Chemistry:Hydrotelluride

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A hydrotelluride or tellanide is an ion or a chemical compound containing the [HTe]− anion which has a hydrogen atom connected to a tellurium atom. HTe is a pseudohalogen. Organic compounds containing the -TeH group are called tellurols. "Tellanide" is the proper name according to the International Union of Pure and Applied Chemistry's Red Book, but hydrogen(tellanide)(1−) is also listed. "Tellanido" as a ligand is not named in the Red Book itself,[1] but "tellanido" and "hydrogentellurido" are listed in the contemporaneous Principles of Chemical Nomenclature:A Guide to IUPAC Recommendations.[2] For the group -HTe or radical HTe• the term tellanyl is used.[1]

Hydrotellurides are usually unstable at room temperature.[3]

List

formula system space group unit cell Å volume density comment reference
ammonium hydrotelluride

Decomposes at room temperature over a fortnight; 116c.

NH4TeH at 25 °C pressure = 22.7 mmHg, decomposing to H3N and H2Te then to Te and H2 [4]
ethylmethylimidazolinium hydrotelluride [(C2H5)(CH3)C3N2H2]+TeH− [3]
N-butyl-N-methylpyrollidinium hydrotelluride [(C4H9)(CH3)C4NH8]+TeH− decompose at room temperature over a fortnight;

decompose 116 °C

[3]
sodium hydrotelluride NaTeH [5]
tri-n-butyl-methylphosphonium hydrotelluride [(C4H9)3(CH3)P]+TeH− red; decompose 163 °C [3]
tetraphenylphosphonium hydrotelluride Ph4PTeH [6]
[(C5H5)Co]2(μ-P(CH3)2)2(μ-TeH)•PF6 red-brown [7]
Na[(CO)5Cr(TeH)] [8][9]
[(Ph3P)2N]+[(CO)5Cr(TeH)]− [9]
[(Ph3P)2N]+[(CO)5Cr(TeH)Cr(CO)5]− [8][9]
[CpCr(CO)3]2(μ-TeH) [8]
[(CO)4Mn(TeH)]2 [8][10]
Cp*=C5Me5 Cp*2Zr(TeH){η1-OC(Ph)=CH2} [8]
(t-BuC5H4)2Nb(η2-Te2)H dark orange [11]
(η-C5H4Me)Ru(PPh3)2(TeH) [12]
(CH2CH2PPh2)3PRhTeH hexagonal P63 a=13.542 c=12.346 Z=2 cherry red; decomposed by light [13][6]
(CH2CH2PPh2)3PRh(TeH)(H)CF3SO3 [13]
(MeCp)2Ta(TeH)CO [14]
(MeCp)2Ta(TeH) (η2-COTe) [14]
Na[(CO)5W(TeH)] [8][9]
Ph4As[(CO)5W(TeH)] [9]
Ph4As[(CO)5W(TeH)W(CO)5] [8][9]
Cp*Re(CO)2(H)(TeH) monoclinic P21/m a=7.467 b=13.208 c=7.570 β=99.48° Z=2 2.287 red-brown
(AdArO)3N3− = tris(2-hydroxy-3-adamantyl-5-methylbenzyl)amine) [((AdArO)3N)U(CH3OC2H4OCH3)(TeH)] stable to 80 °C; U–Te bond length 3.122 Å [15]
{((AdArO)3N)U}2(μ-TeH)2 [15]

