Chemistry:Liquid dielectric
A liquid dielectric is a dielectric material in liquid state. Its main purpose is to prevent or rapidly quench electric discharges. Dielectric liquids are used as electrical insulators in high voltage applications, e.g. transformers, capacitors, high voltage cables, and switchgear (namely high voltage switchgear). Its function is to provide electrical insulation, suppress corona and arcing, and to serve as a coolant. A good liquid dielectric should have high dielectric strength, high thermal stability and inertness against the construction materials used, non-flammability and low toxicity, good heat transfer properties, and low cost.
Liquid dielectrics are self-healing; when an electric breakdown occurs, the discharge channel does not leave a permanent conductive trace in the fluid.
The electrical properties tend to be strongly influenced by dissolved gases (e.g. oxygen or carbon dioxide), dust, fibers, and especially ionic impurities and moisture. Electrical discharge may cause production of impurities degrading the dielectric's performance.[1]
Some examples of dielectric liquids are transformer oil, perfluoroalkanes, and purified water.
| Name | Dielectric constant | Max. breakdown strength (MV⁄cm) | Properties |
|---|---|---|---|
| Mineral oil | 1.0[1] | Flammable. Common type of transformer oil. | |
| n-Hexane | 1.1–1.3[1] | Flammable. Used in some capacitors. | |
| n-Heptane | Flammable. | ||
| Castor oil natural ester | 4.7 | High dielectric constant. Flammable. Refined and dried castor oil is used in some high voltage capacitors. | |
| Hatcol 5005 synthetic ester[2] | 3.2 | High dielectric constant. Fire Resistant. Biodegradable PCB replacement. Low temperature fluidity. | |
| Silicone oil | 2.3–2.8 [3] | 1.0-1.2[1] | More expensive than hydrocarbons. Less flammable. |
| Fluorinert FC-72 | 1.75[4] | >0.16[4] | More expensive than hydrocarbons. Non flammable and non toxic. High global warming potential. Boiling point of 56 °C. |
| Novec 649 | 1.8[5] | >0.16[5] | More expensive than hydrocarbons. Non flammable and non toxic. Low global warming potential. Boiling point of 49 °C. |
| Novec 7100 | 7.4[6] | >0.01[6] | More expensive than hydrocarbons. Higher Dk compared to other perfluoroalkanes. Non flammable and non toxic. Low global warming potential. Boiling point of 61 °C. |
| Polychlorinated biphenyls | Formerly used in transformers and capacitors. Persistent organic pollutant, toxic, now phased out. Low flammability. | ||
| Purified water | 78[7]:503 | High thermal capacity, good cooling properties. Low electrical conductivity when free of ions. | |
| Benzene | 2.28[7]:503 | 1.1[1] | Toxic, flammable. |
| Liquid oxygen | 2.4 | Cryogenic. Highly flammable with combustible materials. | |
| Liquid nitrogen | 1.43[7]:498 | 1.6-1.9[1] | Cryogenic. Used as coolant with many low-temperature sensors and high-temperature superconductors. |
| Liquid hydrogen | 1.0[1] | Cryogenic. Flammable. | |
| Liquid helium | 0.7[1] | Cryogenic. Used with superconductors. | |
| Liquid argon | 1.10–1.42[1] | Cryogenic. |
See also
References
- ↑ 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 Naidu, S.; Kamaraju, V. (2009). High Voltage Engineering. Tata McGraw Hill Education Private Limited. p. 85. ISBN 9780070669284. https://books.google.com/books?id=FGowlP_lKK8C&pg=PA85. Retrieved July 24, 2015.
- ↑ "Lanxess Lubricant Additives". 8 November 2019. https://lanxess.com/corporate/products-solutions/business-units/lubricant-additives-business/.
- ↑ Walter Noll (2 December 2012). Chemistry and Technology of Silicones. Elsevier. pp. 468–. ISBN 978-0-323-14140-6. https://books.google.com/books?id=5J3YS3dXA6kC&pg=PA468.
- ↑ 4.0 4.1 "3M Fluorinert Electronic Liquid FC-72". 27 August 2019. https://www.3m.com/3M/en_US/company-us/all-3m-products/~/3M-Fluorinert-Electronic-Liquid-FC-72/?N=5002385+3290667393&rt=rud.
- ↑ 5.0 5.1 "3M Novec 649 Engineered Fluid". https://www.3m.com/3M/en_US/company-us/all-3m-products/~/3M-Novec-649-Engineered-Fluid/?N=5002385+3290667401&rt=rud.
- ↑ 6.0 6.1 "3M Novec 7100 Engineered Fluid". https://www.3m.com/3M/en_US/company-us/all-3m-products/~/3M-Novec-7100-Engineered-Fluid/?N=5002385+3290667247&rt=rud.
- ↑ 7.0 7.1 7.2 Murphy, E. J.; Morgan, S. O. (October 1937). "The Dielectric Properties of Insulating Materials". Bell System Technical Journal 16 (4): 493–512. doi:10.1002/j.1538-7305.1937.tb00765.x. http://www.alcatel-lucent.com/bstj/vol16-1937/articles/bstj16-4-493.pdf. Retrieved September 27, 2020.
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