Chemistry:Cyclopentanecarboxylic acid
From HandWiki
| |
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
| ChEMBL | |
| ChemSpider | |
| EC Number |
|
PubChem CID
|
|
| UNII | |
| |
| |
| Properties | |
| C6H10O2 | |
| Molar mass | 114.144 g·mol−1 |
| Appearance | colorless oil |
| Density | 1.0510 g/cm3 |
| Melting point | −7 °C (19 °F; 266 K) |
| Boiling point | 212 °C (414 °F; 485 K) |
| Hazards | |
| GHS pictograms | 
|
| GHS Signal word | Warning |
| H315, H319, H335 | |
| P261, P264, P264+265Script error: No such module "Preview warning".Category:GHS errors, P271, P280, P302+352, P304+340, P305+351+338, P319Script error: No such module "Preview warning".Category:GHS errors, P321, P332+317Script error: No such module "Preview warning".Category:GHS errors, P337+317Script error: No such module "Preview warning".Category:GHS errors, P362+364Script error: No such module "Preview warning".Category:GHS errors, P403+233, P405, P501 | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Cyclopentanecarboxylic acid is an organic compound with the formula C
5H
9CO
2H. It is a colorless nonvolatile oil. It can be produced by the palladium-catalyzed hydrocarboxylation of cyclopentene:[2]
- C
5H
8 + CO + H
2O → C
5H
9CO
2H
An alternative route involves base-induced ring contraction of 2-chlorocyclohexanone to give the ester methyl cyclopentanecarboxylate, which can be hydrolyzed to the carboxylic acid.[3]
References
- ↑ "Cyclopentanecarboxylic acid" (in en). https://pubchem.ncbi.nlm.nih.gov/compound/18840#section=Safety-and-Hazards.
- ↑ Sang, Rui; Kucmierczyk, Peter; Dühren, Ricarda; Razzaq, Rauf; Dong, Kaiwu; Liu, Jie; Franke, Robert; Jackstell, Ralf et al. (2019). "Synthesis of Carboxylic Acids by Palladium‐Catalyzed Hydroxycarbonylation". Angewandte Chemie International Edition 58 (40): 14365–14373. doi:10.1002/anie.201908451. PMID 31390131.
- ↑ D. W. Goheen, W. R. Vaughan (1959). "Methyl Cyclopentanecarboxylate". Organic Syntheses 39: 37. doi:10.15227/orgsyn.039.0037.
 |  |