References

  1. ↑ 1.0 1.1 Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005. p. 304. https://iupac.qmul.ac.uk/bibliog/RedBook2005.pdf. 
  2. ↑ Leigh, G. J.; Favre, H. A.; Metanomski, W. W. (1998). Principles of Chemical Nomenclature: A Guide to IUPAC Recoomendations. Table 4.6. https://old.iupac.org/publications/books/principles/principles_of_nomenclature.pdf. 
  3. ↑ 3.0 3.1 3.2 3.3 Finger, Lars H.; Sundermeyer, Jörg (2016-03-14). "Halide-Free Synthesis of Hydrochalcogenide Ionic Liquids of the Type [Cation[HE] (E=S, Se, Te)"] (in en). Chemistry – A European Journal 22 (12): 4218–4230. doi:10.1002/chem.201504577. ISSN 0947-6539. PMID 26879604. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201504577. 
  4. ↑ Mikus, F. F.; Carlyon, S. J. (May 1950). "The Equilibrium between Ammonia and Hydrogen Telluride 1" (in en). Journal of the American Chemical Society 72 (5): 2295–2296. doi:10.1021/ja01161a522. ISSN 0002-7863. Bibcode: 1950JAChS..72.2295M. https://pubs.acs.org/doi/abs/10.1021/ja01161a522. 
  5. ↑ "The Structure of Yttrium Hydride Telluride YHTe from Single-Crystal X-Ray Diffraction Data". Joint Polish-German Crystallographic Meeting, February 24–27, 2020, Wrocław, Poland: 64–65. 24 February 2020. doi:10.1515/9783110692914-002. 
  6. ↑ 6.0 6.1 Roof, Lisa C.; Kolis, Joseph W. (1993-05-01). "New developments in the coordination chemistry of inorganic selenide and telluride ligands" (in en). Chemical Reviews 93 (3): 1037–1080. doi:10.1021/cr00019a010. ISSN 0009-2665. https://pubs.acs.org/doi/abs/10.1021/cr00019a010. 
  7. ↑ Hofmann, Werner; Werner, Helmut (December 1981). "Electrophilic Addition of a Sulfur, Selenium, and Tellurium Atom as well as of an SO 2 Molecule to a Metal-Metal Bond" (in en). Angewandte Chemie International Edition in English 20 (12): 1014–1016. doi:10.1002/anie.198110142. ISSN 0570-0833. https://onlinelibrary.wiley.com/doi/10.1002/anie.198110142. 
  8. ↑ 8.0 8.1 8.2 8.3 8.4 8.5 8.6 Howard, William A.; Parkin, Gerard (January 1994). "Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths" (in en). Journal of the American Chemical Society 116 (2): 606–615. doi:10.1021/ja00081a022. ISSN 0002-7863. Bibcode: 1994JAChS.116..606H. https://pubs.acs.org/doi/abs/10.1021/ja00081a022. 
  9. ↑ 9.0 9.1 9.2 9.3 9.4 9.5 Hausmann, Heinz; Höfler, Mathias; Kruck, Thomas; Zimmermann, Heinz Willi (March 1981). "Chalkogenide als Komplexliganden, I. Carbonyl-Hydrogenchalkogenid-Komplexe von Chrom, Molybdän und Wolfram" (in en). Chemische Berichte 114 (3): 975–981. doi:10.1002/cber.19811140315. ISSN 0009-2940. https://onlinelibrary.wiley.com/doi/10.1002/cber.19811140315. 
  10. ↑ Küllmer, Volker; Vahrenkamp, Heinrich (January 1977). "Selen- und Tellur-verbrückte Carbonylkomplexe des Mangans und Rheniums" (in en). Chemische Berichte 110 (1): 228–236. doi:10.1002/cber.19771100122. ISSN 0009-2940. https://onlinelibrary.wiley.com/doi/10.1002/cber.19771100122. 
  11. ↑ Ebner, Alexander; Meier, Walter; Mugnier, Yves; Wachter, Joachim (July 2007). "Investigation into the reaction of (t-BuC5H4)2Nb(η2-Te2)H with CH3Li: Hydride abstraction versus telluride methylation" (in en). Inorganica Chimica Acta 360 (10): 3330–3334. doi:10.1016/j.ica.2007.03.060. https://linkinghub.elsevier.com/retrieve/pii/S0020169307002162. 
  12. ↑ Schriver, D. F.; Bruce, M. I. (2002-09-10) (in en). Comprehensive Organometallic Chemistry II, Volume 7: Iron, Ruthenium and Osmium: A Review of the Literature 1982-1994. Elsevier. pp. 883. ISBN 978-0-08-096396-9. https://books.google.com/books?id=3kWmDAAAQBAJ&pg=PA883. 
  13. ↑ 13.0 13.1 Di Vaira, Massimo; Peruzzini, Maurizio; Stoppioni, Piero (March 1991). "Hydrochalcogenide and hydride hydrochalcogenide derivatives of rhodium" (in en). Inorganic Chemistry 30 (5): 1001–1007. doi:10.1021/ic00005a024. ISSN 0020-1669. https://pubs.acs.org/doi/abs/10.1021/ic00005a024. 
  14. ↑ 14.0 14.1 Winkler, Uwe; Khan, Masood A.; Nicholas, Kenneth M. (August 1998). "Atom addition and insertion reactions of (MeCp)2Ta(H)CO with sulfur, tellurium, carbonyl sulfide and carbon disulfide" (in en). Inorganic Chemistry Communications 1 (8): 317–319. doi:10.1016/S1387-7003(98)00085-9. https://linkinghub.elsevier.com/retrieve/pii/S1387700398000859. 
  15. ↑ 15.0 15.1 Franke, Sebastian M.; Rosenzweig, Michael W.; Heinemann, Frank W.; Meyer, Karsten (2015). "Reactivity of uranium( iii ) with H 2 E (E = S, Se, Te): synthesis of a series of mononuclear and dinuclear uranium( iv ) hydrochalcogenido complexes" (in en). Chemical Science 6 (1): 275–282. doi:10.1039/C4SC02602K. ISSN 2041-6520. PMID 29560170. 



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