Chemistry:Nabalamprophyllite
| Nabalamprophyllite | |
|---|---|
| General | |
| Category | Sorosilicate |
| Formula (repeating unit) | Ba(Na,Ba){Na 3Ti[Ti 2O 2Si 4O 14](OH,F) 2} |
| Crystal system | Monoclinic |
| Crystal class | Prismatic (2/m) (same H-M symbol) |
| Space group | P2/m |
| Unit cell | a = 19.805, b = 7.123 c = 5.426 [Å]; β = 96.45; Z = 2 ; V = 753.4 Å3 |
| Identification | |
| Color | Brown to bright yellow crystals |
| Crystal habit | Prismatic, sheaf-like, random aggregates |
| Cleavage | Perfect (001) |
| Mohs scale hardness | 3 |
| |re|er}} | Glassy |
| Streak | White |
| Diaphaneity | Transparent to translucent |
| Optical properties | Biaxial positive |
| Refractive index | nα=1.750, nγ=1.799 |
| Pleochroism | Weak, green-brown |
| 2V angle | 40.5° |
| References | [1][2] |
Nabalamprophyllite has a general formula of Ba(Na,Ba){Na
3Ti[Ti
2O
2Si
4O
14](OH,F)
2}.[2] The name is given for its composition (Naba, meaning sodium, Na and barium, Ba) and relation to other lamprophyllite-group minerals. Lamprophyllite is a rare Ti-bearing silicate mineral usually found in intrusive igneous rocks.[4]
Nabalamprophyllite is monoclinic, which means crystallographically, it contains three axes of unequal length and the angles between two of the axes are 90°, and one is less than 90°. It belongs to the space group P2/m.[2] The mineral also has an orthorhombic polytype (nabalamprophyllite-2O).[5] This mineral belongs to the space group Pnmn. In terms of its optical properties, nabalamprophyllite is anisotropic which means the velocity of light varies depending on direction through the mineral. Its calculated relief is 1.86 - 1.87.[1] Its color in plane polarized light is green-brown, and it is weakly pleochroic.
The mineral has only been found in Russia , usually in association with coarse-grained igneous rocks called pegmatites. The type localities are the Inagli alkaline–ultrabasic massif, Yakutia and the Kovdor alkaline–ultrabasic massif in the Kola Peninsula.
References
- ↑ 1.0 1.1 Webmineral data
- ↑ 2.0 2.1 2.2 Philonen, P.C., Grew, E.S., Ercit, T.S., Roberts, A.C., Jambor, J.L. (2005) New mineral names. American Mineralogist, 90, 1227-1233
- ↑ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode: 2021MinM...85..291W.
- ↑ Klein, C., Dutrow, B. (2007) The 23rd edition of the Manual of Mineral Science. John Wiley Publishers, p.497.
- ↑ Sokolova, E., Hawthorne, F.C. (2008) From Structure Topology to Chemical Composition. IV. Titanium Silicates: The Orthorhombic Polytype of Nabalamprophyllite from the Lovozero Massif, Kola Peninsula, Russia. The Canadian Mineralogist, 46, 1323-1331.
- N.V. Chukanov, M.M. Moiseev, I.V. Pekov, K.A. Lazebnik, R.K. Rastsvetaeva, N.V. Zayakina, G. Ferraris, G. Ivaldi (2004) Nabalamprophyllite Ba(Na,Ba){Na3Ti[Ti2O2Si4O14](OH,F)2}, a new layer titanosilicate of the lamprophyllite group from the Inagli and Kovdor alkaline-ultrabasic massifs, Russia. Zapiski Vseross. Mineral. Obshch., 133(1), 59–72 (in Russian, English abstract).
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