Chemistry:Potash

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Short description: Salt mixture
Polycrystalline potash, with a U.S. penny for reference. (The coin is 19 mm (0.75 in) in diameter and copper in color.)

Potash (/ˈpɒtæʃ/) includes various mined and manufactured salts that contain potassium in water-soluble form.[1] The name derives from pot ash, plant ashes or wood ash soaked in water in a pot, the primary means of manufacturing potash before the Industrial Era. The word potassium is derived from potash.[2]

Potash is produced worldwide in amounts exceeding 71.9 million tonnes (~45.4 million tonnes K2O equivalent[5]) per year as of 2021, with Canada being the largest producer, mostly for use in fertilizer.[6] Various kinds of fertilizer-potash constitute the single greatest industrial use of the element potassium in the world. Potassium was first derived in 1807 by electrolysis of caustic potash (potassium hydroxide).[7]

Terminology

Potash refers to potassium compounds and potassium-bearing materials, most commonly potassium carbonate. The word "potash" originates from the Middle Dutch "potaschen", denoting "pot ashes" in 1477.[8] The old method of making potassium carbonate (K2CO3) was by collecting or producing wood ash (the occupation of ash burners), leaching the ashes, and then evaporating the resulting solution in large iron pots, which left a white residue denominated "pot ash".[9] Approximately 10% by weight of common wood ash can be recovered as potash.[10][11] Later, "potash" became widely applied to naturally occurring minerals that contained potassium salts and the commercial product derived from them,[12].

The following table lists a number of potassium compounds that have "potash" in their traditional names:

Common name Chemical name (Formula)
Potash fertilizer c. 1942 potassium carbonate (K2CO3); c. 1950 any one or more of potassium chloride (KCl), potassium sulfate (K2SO4) or potassium nitrate (KNO3).[13][14] Does not contain potassium oxide (K2O), which plants do not take up.[15] The amount of potassium is often reported as K2O equivalent (that is, how much it would be if in K2O form), however, to allow apples-to-apples comparison between different fertilizers using different types of potash.
Caustic potash or potash lye potassium hydroxide (KOH)
Carbonate of potash, salts of tartar, or pearl ash potassium carbonate (K2CO3)
Chlorate of potash potassium chlorate (KClO3)
Muriate of potash (MOP) potassium chloride (KCl:NaCl = 95:5 or higher)[1]
Nitrate of potash or saltpeter potassium nitrate (KNO3)
Sulfate of potash (SOP) potassium sulfate (K2SO4)
Permanganate of potash potassium permanganate (KMnO4)

History

The first U.S. patent was issued for an improvement "in the making of Pot ash and Pearl ash by a new Apparatus and Process"; it was signed by then President George Washington.
A covered hopper car in a Canadian train for shipping potash by rail.

Origin of potash ore

Most of the world reserves of potassium (K) were deposited as sea water in ancient inland oceans. After the water evaporated, the potassium salts crystallized into beds of potash ore. These are the locations where potash is being mined today. The deposits are a naturally occurring mixture of potassium chloride (KCl) and sodium chloride (NaCl), more commonly known as table salt. Over time, as the surface of the earth changed, these deposits were covered by thousands of feet of earth.[16]

Bronze Age

Potash (especially potassium carbonate) has been used in bleaching textiles, making glass, ceramic, and making soap, since the Bronze Age.[17] Potash was principally obtained by leaching the ashes of land plants.

14th–17th century

Potash mining

Beginning in the 14th century potash was mined in Ethiopia. One of the world's largest deposits, 140 to 150 million tons, is located in the Dallol area of the Afar Region.[18]

Wood-derived potash

Potash was one of the most important industrial chemicals. It was refined from the ashes of broadleaved trees and produced primarily in the forested areas of Europe, Russia , and North America. Although methods for producing artificial alkalis were invented in the late 18th century, these did not become economical until the late 19th century and so the dependence on organic sources of potash remained.

Potash became an important international trade commodity in Europe from at least the early 14th century. It is estimated that European imports of potash required 6 or more million cubic metres each year from the early 17th century.[19] Between 1420 and 1620, the primary exporting cities for wood-derived potash were Gdańsk, Königsberg and Riga. In the late 15th century, London was the lead importer due to its position as the centre of soft soap making while the Dutch dominated as suppliers and consumers in the 16th century.[20] From the 1640s, geopolitical disruptions (i.e. Russo-Polish War (1654–1667)) meant that the centres of export moved from the Baltic to Archangel, Russia. In 1700, Russian ash was dominant though Gdańsk remained notable for the quality of its potash.

