Chemistry:Silicate minerals

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Short description: Rock-forming minerals with predominantly silicate anions
Copper silicate mineral chrysocolla.

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of the Earth's crust.[1][2][3]

In mineralogy, silica (silicon dioxide) SiO2 is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs.

On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis.

Diatomaceous earth, a biogenic form of silica as viewed under a microscope. The imaged region measures approximately 1.13 by 0.69 mm.

Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth.[citation needed]

General structure

A silicate mineral is generally an ionic compound whose anions consist predominantly of silicon and oxygen atoms.

In most minerals in the Earth's crust, each silicon atom is the center of an ideal tetrahedron, whose corners are four oxygen atoms covalently bound to it. Two adjacent tetrahedra may share a vertex, meaning that the oxygen atom is a bridge connecting the two silicon atoms. An unpaired vertex represents an ionized oxygen atom, covalently bound to a single silicon atom, that contributes one unit of negative charge to the anion.

Some silicon centers may be replaced by atoms of other elements, still bound to the four corner oxygen corners. If the substituted atom is not normally tetravalent, it usually contributes extra charge to the anion, which then requires extra cations. For example, in the mineral orthoclase [KAlSi3O8]n, the anion is a tridimensional network of tetrahedra in which all oxygen corners are shared. If all tetrahedra had silicon centers, the anion would be just neutral silica [SiO2]n. Replacement of one in every four silicon atoms by an aluminum atom results in the anion [AlSi3O−8]n, whose charge is neutralized by the potassium cations K+.

Main groups

In mineralogy, silicate minerals are classified into seven major groups according to the structure of their silicate anion:[4][5]

Major group Structure Chemical formula Example
Nesosilicates isolated silicon tetrahedra [SiO4]4− olivine
Sorosilicates double tetrahedra [Si2O7]6− epidote, melilite group
Cyclosilicates rings [SinO3n]2n− tourmaline group
Inosilicates single chain [SinO3n]2n− pyroxene group
Inosilicates double chain [Si4nO11n]6n− amphibole group
Phyllosilicates sheets [Si2nO5n]2n− micas and clays
Tectosilicates 3D framework [AlxSiyO(2x+2y)]x− quartz, feldspars, zeolites

Note that tectosilicates can only have additional cations if some of the silicon is replaced by an atom of lower valence such as aluminium. Al for Si substitution is common.

Nesosilicates or orthosilicates

Orthosilicate anion SiO4−4. The grey ball represents the silicon atom, and the red balls are the oxygen atoms.
Nesosilicate specimens at the Museum of Geology in South Dakota

Nesosilicates (from Greek νῆσος nēsos, island), or orthosilicates, have the orthosilicate ion, which constitute isolated (insular) [SiO4]4− tetrahedra that are connected only by interstitial cations. The Nickel–Strunz classification is 09.A –examples include:

Kyanite crystals (unknown scale)

Sorosilicates

Pyrosilicate anion Si2O6−7.
Sorosilicate exhibit at Museum of Geology in South Dakota

Sorosilicates (from Greek σωρός sōros, heap, mound) have isolated pyrosilicate anions Si2O6−7, consisting of double tetrahedra with a shared oxygen vertex—a silicon:oxygen ratio of 2:7. The Nickel–Strunz classification is 09.B. Examples include:

Cyclosilicates

Cyclosilicate specimens at the Museum of Geology, South Dakota
Pezzottaite
Bazzite.

Cyclosilicates (from Greek κύκλος kuklos, circle), or ring silicates, have three or more tetrahedra linked in a ring. The general formula is (SixO3x)2x−, where one or more silicon atoms can be replaced by other 4-coordinated atom. The silicon:oxygen ratio is 1:3. Double rings have the formula (Si2xO6x)2x−. The Nickel–Strunz classification is 09.C. Possible ring sizes include:

Some example minerals are:

  • 3-member single ring
  • 4-member single ring
  • 6-member single ring
  • 9-member single ring
    • Eudialyte – Na15Ca6(Fe,Mn)3Zr3SiO(O,OH,H2O)3(Si3O9)2(Si9O27)2(OH,Cl)2
  • 6-member double ring

Note that the ring in axinite contains two B and four Si tetrahedra and is highly distorted compared to the other 6-member ring cyclosilicates.

