Chemistry:Carbonado

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Short description: Impure form of polycrystalline diamond consisting of diamond, graphite, and amorphous carbon
Carbonado
Sometimes cut as gemstones - often requiring lasers -, but have a granular appearance. Usually cracked in high-pressure presses for industrial usage.
Three carbonados from the Central African Republic
General
CategoryNative minerals
Formula
(repeating unit)		C
Crystal systemIsometric-hexoctahedral (cubic)
Identification
Formula mass12.01 u
ColorTypically black, can be grey, various shades of green and brown sometimes mottled.
Crystal habitPolycrystalline
FractureIrregular torn surfaces
Mohs scale hardness10
|re|er}}Adamantine
StreakWhite
Specific gravity3.52±0.01
Density3.5–3.53 g/cm3
Polish lusterAdamantine
Optical propertiesNone
BirefringenceNone
PleochroismNone

Carbonado, commonly known as black diamond, is one of the toughest forms of natural diamond. It is an impure, high-density, micro-porous form of polycrystalline diamond consisting of diamond, graphite, and amorphous carbon, with minor crystalline precipitates filling pores and occasional reduced metal inclusions.[1] Titanium nitride (TiN, osbornite) has been found in carbonado.[2] It is found primarily in alluvial deposits where it is most prominent in mid-elevation equatorial regions such as Central African Republic and in Brazil , where the vast majority of carbonado diamondites have been found. Its natural colour is black or dark grey, and it is more porous than other diamonds.

Unusual properties

Carbonado diamonds are typically pea-sized or larger porous aggregates of many tiny black crystals. The most characteristic carbonados are mined in the Central African Republic and in Brazil, in neither place associated with kimberlite, the source of typical gem diamonds. Lead isotope analyses have been interpreted as documenting crystallization of carbonados about 3 billion years ago; yet carbonado is found in younger sedimentary rocks.[3]

Mineral grains included within diamonds have been studied extensively for clues to diamond origin. Some typical diamonds contain inclusions of common mantle minerals such as pyrope and forsterite, but such mantle minerals have not been observed in carbonado. In contrast, some carbonados contain authigenic inclusions of minerals characteristic of the Earth's crust; the inclusions do not necessarily establish formation of the diamonds in the crust, because while the obvious crystal inclusions occur in the pores that are common in carbonados, they may have been introduced after carbonado formation. Inclusions of other minerals, rare or nearly absent in the Earth's crust, are found at least partly incorporated in diamond, not just in pores: among such other minerals are those with compositions of Si, SiC, and Fe‑Ni. No distinctive high-pressure minerals, including the hexagonal carbon polymorph, lonsdaleite, have been found as inclusions in carbonados although such inclusions might be expected if carbonados formed by meteorite impact.[3]

Isotope studies have yielded further clues to carbonado origin. The carbon isotope value is very low (little carbon‑13 compared to carbon‑12, relative to typical diamonds).[3]

Carbonado exhibits strong luminescence (photoluminescence and cathodoluminescence) induced by nitrogen and by vacancies existing in the crystal lattice. Luminescence halos are present around radioactive inclusions, and it is suggested that the radiation damage occurred after formation of the carbonados,[4] an observation perhaps pertinent to the radiation hypothesis listed below.

Toughness vs. hardness

Carbonado’s polycrystalline texture makes it more durable than a monocrystalline diamond. It is the same hardness as other types of diamond, but it is much tougher. Its polycrystalline texture allows a single abrasive granule to present multiple crystallographic orientations of the diamond crystal at the cutting surface and the hardest orientation does the most aggressive cutting.

Cutting tools made with carbonado last longer and require less maintenance. Carbonado was recognized as an abrasive in the 1800s and was more highly valued for its cutting and grinding effectiveness over other varieties of diamond. The problem with carbonado is its rarity. It is only found in two countries, and total worldwide production has only been a few tons. Carbonado is not an important commodity in today's abrasive market.

In the late 1800s, when De Beers was developing their diamond mines in South Africa, they preferred carbonado over their own diamonds for diamond drilling. Gardner F. Williams, General Manager of De Beers Consolidated Mines, Ltd. lamented: "Round or shot boart is found in the mines at Kimberley and is very valuable for use in diamond drilling since the Brazilian carbonado has become so scarce."<ref{{cite web> |author1=Hobart M. King |url=https://geology.com/diamond/carbonado/ |date=2022|title=Carbonado Diamonds}}</ref>

Hypotheses for origin

The origin of carbonado is controversial, and some proposed hypotheses are as follows:

  1. Direct conversion of organic carbon under high-pressure conditions in the Earth's interior, the most common hypothesis for diamond formation
  2. Shock metamorphism induced by meteoritic impact at the Earth's surface
  3. Radiation-induced diamond formation by spontaneous fission of uranium and thorium
  4. Accumulated local formation in reduced organic-rich sediment over long geologic periods due to pyrometamorphic-rapid processes associated with long-duration superbolt lightning strikes, known to have similar global distribution as carbonado diamondite deposits at similar elevations.
  5. Formation inside an earlier-generation giant star in our area, that long ago exploded in a supernova.[5]
  6. An origin in interstellar space, due to the impact of an asteroid, rather than being thrown from within an exploding star.[5]

The origin of carbonado is still under debate.[6][7][8]

Extraterrestrial origin hypothesis

Supporters of an extraterrestrial origin of carbonados such as Stephen Haggerty propose that their material source was a supernova which occurred at least 3.8 billion years ago.[9][10][11][12] After coalescing and drifting through outer space for about one and a half billion years, a large mass fell to earth as a meteorite approximately 2.3 billion years ago. It possibly fragmented during entry into the Earth's atmosphere and impacted in a region which would much later split into Brazil and the Central African Republic, assumed to be the only two known locations of carbonado-diamond deposits.

