Chemistry:Lanthanum cobaltite

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Lanthanum cobaltite
Names
Other names
Lanthanum cobalt oxide
Identifiers
3D model (JSmol)
EC Number
  • 807-340-6
Properties
CoLaO3
Molar mass 245.836 g·mol−1
Hazards
GHS pictograms GHS07: HarmfulGHS08: Health hazard
GHS Signal word Warning
H319, H335, H302, H317, H351
P201, P202, P261, P264, P271, P272, P280, P302+352, P304+340, P305+351+338, P308+313, P321, P333+313, P337+313, P362, P403+233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Lanthanum cobaltite is a perovskite with chemical formula LaCoO3. As a solid, the structure LaCoO3, will exist as rhombohedral material at room temperature with ferroelastic properties; though at temperatures above ~900 °C a phase transition to a cubic lattice occurs.[1][2]

It is also common of LaCoO3 to be utilized with either dopants or exhibit oxygen non-stoichometry where it may assume the structure La1−xA'xCo1−yB'yO3±𝛿 where 𝛿 is some small quantity[3] making this class of perovskites extremely versatile for catalysis, one such commonly utilized material is lanthanum strontium cobalt ferrite otherwise known as LSCF.

References

  1. Kleveland, Kjersti (2001). "Ferroeleastic Behavior of LaCoO3". Journal of the American Ceramic Society 84 (9): 2029–2033. doi:10.1111/j.1151-2916.2001.tb00953.x. 
  2. Petrov, A. N.; Kononchuk, O. F.; Andreev, A. V.; Cherepanov, V. A.; Kofstad, P. (1995-09-01). "Crystal structure, electrical and magnetic properties of La1−xSrxCoO3−y". Solid State Ionics 80 (3): 189–199. doi:10.1016/0167-2738(95)00114-L. 
  3. Orlovskaya, Nina (2000). "Mechanical properties of LaCoO3 based ceramics". Journal of the European Ceramic Society 20 (1): 51–56. doi:10.1016/S0955-2219(99)00084-9.