Inosilicates

Inosilicates (from Greek ἴς is [genitive: ἰνός inos], fibre), or chain silicates, have interlocking chains of silicate tetrahedra with either SiO3, 1:3 ratio, for single chains or Si4O11, 4:11 ratio, for double chains. The Nickel–Strunz classification is 09.D – examples include:

Single chain inosilicates

Double chain inosilicates

  • Inosilicate, pyroxene family, with 2-periodic single chain (Si2O6), diopside

  • Inosilicate, clinoamphibole, with 2-periodic double chains (Si4O11), tremolite

  • Inosilicate, unbranched 3-periodic single chain of wollastonite

  • Inosilicate with 5-periodic single chain, rhodonite

  • Inosilicate with cyclic branched 8-periodic chain, pellyite

Phyllosilicates

Phyllosilicates (from Greek φύλλον phyllon, leaf), or sheet silicates, form parallel sheets of silicate tetrahedra with Si2O5 or a 2:5 ratio. The Nickel–Strunz classification is 09.E. All phyllosilicate minerals are hydrated, with either water or hydroxyl groups attached.

Kaolinite

Examples include:

  • Phyllosilicate, mica group, muscovite (red: Si, blue: O)

  • Phyllosilicate, single net of tetrahedra with 4-membered rings, apophyllite-(KF)-apophyllite-(KOH) series

  • Phyllosilicate, single tetrahedral nets of 6-membered rings, pyrosmalite-(Fe)-pyrosmalite-(Mn) series

  • Phyllosilicate, single tetrahedral nets of 6-membered rings, zeophyllite

  • Phyllosilicate, double nets with 4- and 6-membered rings, carletonite

Tectosilicates

Silica family (SiO2 3D network), β-quartz.
The 3D aluminosilicate anion of synthetic zeolite ZSM-5.
Quartz
Lunar ferroan anorthosite (plagioclase feldspar) collected by Apollo 16 astronauts from the Lunar Highlands near Descartes Crater

Tectosilicates, or "framework silicates," have a three-dimensional framework of silicate tetrahedra with SiO2 or a 1:2 ratio. This group comprises nearly 75% of the crust of the Earth.[6] Tectosilicates, with the exception of the quartz group, are aluminosilicates. The Nickel–Strunz classifications are 09.F and 09.G, 04.DA (Quartz/ silica family). Examples include:

See also

References

  1. ↑ "Mineral - Silicates". Archived from the original on 25 October 2017. https://web.archive.org/web/20171025133427/https://www.britannica.com/science/mineral-chemical-compound/Silicates. Retrieved 8 May 2018. 
  2. ↑ Deer, W.A.; Howie, R.A.; Zussman, J. (1992). An introduction to the rock-forming minerals (2nd ed.). London: Longman. ISBN 0-582-30094-0. 
  3. ↑ Hurlbut, Cornelius S.; Klein, Cornelis (1985). Manual of Mineralogy (20th ed.). Wiley. ISBN 0-47180580-7. https://archive.org/details/manualofmineralo00klei. 
  4. ↑ Deer, W.A.; Howie, R.A., & Zussman, J. (1992). An introduction to the rock forming minerals (2nd edition ed.). London: Longman ISBN:0-582-30094-0
  5. ↑ Hurlbut, Cornelius S.; Klein, Cornelis ||1985). Manual of Mineralogy, Wiley, (20th edition ed.). ISBN:0-471-80580-7
  6. ↑ Deer, W.A.; Howie, R.A.; Wise, W.S.; Zussman, J. (2004). Rock-forming minerals. Volume 4B. Framework silicates: silica minerals. Feldspathoids and the zeolites (2nd ed.). London: Geological Society of London. p. 982 pp. 

External links


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