Kelp ash

On the Orkney islands as early as 1719 for a century, kelp ash provided potash and soda ash, "substances eagerly sought after by the glass and soap industries of the time."[21]

18th century

North America

By the 18th century, higher quality American potash was increasingly exported to Britain. In the late 18th and early 19th centuries, potash production provided settlers in North America badly needed cash and credit as they cleared wooded land for crops. To make full use of their land, settlers needed to dispose of excess wood. The easiest way to accomplish this was to burn any wood not needed for fuel or construction. Ashes from hardwood trees could then be used to make lye, which could either be used to make soap or boiled down to produce valuable potash. Hardwood could generate ashes at the rate of 60 to 100 bushels per acre (500 to 900 m³/km2). In 1790, the sale of ashes could generate $3.25 to $6.25 per acre ($800 to $1,500/km2) in rural New York State – nearly the same rate as hiring a laborer to clear the same area. Potash making became a major industry in British North America. Great Britain was always the most important market. The American potash industry followed the woodsman's ax across the country.

The first U.S. patent

The first U.S. patent of any kind was issued in 1790 to Samuel Hopkins for an improvement "in the making of Pot ash and Pearl ash by a new Apparatus and Process".[22] Pearl ash was a purer quality made by calcination of potash in a reverberatory furnace or kiln. Potash pits were once used in England to produce potash that was used in making soap for the preparation of wool for yarn production.

19th century

After about 1820, New York replaced New England as the most important source; by 1840 the center was in Ohio. Potash production was always a by-product industry, following from the need to clear land for agriculture.[16]

Canada

From 1767, potash from wood ashes was exported from Canada. By 1811, 70% of the total 19.6 million lbs of potash imports to Britain came from Canada.[20] Exports of potash and pearl ash reached 43,958 barrels in 1865. There were 519 asheries in operation in 1871.

20th century industrializaton

The wood-ash industry declined in the late 19th century when large-scale production of potash from mineral salts was established in Germany . In 1943, potash was discovered in Saskatchewan, Canada, during oil drilling. Active exploration began in 1951. In 1958, the Potash Company of America became the first potash producer in Canada with the commissioning of an underground potash mine at Patience Lake. Due to water seepage, production stopped late in 1959. Following extensive grouting and repairs, production resumed in 1965. The underground mine was flooded in 1987, and was reactivated for commercial production as a solution mine in 1989.[11]

A postcard of the Kalium Chemicals plant in Belle Plaine, Saskatchewan

In 1964 Canadian company Kalium Chemicals established the first potash mine using the solution process. The discovery was made during oil reserve exploration. The mine was developed near Regina, Saskatchewan. The mine reached depths greater than 1500 meters. It is now the Mosaic Corporation's Belle Plaine unit.

In the beginning of the 20th century, potash deposits were found in the Dallol Depression in Musely and Crescent localities near the Ethiopean-Eritrean border. The estimated reserves are 173 and 12 million tonnes for the Musely and Crescent, respectively. The latter is particularly suitable for surface mining. It was explored in the 1960s but the works stopped due to flood in 1967. Attempts to continue mining in the 1990s were halted by the Eritrean–Ethiopian War and have not resumed as of 2009.[23]

Potash evaporation ponds at the Intrepid Potash mine near Moab, Utah

Mining

Shaft mining and strip mining

All commercial potash deposits come originally from evaporite deposits and are often buried deep below the earth's surface. Potash ores are typically rich in potassium chloride (KCl), sodium chloride (NaCl) and other salts and clays, and are typically obtained by conventional shaft mining with the extracted ore ground into a powder.[24] Most potash mines today are deep shaft mines as much as 4,400 feet (1,400 m) underground. Others are mined as strip mines, having been laid down in horizontal layers as sedimentary rock. In above-ground processing plants, the KCl is separated from the mixture to produce a high-analysis potassium fertilizer. Other potassium salts can be separated by various procedures, resulting in potassium sulfate and potassium-magnesium sulfate.

