Chemistry:Pentafluorobenzene

From HandWiki
Pentafluorobenzene
Pentafluorobenzene.svg
Names
Preferred IUPAC name
Pentafluorobenzene
Other names
Pentafluorobenzene, phenyl pentafluoride
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 206-658-7
UNII
Properties
C6HF5
Molar mass 168.066 g·mol−1
Appearance Colorless liquid
Density 1.511 g/cm3
Melting point -47.4
Boiling point 85 °C (185 °F; 358 K)
Insoluble
Hazards
GHS pictograms GHS02: Flammable GHS05: Corrosive GHS07: Harmful
GHS Signal word DANGER
H225, H302, H315, H318, H335
Flash point 14 °C (57 °F; 287 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references
Tracking categories (test):

Pentafluorobenzene is an organofluoride compound with the molecular formula C6HF5.[1] The compound consists of a benzene ring substituted with five fluorine atoms.[2] The substance is a colorless liquid with a boiling point similar to that of benzene.[3][4] It is prepared by defluorination of highly fluorinated cyclohexanes over hot nickel or iron.[5] Another method involved dehydrofluorination of polyfluorinated cyclohexane using hot aqueous solution of KOH.[6]

See also

References

  1. "Pentafluorobenzene". sigmaaldrich.com. http://www.sigmaaldrich.com/catalog/product/aldrich/p5301?lang=en&region=RU&gclid=Cj0KEQjw6-PJBRCO_br1qoOB4LABEiQAEkqcVZI5xErFDTYKmyXDPaZoi7a8XDWgAXiIZSrKwDGKvVsaAn_18P8HAQ. Retrieved 8 June 2017. 
  2. "Пентафторбензол" (in Russian). himreakt.ru. http://www.himreakt.ru/4102/. Retrieved 8 June 2017. 
  3. "Pentafluorobenzene". webbook.nist.gov. http://webbook.nist.gov/cgi/cbook.cgi?ID=363-72-4. Retrieved 8 June 2017. 
  4. CRC Handbook of Chemistry and Physics, 90. Edition, CRC Press, Boca Raton, Florida, 2009, ISBN:978-1-4200-9084-0, Section 3, Physical Constants of Organic Compounds, p. 3-414.
  5. Gething, B.; Patrick, C. R.; Tatlow, J. C.; Banks, R. E.; Barbour, A. K.; Tipping, A. E. (1959). "Thermal Reactions of Highly Fluorinated Cyclo Hexadienes". Nature 183 (4661): 586–587. doi:10.1038/183586a0. Bibcode1959Natur.183..586G. 
  6. Nield, E.; Stephens, R.; Tatlow, J. C. (1959). "31. Aromatic polyfluoro-compounds. Part I. The synthesis of aromatic polyfluoro-compounds from pentafluorobenzene". Journal of the Chemical Society (Resumed): 166. doi:10.1039/JR9590000166.