Chemistry:Humboldtine
| Humboldtine | |
|---|---|
 | |
| General | |
| Category | Mineral |
| Formula (repeating unit) | FeC2O4·2H2O |
| Crystal system | Monoclinic |
| Identification | |
| Color | Yellow to amber-yellow |
| Cleavage | Perfect on {110}, imperfect on {100} and {010} |
| Mohs scale hardness | 1.5 to 2 |
| |re|er}} | Resinous to dull |
| Streak | Pale yellow |
| Diaphaneity | Transparent to opaque |
| Density | 2.28 g/cm3 (measured) 2.307 g/cm3 (calculated) |
| Refractive index | nα = 1.494 nβ = 1.561 nγ = 1.692 |
Humboldtine is a rarely occurring mineral from the mineral class of "organic compounds" with the chemical composition FeC2O4•2H2O and is therefore a water-containing iron(II) oxalate or the iron salt of oxalic acid.[2]
Humboldtine crystallizes in the monoclinic crystal system, but only rarely develops well-formed, tabular to prismatic crystals with a resin-like sheen on the surfaces. It is mostly found in the form of botryoidal or fibrous to earthy aggregates and crusty coatings from dull yellow to brownish yellow or amber yellow in color. It can be transparent to opaque.[3] It can form from hematite in oxalic acid.[4]
With a Mohs hardness of 1.5 to 2, humboldtine is one of the softest minerals and can be scratched with a fingernail.
Etymology and history
Humboldtine was first discovered by August Breithaupt in a weathered brown coal deposit near the municipality of Korozluky in Okres Most in the Czech Republic and described in 1821 by Mariano Eduardo de Rivero y Ustariz (1798-1857),[5] who named the mineral after the German naturalist Alexander von Humboldt.
The mineral was already known and characterized when the IMA was founded (1959). Accordingly, humboldtine is listed as an officially recognized mineral.
Occurence
The mineral is known to be found in 30 localities, including Germany, Brazil, the U.K. and Canada.
In 2023, during the digitization of the archive of the LfU, a 75 year old letter from a coal mine owner written in 1949 was found. It mentioned that mineral was found in coal mine near the town of Schwandorf. Analysis of the mineral was done which confirmed the discovery. The discovery doubled the amount of Humboldtine known so far.[6]
Crystal structure
Humboldtine crystallizes monoclinically in the space group C2/c (space group no. 15) with the lattice parameters a = 12.011 Å; b = 5.557 Å; c = 9.920 Å and β = 128.53°, with four formula units per unit cell.
Uses
It is an important synthetic intermediate and also a key building block for the preparation of various advanced materials.[7]
References
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Frost, R.L.; Weier, Matt L. (2004). "Thermal decomposition of humboldtine –a high resolution thermogravimetric and hot stage Raman spectroscopic study". https://eprints.qut.edu.au/838/1/Raman_spectroscopy_of_humboldtine_JTAC_revised_43.pdf.
- ↑ "Humboldtine". https://www.mindat.org/min-1946.html.
- ↑ Vehmaanperä, Paula; Gong, Bo; Sit, Patrick H.-L.; Barbiellini, Bernardo; Salmimies, Riina; Häkkinen, Antti (2021). "Formation of Humboldtine During the Dissolution of Hematite in Oxalic Acid – Density Functional Theory (DFT) Calculations and Experimental Verification". Clays and Clay Minerals 69 (6): 655–662. doi:10.1007/s42860-021-00146-5.
- ↑ de Rivero, Mariano (1821). "Note sur une combinaison de l'acide oxalique avec le fer trouvé à Kolowserux, près Belin en Bohéme". Annales de Chimie et de Physique 18: 207–210.
- ↑ Bressan, David. "One Of Earth's Rarest Minerals Found Thanks To A 75-Year-Old Letter" (in en). https://www.forbes.com/sites/davidbressan/2024/01/19/one-of-the-rarest-minerals-on-earth-found-thanks-to-a-75-year-old-letter/.
- ↑ "Iron(II)oxalate Dihydrate—Humboldtine: Synthesis, Spectroscopic and Structural Properties of a Versatile Precursor for High Pressure Research". https://www.mdpi.com/2075-163X/11/2/113.
 |  |