Dissolution mining and evaporation methods

Other methods include dissolution mining and evaporation methods from brines. In the evaporation method, hot water is injected into the potash, which is dissolved and then pumped to the surface where it is concentrated by solar induced evaporation. Amine reagents are then added to either the mined or evaporated solutions. The amine coats the KCl but not NaCl. Air bubbles cling to the amine + KCl and float it to the surface while the NaCl and clay sink to the bottom. The surface is skimmed for the amine + KCl, which is then dried and packaged for use as a K rich fertilizer—KCl dissolves readily in water and is available quickly for plant nutrition.[25]

Recovery of potassium fertilizer salts from sea water has been studied in India .[26] During extraction of salt from seawater by evaporation, potassium salts get concentrated in bittern, an effluent from the salt industry.

Production

Potash deposits are located throughout the world. (As of 2015), deposits are being mined in Canada, Russia, China, Belarus, Israel, Germany, Chile, the United States, Jordan, Spain, the United Kingdom, Uzbekistan and Brazil,[27] with the most significant deposits present under the great depths of the Prairie Evaporite Formation in Saskatchewan, Canada.[11]

The Permian Basin deposit includes the major mines outside of Carlsbad, New Mexico, to the world's purest potash deposit in Lea County, New Mexico (near the Carlsbad deposits), which is believed to be roughly 80% pure. (Osceola County, Michigan has deposits 90+% pure; the only mine there was converted to salt production, however.) Canada is the largest producer, followed by Russia and Belarus. The most significant reserve of Canada's potash is located in the province of Saskatchewan and is mined by The Mosaic Company, Nutrien and K+S.[1]

In China , most potash deposits are concentrated in the deserts and salt flats of the endorheic basins of its western provinces, particularly Qinghai. Geological expeditions discovered the reserves in the 1950s[28] but commercial exploitation lagged until Deng Xiaoping's Reform and Opening Up Policy in the 1980s. The 1989 opening of the Qinghai Potash Fertilizer Factory in the remote Qarhan Playa increased China's production of potassium chloride sixfold, from less than 40,000 t (39,000 long tons; 44,000 short tons) a year at Haixi and Tanggu to just under 240,000 t (240,000 long tons; 260,000 short tons) a year.[29]

In 2013, almost 70% of potash production was controlled by Canpotex, an exporting and marketing firm, and the Belarusian Potash Company. The latter was a joint venture between Belaruskali and Uralkali, but on July 30, 2013, Uralkali announced that it had ended the venture.[30]

List of countries by potash production
Rank Country Extraction in metric tons K2O equivalent
2016 2017 2018 2019 2020
1  Canada 10,789,662 12,562,695 14,023,931 12,643,318 13,881,665
2  Russia 6,480,000 7,300,000 7,055,000 7,368,000 8,167,300
3  Belarus 6,180,100 7,101,800 7,346,096 7,348,293 7,562,153
4  China 5,783,000 5,534,000 5,452,000 5,902,000 5,530,000
5  Germany 2,750,841 2,963,561 2,754,085 2,615,284 2,874,026
6  Israel 2,093,100 2,126,700 2,149,300 2,043,500 2,415,600
7  Jordan 1,222,140 1,415,260 1,485,960 1,516,460 1,598,200
8  Chile 1,303,840 1,238,630 991,180 683,540 966,680
9  United States 510,000 480,000 520,000 510,000 460,000
10  Spain 672,246 557,468 635,490 547,100 455,000
11  Laos 198,600 307,600 343,500 286,900 442,500
12  Brazil 316,429 306,296 201,181 269,300 276,600
13  Uzbekistan 83,000 114,900 176,900 198,400 210,000
14  United Kingdom 482,800 297,400 291,100 84,000 99,260
15  Iran 10,500 15,300 32,900 37,200 37,000
16  Turkmenistan 0 0 15,200 11,100 16,000
17  Bolivia 0 0 1,700 17,800 4,400
Total 38,876,258 42,321,610 43,475,523 42,082,195 44,996,384

Occupational hazards

Excessive respiratory disease due to environmental hazards, such as radon and asbestos, has been a concern for potash miners throughout history. Potash miners are liable to develop silicosis. Based on a study conducted between 1977 and 1987 of cardiovascular disease among potash workers, the overall mortality rates were low, but a noticeable difference in above-ground workers was documented.[31]

