Chemistry:Fluoroanion

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In chemistry, a fluoroanion or fluorometallate anion is a polyatomic anion that contains one or more fluorine atoms. The ions and salts form from them are also known as complex fluorides. They can occur in salts, or in solution, but seldom as pure acids. Fluoroanions often contain elements in higher oxidation states. They mostly can be considered as fluorometallates, which are a subclass of halometallates.[1][2] However some fluoroanions contain non-metals.

Anions that contain both fluorine and oxygen can be called "oxofluoroanions"[3] (or rarely "fluorooxoanions").[4]

List of fluoroanions

Template:No sources section The following is a list of fluoroanions in atomic number order.

  • trifluoroberyllate[5]
  • tetrafluoroberyllate[6]
  • tetrafluoroborate[7]
  • magnesium tetrafluoride
  • trifluoroaluminate AlOF2−
    3
  • tetrafluoroaluminate
  • pentafluoroaluminate
  • hexafluoroaluminate (fluoroaluminate)[8]
  • heptafluoroaluminate
  • hexafluorosilicate[9]
  • hexafluorophosphate[10]
  • Sulfur trifluoride anion
  • pentafluorosulfate(IV) aka pentafluorosulfite or Sulfur pentafluoride ion or sulfur pentafluoride anion [SF5]− gives off SF4 vapour.[11]
  • tetrafluorochlorate[12]
  • trifluoroscandate(II)?
  • tetrafluoroscandate?
  • hexafluoroscandate[13]
  • pentafluorotitanite [TiF5]2−[14]
  • hexafluorotitanite [TiF6]3−[14]
  • hexafluorotitanate [TiF6]2−[14]
  • tetrafluorovanadate(III)[15]
  • pentafluorovanadate(III)[15]
  • hexafluorovanadate(III)[15]
  • hexafluorovanadate(IV)[16]
  • hexafluorovanadate(V)[16] unstable in water
  • hexafluorochromite [CrF6]3−[17]
  • hexafluorochromate [CrF6]2−[17]
  • trifluoromanganate MnF−
    3
  • hexafluoromanganate(III)
  • hexafluoromanganate(IV)
  • heptafluoromanganate IV
  • Tetrafluoroferrate 1− and 2−
  • hexafluoroferrate 4− and 3−
  • tetrafluorocobaltate II
  • Hexafluorocobaltate III and IV[18]
  • Heptafluorocobaltate IV[18]
  • Tetrafluoronickelate
  • Hexafluoronickelate II, III and IV
  • hexafluorocuprate
  • tetrafluorozincate
  • Hexafluorogallate[19]
  • hexafluorogermanate[20]
  • hexafluoroarsenate[21]
  • tetrafluorobromate
  • hexafluorobromate
  • tetrafluoroyttrate
  • pentafluorozirconate ZrF−
    5
  • hexafluorozirconate ZrF2−
    6    [14]
  • heptafluorozirconate ZrF3−
    7    [14]
  • octafluorozirconate ZrF4−
    8
  • hexafluoroniobate NbF−
    6    [22]
  • heptafluoroniobate NbF2−
    7    [22]
  • octafluoromolybdate MoF2−
    8
  • tetrafluoropalladate
  • hexafluororhodate
  • hexafluororuthenate(IV)
  • hexafluororuthenate(V)
  • trifluoroargentate(I)
  • hexafluoroindate[23]
  • hexafluorostannate[24]
  • fluoroantimonate[21]
  • hexafluoroiodate 1−
  • octafluoroxenate
  • tetrafluorolanthanate LaF−
    4
  • pentafluorocerate IV
  • Hexafluorocerate IV[25][26]
  • Heptafluorocerate IV[25]
  • octafluorocerate IV[25]
  • pentafluorohafnate
  • hexafluorohafnate[26]
  • heptafluorotantalate TaF2−
    7    [22]
  • octafluorotantalate
  • heptafluorotungstate
  • octafluorotungstate WF2−
    8
  • octafluororhenate
  • hexafluoroplatinate
  • tetrafluoroaurate AuF−
    4
  • hexafluoroaurate AuF−
    6
  • trifluorothallate(I)
  • tetrafluorothallate(I)
  • tetrafluorothallate(III)[27]
  • hexafluorothallate(III)
  • tetrafluorobismuthate BiF−
    4
  • hexafluorobismuthate
  • hexafluorothorate
  • heptafluoroprotactinate(V)[22]
  • octafluoroprotactinate(V)
  • hexafluorouranate(IV)[26]
  • hexafluorouranate(V)[28]
  • heptafluorouranate(VI)
  • octafluorouranate(IV)
  • octafluorouranate(V)
  • octafluorouranate(VI)
  • hexafluoroneptunate(IV)[29]
  • hexafluoroneptunate(V)
  • hexafluoroneptunate(VII)[30]
  • heptafluoroneptunate(V)
  • heptafluoroneptunate(VI)
  • octafluoroneptunate(V)
  • hexafluoroplutonate(IV)[29]
  • hexafluoroplutonate(V)

