Chemistry:Pentafluorobenzene
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Names | |
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Preferred IUPAC name
Pentafluorobenzene | |
Other names
Pentafluorobenzene, phenyl pentafluoride
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
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PubChem CID
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Properties | |
C6HF5 | |
Molar mass | 168.066 g·mol−1 |
Appearance | Colorless liquid |
Density | 1.511 g/cm3 |
Melting point | -47.4 |
Boiling point | 85 °C (185 °F; 358 K) |
Insoluble | |
Hazards | |
GHS pictograms | |
GHS Signal word | DANGER |
H225, H302, H315, H318, H335 | |
Flash point | 14 °C (57 °F; 287 K) |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Infobox references | |
Tracking categories (test):
Pentafluorobenzene is an organofluoride compound with the molecular formula C6HF5.[1] The compound consists of a benzene ring substituted with five fluorine atoms.[2] The substance is a colorless liquid with a boiling point similar to that of benzene.[3][4] It is prepared by defluorination of highly fluorinated cyclohexanes over hot nickel or iron.[5] Another method involved dehydrofluorination of polyfluorinated cyclohexane using hot aqueous solution of KOH.[6]
See also
References
- ↑ "Pentafluorobenzene". sigmaaldrich.com. http://www.sigmaaldrich.com/catalog/product/aldrich/p5301?lang=en®ion=RU&gclid=Cj0KEQjw6-PJBRCO_br1qoOB4LABEiQAEkqcVZI5xErFDTYKmyXDPaZoi7a8XDWgAXiIZSrKwDGKvVsaAn_18P8HAQ. Retrieved 8 June 2017.
- ↑ "Пентафторбензол" (in Russian). himreakt.ru. http://www.himreakt.ru/4102/. Retrieved 8 June 2017.
- ↑ "Pentafluorobenzene". webbook.nist.gov. http://webbook.nist.gov/cgi/cbook.cgi?ID=363-72-4. Retrieved 8 June 2017.
- ↑ CRC Handbook of Chemistry and Physics, 90. Edition, CRC Press, Boca Raton, Florida, 2009, ISBN:978-1-4200-9084-0, Section 3, Physical Constants of Organic Compounds, p. 3-414.
- ↑ Gething, B.; Patrick, C. R.; Tatlow, J. C.; Banks, R. E.; Barbour, A. K.; Tipping, A. E. (1959). "Thermal Reactions of Highly Fluorinated Cyclo Hexadienes". Nature 183 (4661): 586–587. doi:10.1038/183586a0. Bibcode: 1959Natur.183..586G.
- ↑ Nield, E.; Stephens, R.; Tatlow, J. C. (1959). "31. Aromatic polyfluoro-compounds. Part I. The synthesis of aromatic polyfluoro-compounds from pentafluorobenzene". Journal of the Chemical Society (Resumed): 166. doi:10.1039/JR9590000166.