Consumption

Production of potash and reserves at some current mines (being <2% of global reserves)
(both in [math]\ce{ K2O }[/math] equivalent)
(2021, in million tonnes)[32]
Country Production Reserves
Canada 14.2 (28.57%) 1,100 (33.33%)
Russia 9.1 (17.14%) 400 (12.12%)
Belarus 7.6 (16.48%) 750 (22.73%)
China 6.0 (14.76%) 170 (5.15%)
Germany 2.8 (6.90%) 150 (4.55%)
Israel 2.4 (5.14%) Large (?%)
Jordan 1.6 (3.37%) Large (?%)
Chile 0.9 (1.85%) 100 (3.03%)
United States 0.5 (1.04%) 220 (6.67%)
Spain 0.4 (0.79%) 68 (2.06%)
Brazil 0.3 (0.58%) 2.3 (0.01%)
Other countries 0.4 (0.76%) 300 (9.09%)
World total 46.3 (100.00%) >3,300 (100.00%)

Fertilizers

Potassium is the third major plant and crop nutrient after nitrogen and phosphorus. It has been used since antiquity as a soil fertilizer (about 90% of current use).[10] Elemental potassium does not occur in nature because it reacts violently with water.[33] As part of various compounds, potassium makes up about 2.6% of the Earth's crust by mass and is the seventh most abundant element, similar in abundance to sodium at approximately 1.8% of the crust.[34] Potash is important for agriculture because it improves water retention, yield, nutrient value, taste, color, texture and disease resistance of food crops. It has wide application to fruit and vegetables, rice, wheat and other grains, sugar, corn, soybeans, palm oil and cotton, all of which benefit from the nutrient's quality-enhancing properties.[35]

Demand for food and animal feed has been on the rise since 2000. The United States Department of Agriculture's Economic Research Service (ERS) attributes the trend to average annual population increases of 75 million people around the world. Geographically, economic growth in Asia and Latin America greatly contributed to the increased use of potash-based fertilizer. Rising incomes in developing countries also were a factor in the growing potash and fertilizer use. With more money in the household budget, consumers added more meat and dairy products to their diets. This shift in eating patterns required more acres to be planted, more fertilizer to be applied and more animals to be fed—all requiring more potash.

After years of trending upward, fertilizer use slowed in 2008. The worldwide economic downturn is the primary reason for the declining fertilizer use, dropping prices, and mounting inventories.[36][37]

The world's largest consumers of potash are China, the United States, Brazil, and India.[38] Brazil imports 90% of the potash it needs.[38] Potash consumption for fertilizers is expected to increase to about 37.8 million tonnes by 2022.[39]

Potash imports and exports are often reported in K2O equivalent, although fertilizer never contains potassium oxide, per se, because potassium oxide is caustic and hygroscopic.

Pricing

At the beginning of 2008, potash prices started a meteoric climb from less than US$200 a tonne to a high of US$875 in February 2009.[40] These subsequently dropped dramatically to an April 2010 low of US$310 level, before recovering in 2011–12, and relapsing again in 2013. For reference, prices in November 2011 were about US$470 per tonne, but as of May 2013 were stable at US$393.[41] After the surprise breakup of the world's largest potash cartel at the end of July 2013, potash prices were poised to drop some 20 percent.[42] At the end of Dec 2015, potash traded for US$295 a tonne. In April 2016 its price was US$269.[43] In May 2017, prices had stabilised at around US$216 a tonne down 18% from the previous year. By January 2018, prices have been recovering to around US$225 a tonne.[44] World potash demand tends to be price inelastic in the short-run and even in the long run.[39]

Other uses

In addition to its use as a fertilizer, potassium chloride is important in many industrialized economies, where it is used in aluminium recycling, by the chloralkali industry to produce potassium hydroxide, in metal electroplating, oil-well drilling fluid, snow and ice melting, steel heat-treating, in medicine as a treatment for hypokalemia, and water softening. Potassium hydroxide is used for industrial water treatment and is the precursor of potassium carbonate, several forms of potassium phosphate, many other potassic chemicals, and soap manufacturing. Potassium carbonate is used to produce animal feed supplements, cement, fire extinguishers, food products, photographic chemicals, and textiles. It is also used in brewing beer, pharmaceutical preparations, and as a catalyst for synthetic rubber manufacturing. Also combined with silica sand to produce potassium silicate, sometimes known as waterglass, for use in paints and arc welding electrodes. These non-fertilizer uses have accounted for about 15% of annual potash consumption in the United States.[1]

Substitutes

No substitutes exist for potassium as an essential plant nutrient and as an essential nutritional requirement for animals and humans. Manure and glauconite (greensand) are low-potassium-content sources that can be profitably transported only short distances to crop fields.[32]

