Chemistry:Johnbaumite

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Johnbaumite
RM2040-roweita-johnbaumita-andradita.jpg
General
CategoryApatite group
Formula
(repeating unit)
Ca5(AsO4)3OH
Strunz classification08.BN.05
Dana classification41.08.03.03
Crystal systemHexagonal
Crystal classDipyramidal (8/m)
Space groupP63/m
Identification
ColourGreyish white to colourless
Crystal habitAnhedral grains, granular minerals without the expression of crystal shapes and massive, uniformly indistinguishable crystals forming large masses.
CleavageDistinct {1010}
FractureIrregular/Uneven
TenacityBrittle
Mohs scale hardness≈ 4.5
|re|er}}Adamantine to greasy on fracture surfaces, vitreous on cleavage surfaces
StreakWhite
DiaphaneityTransparent
Density3.65 – 3.73 g/cm3
Optical propertiesUniaxial (−)
Refractive indexnω = 1.687 nε = 1.684
Birefringence0.003
PleochroismNon-pleochroic
ExtinctionParallel
References[1] [2]

Johnbaumite is a calcium arsenate hydroxide mineral. It was first described in 1980, where it appeared in Franklin Township, Somerset County, New Jersey.[4] Johnbaumite was discovered at Harstigen mine in Sweden in the 19th century, but it was described as svabite.[5]

Etymology

It is named after geologist John Leach Baum (March 15, 1916 – October 16, 2011), who found the original specimen in 1944. He was a significant contributor to the geology and mineralogy of the Franklin deposit, and the Curator Emeritus at the Franklin Mineral Museum.

See also

References

  1. "Johnbaumite". http://webmineral.com/data/Johnbaumite.shtml. 
  2. "Johnbaumite". https://www.mindat.org/min-2105.html. 
  3. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  4. Pete J. Dunn, Donald R. Peacor, Nancy Newberry; Johnbaumite, a new member of the apatite group from Franklin, New Jersey. American Mineralogist 1980;; 65 (11–12): 1143–1145. doi:
  5. Cristian Biagioni, Marco Pasero; The crystal structure of johnbaumite, Ca5(AsO4)3OH, the arsenate analogue of hydroxylapatite. American Mineralogist 2013;; 98 (8–9): 1580–1584. doi: https://doi.org/10.2138/am.2013.4443

Further reading

  • Biagioni C, Bosi F, Hålenius U, Pasero M (2017) The crystal structure of turneaureite, Ca5(AsO4)3Cl, the arsenate analog of chlorapatite, and its relationships with the arsenate apatites johnbaumite and svabite, American Mineralogist, 102, 1981–1986
  • Lee Y J, Stephens P W, Tang Y, Li W, Phillips B L, Parise J B, Reeder R J (2009) Arsenate substitution in hydroxylapatite: Structural characterization of the Ca5(PxAs1-xO4)3OH solid solution, American Mineralogist, 94, 666–675
  • Zheng Y, Gao T, Gong Y, Ma S, Yang M, Chen P (2015) Electronic, vibrational and thermodynamic properties of Ca10(AsO4)6(OH)2: first principles study, The European Physical Journal of Applied Physics, 72, 1–7
  • Anthony J W, Bideaux R A, Bladh K W, and Nichols M C (1990) Handbook of Mineralogy, Mineral Data Publishing, Tucson Arizona, USA, by permission of the Mineralogical Society of America.