References

  1. ↑ "fluorometallate anion (CHEBI:51527)". https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI%3A51527. 
  2. ↑ "fluorometallate anion - Ontology Browser - Rat Genome Database". https://rgd.mcw.edu/rgdweb/ontology/view.html?acc_id=CHEBI:51527. 
  3. ↑ Jones, Peter J.; Levason, William; Tajik, Mahmoud (June 1984). "Coordination chemistry of higher oxidation states. 10 [1]. Oxofluoroanions of osmium(VIII) [OsO4F2]2− and [OsO3F3]−". Journal of Fluorine Chemistry 25 (2): 195–201. doi:10.1016/S0022-1139(00)80948-3. 
  4. ↑ Hilbers, Martin; Leimkühler, Manfred; Mattes, Rainer (1 April 1989). "Zwei-und dreikernige Fluorooxoanionen des Vanadins. Kristallstrukturen von Cs(NMe 4 )[V 2 O 2 F 8 (H 2 O)] und (Na,K)(NMe 4 ) 2 [V 3 O 3 F 1 2] / Di- and Trinuclear Fluorooxoanions of Vanadium. Crystal Structures of Cs(NMe 4 )[VO 2 F 8 (H 2 O)] and (Na,K)(NMe 4 ) 2 [V 3 O 3 F 12 ]". Zeitschrift für Naturforschung B 44 (4): 383–388. doi:10.1515/znb-1989-0403. 
  5. ↑ (in en) Beryllium: sect. 1. Coordination compounds 1. Springer-Verlag. 1996. p. 454. ISBN 978-0-387-93741-0. https://books.google.com/books?id=wf4uAQAAIAAJ&q=trifluoroberyllate. 
  6. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. pp. 4–5. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&dq=tetrafluoroberyllate&pg=PA5. 
  7. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. pp. 7–8. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&dq=tetrafluoroberyllate&pg=PA5. 
  8. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. pp. 9–10. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA9. 
  9. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 12. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA12. 
  10. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 18. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA18. 
  11. ↑ Tunder, R.; Siegel, B. (September 1963). "The SF5 anion". Journal of Inorganic and Nuclear Chemistry 25 (9): 1097–1098. doi:10.1016/0022-1902(63)80128-1. 
  12. ↑ Christe, Karl O.; Guertin, Jacques P. (1966). "Structure of the Tetrafluorochlorate(III) Anion, CLF4". Inorganic Chemistry 5 (3): 473–476. doi:10.1021/ic50037a031. 
  13. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 11. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA11. 
  14. ↑ 14.0 14.1 14.2 14.3 14.4 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 15. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA15. 
  15. ↑ 15.0 15.1 15.2 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 20. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA20. 
  16. ↑ 16.0 16.1 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 21. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA21. 
  17. ↑ 17.0 17.1 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 22. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA22. 
  18. ↑ 18.0 18.1 Klemm, W.; Brandt, W.; Hoppe, R. (March 1961). "Über Fluorocobaltate(III) und -(IV) und Fluoroniccolate(III)". Zeitschrift für anorganische und allgemeine Chemie 308 (1–6): 179–189. doi:10.1002/zaac.19613080119. Bibcode: 1961ZAACh.308..179K. 
  19. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 10. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA10. 
  20. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 13. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA13. 
  21. ↑ 21.0 21.1 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 19. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA19. 
  22. ↑ 22.0 22.1 22.2 22.3 Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 22. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA22. 
  23. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 10. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA10. 
  24. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 13. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&pg=PA13. 
  25. ↑ 25.0 25.1 25.2 Macintyre, Jane E. (1992) (in en). Dictionary of Inorganic Compounds. CRC Press. p. 2819. ISBN 9780412301209. https://books.google.com/books?id=9eJvoNCSCRMC&pg=PA2819. 
  26. ↑ 26.0 26.1 26.2 Tetraethylammonium Hexafluoro Uranate(IV), Hafnate(IV), and Cerate(IV) Salts: Preparation and Solid-state Structure
  27. ↑ Simons, J. H. (2 December 2012) (in en). Fluorine Chemistry V2. Elsevier. p. 10. ISBN 978-0-323-14543-5. https://books.google.com/books?id=ott67ONZPKwC&dq=tetrafluoroberyllate&pg=PA10. 
  28. ↑ Nitrosylium Hexafluorouranate (NOUF6) and Its Derivatives
  29. ↑ 29.0 29.1 ChemInform Abstract: Reactions of Hexafluorides of Uranium, Neptunium, and Plutonium with Nitrogen Oxides and Oxyfluorides. Synthesis and Characterization of (NO)[NpF6 and (NO)[PuF6]]
  30. ↑ [https://www.academia.edu/13781200/Understanding_Structure_and_Bonding_in_Early_Actinide_6d_0_5f_0_MX_6_q_M_Th_Np_X_H_F_Complexes_in_Comparison_with_Their_Transition_Metal_5d_0_Analogues#:~:text=Abstract,to%20the%20transition%20metal%20systems. Understanding Structure and Bonding in Early Actinide 6d 0 5f 0 MX 6 q (M ) Th-Np; X ) H, F) Complexes in Comparison with Their Transition Metal 5d 0 Analogues]



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