Chemistry:Hornblende
| Hornblende | |
|---|---|
-Hornblende-38354.jpg) Hornblende crystal (dark green) about 35 mm long, with apatite (white) | |
| General | |
| Category | Silicate mineral |
| Formula (repeating unit) | Ca 2(Mg,Fe,Al) 5(Al,Si) 8O 22(OH) 2 |
| Crystal system | Monoclinic |
| Space group | C2/m |
| Identification | |
| Color | Black to dark green or brown |
| Crystal habit | Hexagonal/granular |
| Cleavage | Imperfect at 56° and 124° |
| Fracture | Uneven |
| Mohs scale hardness | 5–6 |
| |re|er}} | Vitreous to dull |
| Streak | Pale gray, gray-white,[1][2] white, colorless[3] |
| Specific gravity | 2.9 |
| Pleochroism | Strong |
| References | [4] |
Hornblende is a complex inosilicate series of minerals.[6] It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.
The general formula is (Ca,Na)
2-3(Mg,Fe,Al)
5(Al,Si)
8O
22(OH,F)
2.
Physical properties
Hornblende has a hardness of 5–6, a specific gravity of 3.0 to 3.6, and is typically an opaque green, dark green, brown, or black color. It tends to form slender prismatic to bladed crystals, diamond-shaped in cross-section, or is present as irregular grains or fibrous masses.[7]
Its planes of cleavage intersect at 56° and 124° angles. Hornblende is most often confused with the pyroxene series and biotite mica, which are also dark minerals found in granite and charnockite. Pyroxenes differ in their cleavage planes, which intersect at 87° and 93°.[8]
Hornblende is an inosilicate (chain silicate) mineral, built around double chains of silica tetrahedra. These chains extend the length of the crystal and are bonded to their neighbors by additional metal ions to form the complete crystal structure.[9]
Compositional variances
Hornblende is part of the calcium-amphibole group of amphibole minerals.[10] It is highly variable in composition, and includes at least five solid solution series:
- Magnesiohornblende-ferrohornblende, Ca
2[(Mg,Fe)
4Al]Si
7AlO
22(OH)
2 - Tschermakite-ferrotschermakite, Ca
2[(Mg,Fe)
3Al
2]Si
6Al
2O
22(OH)
2 - Edenite-ferroedenite, NaCa
2(Mg,Fe)
5Si
7AlO
22(OH)
2 - Pargasite-ferropargasite, NaCa
2[(Mg,Fe)
4Al]Si
6Al
2O
22(OH)
2 - Magnesiohastingstite-hastingsite, NaCa
2[(Mg,Fe)
4Fe3+
]Si
6Al
2O
22(OH)
2
In addition, titanium, manganese, or chromium can substitute for some of the cations and oxygen, fluorine, or chlorine for some of the hydroxide (OH). The different chemical types are almost impossible to distinguish even by optical or X-ray methods, and detailed chemical analysis using an electron microprobe is required.[11]
There is a solid solution series between hornblende and the closely related amphibole minerals, tremolite-actinolite, at elevated temperature. A miscibility gap exists at lower temperatures, and, as a result, hornblende often contains exsolution lamellae of grunerite.[12]
Occurrence
Hornblende is a common constituent of many igneous and metamorphic rocks such as granite, syenite, diorite, gabbro, basalt, andesite, gneiss, and schist. It crystallizes in preference to pyroxene minerals from cooler magma that is richer in silica and water.[13]
It is the principal mineral of amphibolites, which form during medium- to high-grade metamorphism of mafic to intermediate igneous rock (igneous rocks with relative low silica content) in the presence of pore water. Much of the pore water comes from the breakdown of micas or other hydrous minerals. However, hornblende itself breaks down at very high temperatures.[13] Hornblende alters easily to chlorite, biotite, or other mafic minerals.[14]
A rare variety of hornblende contains less than 5% of iron oxide, is gray to white in color, and is named edenite from its locality in Edenville, Orange County, New York.
Oxyhornblende is a variety in which most of the iron has been oxidized to the ferric state, Fe+3
. Charge balance is preserved by the substitution of oxygen ions for hydroxide. Oxyhornblende is also typically enriched in titanium. It is found almost exclusively in volcanic rock and is sometimes called basaltic hornblende.[15][16]
Etymology
The word hornblende is derived from German Horn ('horn') and blende ('deceive'), in allusion to its similar appearance to metal-bearing ore minerals.[17]
See also
References
- ↑ Ferrohornblende, MinDat.org, http://www.mindat.org/show.php?id=1519
- ↑ Magnesiohornblende, MinDat.org, http://www.mindat.org/show.php?id=2524.html
- ↑ "Hornblende Mineral | Uses and Properties". https://geology.com/minerals/hornblende.shtml.
- ↑ Phillips, M.W.; Draheim, J.E.; Popp, R.K.; Clowe, C.A.; Pinkerton, A.A. (1989). "Effects of oxidation-dehydrogenation in tschermakitic hornblende". American Mineralogist 74: 764–773. https://pubs.geoscienceworld.org/msa/ammin/article-abstract/74/7-8/764/42278/Effects-of-oxidation-dehydrogenation-in?redirectedFrom=fulltext. Retrieved 30 December 2020.
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Hornblende Root Name Group, MinDat.org, http://www.mindat.org/show.php?id=8789.html
- ↑ Nesse, William D. (2000). Introduction to mineralogy. New York: Oxford University Press. pp. 285–286. ISBN 9780195106916.
- ↑ Pough, Frederick H. (1976). A Field Guide To Rocks and Minerals (4 ed.). Boston: Houghton Mifflin. p. 249.
- ↑ Nesse 2000, p. 277–279.
- ↑ Nesse 2000, p. 278.
- ↑ Nesse 2000, p. 285.
- ↑ Klein, Cornelis; Hurlbut, Cornelius S. Jr. (1993). Manual of mineralogy : (after James D. Dana) (21st ed.). New York: Wiley. pp. 496–497. ISBN 047157452X.
- ↑ 13.0 13.1 Nesse 2000, p. 279.
- ↑ Nesse 2000, p. 286.
- ↑ Jackson, Julia A., ed (1997). "basaltic hornblende". Glossary of geology. (Fourth ed.). Alexandria, Virginia: American Geological Institute. ISBN 0922152349.
- ↑ Nesse 2000, p. 285–286.
- ↑ Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Ferrohornblende". Mineral Data Publishing. http://www.handbookofmineralogy.org/pdfs/ferrohornblende.pdf.
de:Amphibolgruppe#Calcium-Amphibole
 |  |