See also

References

  1. ↑ 1.0 1.1 1.2 1.3 Potash, USGS 2008 Minerals Yearbook
  2. ↑ Davy, Humphry (1808). "On some new phenomena of chemical changes produced by electricity, in particular the decomposition of the fixed alkalies, and the exhibition of the new substances that constitute their bases; and on the general nature of alkaline bodies". Philosophical Transactions of the Royal Society of London 98: 32. doi:10.1098/rstl.1808.0001. https://books.google.com/books?id=gpwEAAAAYAAJ&pg=PA32. 
  3. ↑ "Production and use of potassium chloride". p. 17. https://www.ipipotash.org/uploads/udocs/Chap-1_potash_production.pdf. 
  4. ↑ "Production and Use of Potassium". Better Crops 82 (3): 6. 1998. http://www.ipni.net/publication/bettercrops.nsf/0/A529956F62A701F6852579800082035A/$FILE/Better%20Crops%201998-3%20p06.pdf. 
  5. ↑ Chemically pure KCl (96% of world potash capacity[3]) contains 63.17% K2O equivalent[4]
  6. ↑ "Potash facts". 2018-01-23. https://natural-resources.canada.ca/our-natural-resources/minerals-mining/minerals-metals-facts/potash-facts/20521. 
  7. ↑ Knight, David (1992). Humphry Davy: Science and Power. Oxford: Blackwell. pp. 66. ISBN 9780631168164. https://archive.org/details/isbn_9780631168164. 
  8. ↑ van der Sijs i.a., Nicoline (2010). "POTAS (SCHEIKUNDIG ELEMENT)" (in nl). http://etymologiebank.nl/trefwoord/potas. 
  9. ↑ Harper, Douglas. "potash". Online Etymology Dictionary. https://www.etymonline.com/?term=potash. 
  10. ↑ 10.0 10.1 Stephen M. Jasinski. "Potash". USGS. http://minerals.usgs.gov/minerals/pubs/commodity/potash/. 
  11. ↑ 11.0 11.1 11.2 "Potash". The Canadian Encyclopedia. March 4, 2015. https://www.thecanadianencyclopedia.ca/en/article/potash. Retrieved August 31, 2019. 
  12. ↑ "The World Potash Industry: Past, Present and Future". New Orleans, LA: 50th Anniversary Meeting The Fertilizer Industry Round Table. 2000. http://www.potashcorp.com/media/pdf/investor_relations/speeches/world_potash_industry.pdf. [yes|permanent dead link|dead link}}]
  13. ↑ Dennis Kostick (September 2006). "Potash". 2005 Minerals Handbook. United States Geological Survey. p. 58.1. http://minerals.usgs.gov/minerals/pubs/commodity/potash/potasmyb05.pdf. Retrieved 2011-01-29. 
  14. ↑ J. W. Turrentine (1934). "Composition of Potash Fertilizer Salts for Sale on the American Market". Industrial & Engineering Chemistry (American Chemical Society) 26 (11): 1224–1225. doi:10.1021/ie50299a022. 
  15. ↑ Joseph R. Heckman (January 17, 2002). "Potash Terminology and Facts". Plant & Pest Advisory (Rutgers University) 7 (13): 3. http://njaes.rutgers.edu/pubs/plantandpestadvisory/2002/fc0117.pdf. Retrieved January 29, 2011.  Reprinted from Agri-Briefs, from the Agronomists of the Potash & Phosphate Institute, Winter 2001–2002, No.7
  16. ↑ 16.0 16.1 Robert C. Fite Origin and occurrence of commercial potash deposits , Academy of Sciences for 1951, p. 123
  17. ↑ "Potash | Encyclopedia.com". https://www.encyclopedia.com/earth-and-environment/minerals-mining-and-metallurgy/mineralogy-and-crystallography/potash#:~:text=POTASH%20(potassium%20carbonate)%20and%20soda%20(sodium%20carbonate)%20have%20been%20used%20from%20the%20dawn%20of%20history%20in%20bleaching%20textiles,%20making%20glass,%20and,%20from%20about%20a.d.%20500,%20in%20making%20soap.. 
  18. ↑ Ethiopia Mining. Photius.com. Retrieved on 2013-06-21.
  19. ↑ Paul Warde, 'Trees, Trade and Textiles: Potash Imports and Ecological Dependency in British Industry, C .1550–1770', Past & Present, 240, 1, 2018, 47-82
  20. ↑ 20.0 20.1 Paul Warde, 'Trees, Trade and Textiles: Potash Imports and Ecological Dependency in British Industry, C .1550–1770', Past & resent, 240, 1, 2018, 47-82