The presence of osbornite, which only forms under very reducing conditions and at very high temperatures, argues for an extraterrestrial origin.[2]

Largest cut diamond

The largest cut black diamond in the world is a carbonado named 'The Enigma', weighing 555.55 carats (111 g).[13]

See also

References

  1. ↑ Kroschwitz, Jacqueline I. (2004). Kirk-Othmer encyclopedia of chemical technology (5th ed.). Hoboken, N. J.: J. Wiley. p. 10. ISBN 9780471484943. 
  2. ↑ 2.0 2.1 G. Parthasarathy (Aug 2016). "Osbornite (TiN): Implications for an extraterrestrial origin of carbonado- diamonds". https://www.researchgate.net/publication/314359536_Osbornite_TiN_Implications_for_an_extraterrestrial_origin_of_carbonado-_diamonds. 
  3. ↑ 3.0 3.1 3.2 Heaney, P. J.; Vicenzi, E. P.; De, S. (2005). "Strange Diamonds: the Mysterious Origins of Carbonado and Framesite". Elements 1 (2): 85. doi:10.2113/gselements.1.2.85. 
  4. ↑ Kagi, H.; Sato, S.; Akagi, T.; Kanda, H. (2007). "Generation history of carbonado inferred from photoluminescence spectra, cathodoluminescence imaging, and carbon-isotopic composition". American Mineralogist 92 (1): 217–224. doi:10.2138/am.2007.1957. Bibcode: 2007AmMin..92..217K. http://www.minsocam.org/msa/ammin/toc/Abstracts/2007_Abstracts/Jan07_Abstracts/Kagi_p217_07.pdf. 
  5. ↑ 5.0 5.1 Garai, Jozsef; Haggerty, Stephen E.; Rekhi, Sandeep; Chance, Mark (2006). "Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado Diamonds". The Astrophysical Journal 653 (2): L153. doi:10.1086/510451. Bibcode: 2006ApJ...653L.153G. Archived from the original on 2007-08-09. https://web.archive.org/web/20070809204752/http://www.fiu.edu/~jgara002/research%20statement/carbonado/carbonado-infrared.htm. . This study suggested that infrared absorption spectra of carbonado are similar to diamonds of extraterrestrial origin; selected significant peaks are due to trace abundances of the elements nitrogen and hydrogen. The researchers concluded with the assumption that the mineral necessarily formed in an interstellar environment. In this sense, carbonado are theorized to be akin to carbon-rich cosmic dust, likely having formed in an environment near carbon stars. The diamonds were suggested to have been fragments of a body of asteroid size that subsequently fell to Earth as meteorites.
  6. ↑ Dorrit Jacob, Larissa Dobrzhinetskaya, and Richard Wirth (Sep 2014). "New insight into polycrystalline diamond genesis from modern nanoanalytical techniques". Earth-Science Reviews. doi:10.1016/j.earscirev.2014.05.005. 
  7. ↑ G.J.H. McCall (April 2009). "The carbonado diamond conundrum". Earth-Science Reviews. doi:10.1016/j.earscirev.2009.01.002. 
  8. ↑ Renjamin Bondeau; Violaine Sautter; Julien Barjon (2008). "New columnar texture of carbonado: Cathodoluminescence study". Diamond and Related Materials 17 (11): 1897. doi:10.1016/j.diamond.2008.04.006. Bibcode: 2008DRM....17.1897R. 
  9. ↑ Stephen Haggerty (2017). "Carbonado Diamond: A Review of Properties and Origin". Gems and Gemology. doi:10.5741/GEMS.53.2.16. https://www.gia.edu/gems-gemology/summer-2017-carbonado-diamond. 
  10. ↑ Stephen Haggerty (Mar 2014). "Carbonado: Physical and chemical properties, a critical evaluation of proposed origins, and a revised genetic model". Earth-Science Reviews. doi:10.1016/j.earscirev.2013.12.008. 
  11. ↑ Broad, William J. (1996-09-17). "Giant Black Diamonds Of Mysterious Origin May Hail From Space". The New York Times. ISSN 0362-4331. https://www.nytimes.com/1996/09/17/science/giant-black-diamonds-of-mysterious-origin-may-hail-from-space.html. 
  12. ↑ Garai, Jozsef; Haggerty, Stephen E.; Rekhi, Sandeep; Chance, Mark (2006-12-20). "Infrared Absorption Investigations Confirm the Extraterrestrial Origin of Carbonado-Diamonds". The Astrophysical Journal 653 (2): L153–L156. doi:10.1086/510451. ISSN 0004-637X. Bibcode: 2006ApJ...653L.153G. 
  13. ↑ "The Enigma: Billion-year-old black diamond sold for £3.16m" (in en). BBC News. 2022-02-12. https://www.bbc.co.uk/news/business-60328375. 

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