Chemistry:Hercynite
From HandWiki
| Hercynite | |
|---|---|
 | |
| General | |
| Category | Oxide minerals Spinel group Spinel structural group |
| Formula (repeating unit) | Fe2+Al2O4 |
| Strunz classification | 4.BB.05 |
| Crystal system | Isometric |
| Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
| Space group | Fd3m (no. 227) |
| Identification | |
| Formula mass | 173.81 g/mol |
| Color | Black |
| Crystal habit | Euhedral crystals. Also massive to granular |
| Cleavage | [111] indistinct |
| Fracture | Uneven – flat surfaces (not cleavage) fractured in an uneven pattern. |
| Mohs scale hardness | 7.5 |
| |re|er}} | Vitreous (glassy) |
| Streak | dark green |
| Specific gravity | 3.95 |
| Optical properties | Isotropic |
| Refractive index | n = 1.8 |
| Other characteristics | non-radioactive |
| References | [1][2][3] |
Hercynite is a spinel mineral with the formula FeAl2O4.
It occurs in high-grade metamorphosed iron-rich argillaceous (clay-containing) sediments as well as in mafic and ultramafic igneous rocks. Due to its hardness it also is found in placers.[1]
It was first described in 1847 and its name originates from the Latin name for the Harz, Silva Hercynia, where the species was first found.[1][2]
Hercynite is a spinel of regular symmetry and normal cation distribution, but some disorder occurs in its structure. It consists of ferrous (Fe2+) ions and aluminium ions (Al3+); however some ferric ions (Fe3+) may be located in the structure of hercynite.[5]
Melting point of this mineral is between 1,692–1,767 °C (3,078–3,213 °F).[6]
References
- ↑ 1.0 1.1 1.2 "Handbook of Mineralogy". http://www.handbookofmineralogy.com/pdfs/hercynite.pdf.
- ↑ 2.0 2.1 Webmineral
- ↑ Mindat
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Jastrzębska, Ilona; Szczerba J.; Stoch P.; Błachowski A.; Ruebenbauer K.; Prorok R.; Snieżek E. (2015). "Crystal structure and Mössbauer study of FeAl2O4". Nukleonika-Journal of Nuclear Research (Institute of Nuclear Chemistry and Technology) 60 (1): 47–49. doi:10.1515/nuka-2015-0012.
- ↑ Agca, Can; Neuefeind, Jörg C.; McMurray, Jake W.; Weber, Richard; Navrotsky, Alexandra (2020-06-07). "Melting temperature measurement of refractory oxide ceramics as a function of oxygen fugacity using containerless methods". Journal of the American Ceramic Society 103 (9): 4867–4875. doi:10.1111/jace.17216. ISSN 0002-7820. http://dx.doi.org/10.1111/jace.17216.
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