Chemistry:Ferroselite

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Short description: Iron selenide mineral
Ferroselite/ Dzharkenite
Ferroselite.jpg
Ferroselite found in Argentina
General
CategorySelenide mineral
Formula
(repeating unit)
FeSe2
Strunz classification2.EB.10a
Crystal systemOrthorhombic
Space groupPnnm (no. 58)
Identification
ColorSteel-gray to tin-white with a rose tint, brass yellow
Crystal habitAcicular prismatic
TwinningStellate and cruciform twins common
Mohs scale hardness6 - 6.5
|re|er}}Metallic
StreakBlack
Specific gravity7.20
Refractive indexOpaque
PleochroismDistinct
Solubilityinsoluble in water
References[1][2][3]

Orthorhombic ferroselite and its isometric polymorph dzharkenite are iron selenides of general formula FeSe2 precipitated under reducing conditions in anoxic environments. They are a source of selenium in the Rocky Mountains where selenium occurrence is associated with Upper Cretaceous shale deposits.

In the frame of safety assessment calculations made for deep disposal of high-level radioactive waste, ferroselite and dzharkenite are also considered in geochemical calculations as one of the mineral phases limiting the solubility of Selenium-79.[4]

Names

Dzharkenite's type locale is in the Suluchekinskoye Se-U deposit in the Dzharkenskaya Depression of the Middle Ili River, Almaty Province, in southeastern Kazakhstan. It was discovered in 1995 and named after the depression.

Ferroselite was first reported in 1955 for an occurrence in the Ust’-Uyuk uranium deposit in Tuva, Siberia.[1] Its name comes from the Latin ferro (iron) and "sel" for selenium.

See also

  • Coccolithophorid, a group of marine planktonic unicellular algae fixing selenium in Upper Cretaceous chalk and shale formations
  • Emiliania huxleyi, a major species of coccolithophorid active in selenium bioconcentration

External links

References