  21. ↑ "Kelp Burning in Orkney". Sigurd Towrie. http://orkneyjar.com/tradition/kelpburning.htm. 
  22. ↑ Patent X1: the making of Pot ash and Pearl ash by a new Apparatus and Process (1790). en.wikisource.org
  23. ↑ "Minerals for Agricultural Industrialization". Ministry of Mines and Energy of Ethiopia. http://www.mome.gov.et/industrial.html. 
  24. ↑ Alikhan, Irfan (2014). Management of Agricultural Inputs. Agrotech Publishing Academy. ISBN 9789383101474. 
  25. ↑ Potassium Fertilizer Production and Technology . International Plant Nutrition Institute.
  26. ↑ Recovery of Potassium Fertiliser Salts from Sea Bittern . Tifac.org.in. Retrieved on 2013-06-21.
  27. ↑ QUICK GUIDE TO POTASH. (2013, June 14). Retrieved September 29, 2015, from http://www.geoalcali.com/en/quick-guide-to-potash/
  28. ↑ Zheng Mianping (1997), An Introduction to Saline Lakes on the Qinghai–Tibet Plateau, Dordrecht: Kluwer Academic Publishers, p. 3–5, ISBN 9789401154581, https://books.google.com/books?id=hFz-CAAAQBAJ .
  29. ↑ Garrett, Donald Everett (1996), Potash: Deposits, Processing, Properties, and Uses, London: Chapman & Hall, p. 176–177, ISBN 9789400915459, https://books.google.com/books?id=_MIjCQAAQBAJ .
  30. ↑ "Potash sector rocked as Russia's Uralkali quits cartel". Reuters. 2013-07-30. https://www.reuters.com/article/russia-uralkali-idUSL6N0G013H20130730. 
  31. ↑ Wild, Pascal; Moulin, Jean-Jacques; Ley, François-Xavier; Schaffer, Paul (16 April 1995). "Mortality from Cardiovascular Diseases among Potash Miners Exposed to Heat". Epidemiology 6 (3): 243–247. doi:10.1097/00001648-199505000-00009. PMID 7619930. 
  32. ↑ 32.0 32.1 "Potash Mineral Commodity Summaries 2023". January 2023. https://pubs.usgs.gov/periodicals/mcs2023/mcs2023-potash.pdf. 
  33. ↑ Arnold F. Holleman, Egon Wiberg and Nils Wiberg (1985). "Potassium" (in de). Lehrbuch der Anorganischen Chemie (91–100 ed.). Walter de Gruyter. ISBN 978-3-11-007511-3. 
  34. ↑ Greenwood, Norman N (1997). Chemistry of the Elements (2 ed.). Oxford: Butterworth-Heinemann. p. 69. ISBN 978-0-08-037941-8. https://archive.org/details/chemistryelement00earn_612. 
  35. ↑ Potash Price Close to all time highs – Future Outlook . ASX Release (14 November 2008). activex.com.au. Retrieved on 2013-06-21.
  36. ↑ Potash Around the World. southernstates.com
  37. ↑ "Potash global review: tunnel vision", Industrial Minerals, May 2009
  38. ↑ 38.0 38.1 Supply and Demand . Potassiodobrasil.com.br. Retrieved on 2013-06-21.
  39. ↑ 39.0 39.1 Rawashdeh, Rami Al; Xavier-Oliveira, Emanuel; Maxwell, Philip (2016). "The potash market and its future prospects". Resources Policy 47: 154–163. doi:10.1016/j.resourpol.2016.01.011. ISSN 0301-4207. Bibcode: 2016RePol..47..154R. 
  40. ↑ "Potash Prices Are Record High". Potash Investing news. February 5, 2009. http://www.potashinvestingnews.com/354-potash-prices-at-record-high.html. 
  41. ↑ 5 Year Potash Prices and Potash Price Charts – InvestmentMine. Infomine.com (2013-05-31). Retrieved on 2013-06-21.
  42. ↑ "Potash prices head for 20 pct drop after cartel disintegrates". Reuters. 5 September 2013. https://www.reuters.com/article/potash-prices-idUSL6N0H032X20130905. 
  43. ↑ "Potash Prices and Potash Price Charts". 2016-04-30. http://www.infomine.com/investment/metal-prices/potash/. 
  44. ↑ "Potash Prices and Potash Price Charts". 2017-06-05. https://ycharts.com/indicators/potassium_chloride_muriate_of_potash_spot_price. 

Further reading

External links



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