with the chemical formula (NH
4
)
3
AsS
4
.[1][2]

Synthesis

Reaction of arsenic trisulfide with yellow ammonium sulphide:[3]

As
2
S
3
+ 3(NH
4
)
2
S + 2S → 2(NH
4
)
3
AsS
4

Physical properties

Ammonium tetrathioarsenate forms colorless crystals of orthorhombic system, spatial group Pcmn.[4]

References

  1. (in en) Structure Reports. A. Oosthoek.. 1993. p. 352. ISBN 978-0-7923-2310-5. https://books.google.com/books?id=Ok3zAAAAMAAJ&q=ammonium+tetrathioarsenate. Retrieved 26 February 2025. 
  2. (in en) Structure Reports for .... International Union of Crystallography. 1963. p. 153. ISBN 978-90-313-0042-6. https://books.google.com/books?id=4JQQAAAAIAAJ&q=ammonium+tetrathioarsenate. Retrieved 26 February 2025. 
  3. Prakash, Satya (October 2000) (in en). Advanced Inorganic Chemistry - Volume II. S. Chand Publishing. p. 42. ISBN 978-81-219-1787-2. https://books.google.com/books?id=YTBFmeorS6AC&dq=ammonium+tetrathioarsenate&pg=PA42. Retrieved 26 February 2025. 
  4. Donnay, Joseph Désiré Hubert (1973) (in en). Crystal Data: Inorganic compounds. National Bureau of Standards. p. O-199. https://books.google.com/books?id=5lVCBwmZsLYC&dq=ammonium+tetrathioarsenate&pg=RA3-PA199. Retrieved 26 February 2025.