Chemistry:Isopropyl fluoride
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| Names | |
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| Systematic IUPAC name
2-Fluoropropane | |
| Other names
HFC-281ea
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| Properties | |
| C3H7F | |
| Molar mass | 62.087 g·mol−1 |
| Boiling point | −10 °C (14 °F; 263 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Isopropyl fluoride (systematic name 2-fluoropropane) is an organofluorine compound consisting of a propane with a fluorine as substituent on the middle carbon.
This chemical reacts with boron trifluoride to form an ionic complex containing a carbocation[1] that can be used as a catalyst for isomerization and disproportionation of alkanes.[2] Isopropyl fluoride can be synthesized by hydrohalogenation of propene or by substitution of isopropyl alcohol using standard fluorination reagents such as hydrogen fluoride–pyridine.[3] As a refrigerant, it is in the hydrofluorocarbon class, identified as HFC-281ea.[4] It has an atmospheric lifetime of 27 days.[5]
References
- ↑ Olah, George A.; Prakash, G. K. Surya; Molnár, Árpád; Sommer, Jean (2009). Superacid Chemistry (2nd ed.). Wiley. pp. 84–85. ISBN 978-0-471-59668-4.
- ↑ Schneider, Abraham; Kennedy, Robert M. (1951). "Reactions of Hydrocarbons Induced by Alkyl Fluoride—Boron Trifluoride. I. Isomerization of Isoparaffins". Journal of the American Chemical Society 73 (11): 5013–5016. doi:10.1021/ja01155a001. Bibcode: 1951JAChS..73.5013S.
- ↑ Olah, George A.; Watkins, Michael (1978). "Fluorinations with Pyriginium Polyhydrogen Fluoride Reagent: 1-Fluoroadamantane". Organic Syntheses 58: 75. http://www.orgsyn.org/demo.aspx?prep=cv6p0628.
- ↑ "Hydrofluorocarbon Consumption Survey (HCS) questionnaire under Statistics Act Reporting Guide". National Environmental Agency (NEA) & Energy Studies Institute (ESI). March 2020. https://www.nea.gov.sg/docs/default-source/cmd-documents/climate-change/hcs--reporting-guide.pdf.
- ↑ "Chapter 2: hydrofluoroCarbons (HFCs)". WMO (World Meteorological Organization), Scientific Assessment of Ozone Depletion: 2018, Global Ozone Research and Monitoring Project – Report No. 58. 2018. https://csl.noaa.gov/assessments/ozone/2018/downloads/Chapter2_2018OzoneAssessment.pdf.
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