Chemistry:Diphenylphosphite
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| Names | |
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| Preferred IUPAC name
Diphenyl phosphonate | |
| Other names
Phosphonic acid, diphenyl ester
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3D model (JSmol)
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| Properties | |
| C12H11O3P | |
| Molar mass | 234.191 g·mol−1 |
| Appearance | colorless liquid |
| Density | 1.2268 g/cm3 |
| Melting point | 12 °C (54 °F; 285 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
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Tracking categories (test):
Diphenylphosphite is a diorganophosphite with the formula (C6H5O)2P(O)H. The molecule is tetrahedral. It is a colorless viscous liquid. The compounds can be prepared by treating phosphorus trichloride with phenol. Many analogues can be prepared similarly. One illustrative reaction, diphenylphosphite, aldehydes, and amines react to afford aminophosphonates (Kabachnik–Fields reaction).[1]
See also
References
- ↑ Bhagat, Srikant; Chakraborti, Asit K. (2007). "An Extremely Efficient Three-Component Reaction of Aldehydes/Ketones, Amines, and Phosphites Kabachnik-Fields reaction for the Synthesis of α-Aminophosphonates Catalyzed by Magnesium Perchlorate". Journal of Organic Chemistry 72 (4): 1263–1270. doi:10.1021/jo062140i. PMID 17253748.
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