Chemistry:Base oil
Base oils are used to manufacture products including lubricating greases, motor oil and metal processing fluids. Different products require different compositions and properties in the oil. One of the most important factors is the liquid’s viscosity at various temperatures. Whether or not a crude oil is suitable to be made into a base oil is determined by the concentration of base oil molecules as well as how easily these can be extracted. Base oil is produced by means of refining crude oil. This means that crude oil is heated in order that various distillates can be separated from one another. During the heating process, light and heavy hydrocarbons are separated – the light ones can be refined to make petrol and other fuels, while the heavier ones are suitable for bitumen and base oils.[1]
There are large numbers of crude oils all around the world that are used to produce base oils. The most common one is a type of paraffinic crude oil, although there are also naphthenic crude oils that create products with better solubility and very good properties at low temperatures. By using hydrogenation technology, in which sulfur and aromatics are removed using hydrogen under high pressure, extremely pure base oils can be obtained, which are suitable when quality requirements are particularly stringent.[2]
Chemical substances – additives – are added to the base oil in order to meet the quality requirements for the end products in terms of, for example, friction and cleaning properties. Certain types of motor oils contain more than twenty percent additives.[3]
Production of mineral base oils
Mineral base oils are first distilled from petroleum, and they comprise the 26-40 carbon fraction. Aromatic compounds are initially removed by solvent extraction: The distillation cut is mixed with an immiscible solvent such as phenol or furfural. This solvent preferentially dissolves aromatic compounds well, and the aromatic compounds are separated together with the solvent.[4]
Long chain alkanes form waxes that precipitate at relatively high temperature. They are removed either by crystallizing the waxes at low temperature, or they can be isomerized to branched alkanes. Various levels of hydrogenation are used thereafter to remove any remaining aromatic compounds and residual heteroatoms (in the form of nitrogen and sulfur compounds).[4]
Very generally, heteroatoms (as nitrogen and sulfur compounds) and aromatic compounds are removed as the base oil is hydrogenated from Group I through Group III. Reduction in heteroatoms reduces formation of acids when engine oils are exposed to the combustion environment, acids being corrosive to the engine. The reduction in aromatic compounds improves the oxidative stability of the oil, delaying formation of sludge and varnish. Yet both effects lead to the oil becoming less polar, making it a poorer solvent for both the additive package of an engine oil, as well as accumulated oxidation byproducts.[5]
API classifications
In 1993, the American Petroleum Institute (API), categorized base oils into five main groups. Chemical and physical characteristics are defined for Groups I through III that reflect how refined they are, correlating in some way to high and low-temperature viscosity, oxidative stability, volatility, and so on. Group IV oils comprise polyalphaolefins by definition, and Group V oils are those that do not fit into any previous category. The intent of such categorization is to help ensure that engine oils retain performance when different base oils are used.[6]
Group I
Originating in the 1930s, the least refined type which is produced by solvent refining. It usually consists of conventional petroleum base oils. An improvement to the refining process in the 1960s called hydro-treating made this base oil more stable, less reactive, and longer lasting than the earlier base oils.
API defines group I as "base stocks contain less than 90 percent saturates and/or greater than 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120".
Group II
Originating in 1971, a better grade of petroleum base oil, which may be partially produced by hydrocracking. All impurities will be removed from the oil leading to clearer color.
API defines group II as "base stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 80 and less than 120".
Group III
Originating in 1993, the most refined grade of petroleum base oil, since they are fully produced by hydrocracking, hydroisomerization, and hydrotreating,[7] which make these oils purer.
API defines group III as "base stocks contain greater than or equal to 90 percent saturates and less than or equal to 0.03 percent sulfur and have a viscosity index greater than or equal to 120".
Group IV
Originating in 1974, consists of synthetic oils made of polyalphaolefins (PAO). Group IV base oils have a viscosity index range of 125 - 200.
Polyalphaolefin oils have a higher oxidative stability in extreme temperatures, and also have exceptionally low pour points, which makes them much more suitable for use in very cold weather (as found in northern Europe), as well as in very hot weather (as in Middle East).
Group V
Originating in the 1940s, any type of base oil other than mentioned in the previously defined groups. Group V oils include alkylated naphthalenes (e.g., ExxonMobil Synesstic[8]) and esters.[9]
Unofficial Classifications
Unofficial base oil classifications are not recognized by the American Petroleum Institute (API), however, they are widely used and marketed for motor oils and automatic transmission fluids.
Group II+
Originating in the 1990s, a more refined grade of petroleum Group II base oil, produced by Hydrotreating. Group II+ base oils have a high viscosity index at the higher end of the API Group II range. The viscosity index is 110-115 minimum.
Group III+
Originating in 2015, produced by a gas to liquids (GTL) process. Group III+ base oils have a Very High Viscosity Index (VHVI) at the higher end of the API Group III range. The viscosity index is 130-140 minimum.
Group VI
Consists of synthetic oils made of Poly-internal-olefins (PIO).
Poly-internal-olefins (PIO) oils are similar to Poly-alpha-olefins (PAO), but use different chemicals in the synthesis process to obtain an even higher viscosity index (VI)[10]
See also
- Mineral oil, a broader term that encompasses many base oils. This term usually refers to the domestic or medical use of oil refined from petroleum
References
- ↑ SPBI
- ↑ 2004/284/EC: Commission Decision of 29 September 1999 declaring a concentration compatible with the common market and the EEA Agreement (Case No IV/M.1383 — Exxon/Mobil)
- ↑ QRP OIL: http://www.qrpoil.com/site/?baseoilsn500
- ↑ 4.0 4.1 Jeremy Wright (2012). "The Fundamentals of Mineral Base Oil Refining". Machinery Lubrication. https://www.machinerylubrication.com/Read/28960/mineral-oil-refining. Retrieved 2023-03-28.
- ↑ "How Solvency Impacts Lube Performance". Lubes 'n' Greases. 2015-02-15. https://www.lubesngreases.com/magazine-emea/69/base-oil-report-92/. Retrieved 2023-03-28.
- ↑ "Annex E - API Base Oil Interchangeability Guidelines for Passenger Car Motor Oils and Diesel Engine Oils". American Petroleum Institute. 2015. https://www.api.org/~/media/files/certification/engine-oil-diesel/publications/anne-rev-03-25-15.pdf.
- ↑ https://www.bobistheoilguy.com A Review of Mineral and Synthetic Base Oils
- ↑ "Alkylated Naphthalene". ExxonMobil. https://www.exxonmobilchemical.com/en/products/synthetic-base-stocks/alkylated-naphthalene. Retrieved 2023-03-27.
- ↑ For example, adipate, trimellitate, and polyol esters: "Ester Base Stocks". Vanderbilt Worldwide Ltd. https://www.vanderbiltworldwide.com/markets/petroleum-ester-base-stocks. Retrieved 2023-03-27.
- ↑ https://patents.google.com/patent/US20140113847 High viscosity index lubricating oil base stock and viscosity modifier combinations, and lubricating oils derived therefrom
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