Chemistry:Danburite

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Short description: Tectosilicate mineral
Danburite
Danburite-162634.jpg
Cluster of creamy crystals of danburite
General
CategoryTectosilicates
Formula
(repeating unit)
CaB2(SiO4)2
Strunz classification9.FA.65
Dana classification56.3.1.1
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPnam
Unit cella = 8.038(3), b = 8.752(5)
c = 7.73 [Å]; Z = 4
Identification
ColourColourless, white, gray, brownish white, straw yellow
Crystal habitEuhedral prismatic crystals; disseminated masses
Cleavage{001} Poor
FractureSubconchoidal to uneven
TenacityBrittle
Mohs scale hardness7 – 7.5
Vitreous to greasy|re|er}}Vitreous to greasy
StreakWhite
DiaphaneityTransparent to translucent
Specific gravity2.93 – 3.02
Optical propertiesBiaxial (+/-)
Refractive indexnα = 1.627 – 1.633 nβ = 1.630 – 1.636 nγ = 1.633 – 1.639
Birefringenceδ = 0.006
2V angle88 to 90° measured
Dispersionr < v strong
Ultraviolet fluorescenceFluorescent and thermoluminescent (red); Short UV=violet blue; Long UV=blue to blue-green
References[1][2][3]

Danburite is a calcium boron silicate mineral with a chemical formula of CaB2(SiO4)2.[5]

It has a Mohs hardness of 7 to 7.5 and a specific gravity of 3.0.[5] The mineral has an orthorhombic crystal form.[5] It is usually colourless, like quartz, but can also be either pale yellow[5] or yellowish-brown. It typically occurs in contact metamorphic rocks.

The Dana classification of minerals categorizes danburite as a sorosilicate, while the Strunz classification scheme lists it as a tectosilicate;[3] its structure can be interpreted as either.

Its crystal symmetry and form are similar to topaz; however, topaz is a calcium fluorine bearing nesosilicate. The clarity, resilience, and strong dispersion of danburite make it valuable as cut stones for jewelry.

It is named for Danbury, Connecticut, United States , where it was first discovered in 1839 by Charles Upham Shephard.[5]

Danburite from Mexico, ≈ 4 cm in height

References

  1. Danburite data on Webmineral
  2. "Danburite in The Handbook of Mineralogy". http://www.handbookofmineralogy.com/pdfs/danburite.pdf. 
  3. 3.0 3.1 Danburite on Mindat.org
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 5.2 5.3 5.4 Chisholm, Hugh, ed (1911). "Danburite". Encyclopædia Britannica. 7 (11th ed.). Cambridge University Press. p. 793.