Chemistry:Potassium phthalimide

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Potassium phthalimide
Identifiers
3D model (JSmol)
ChemSpider
UNII
Properties
C8H4KNO2
Molar mass 185.221 g/mol
Appearance Light yellow solid
Melting point > 300 °C (572 °F; 573 K)
Soluble in water
Hazards
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondFlammability code 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilHealth code 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformReactivity code 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
2
0
Related compounds
Related compounds
Phthalimide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
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Potassium phthalimide is an organic compound with the formula C
6
H
4
(CO)
2
NK
. It is the potassium salt of phthalimide, and usually presents as fluffy, very pale yellow crystals. It can be prepared by combining phthalimide and potassium hydroxide.[1]:

This compound is a commercially available reagent used in the Gabriel synthesis of amines. It is a precursor to anthranilic acid, although sodium phthalimide is a more typical precursor.[2]

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Structure

The structure of solid potassium phthalimide has been determined by X-ray crystallography. It is a salt, the K+ centers being bound to oxygen and nitrogen ligands.[3]

References

  1. ↑ P. L. Salzberg and J. V. Supniewski (1927). "β-Bromoethylphthalimide". Organic Syntheses 7: 8. doi:10.15227/orgsyn.007.0008. 
  2. ↑ Maki, Takao; Takeda, Kazuo (2000). "Benzoic Acid and Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a03_555. ISBN 3527306730. .
  3. ↑ Nagel, N.; Bock, H.; Bats, J. W. (1996). "Potassium Phthalimide". Acta Crystallographica Section C Crystal Structure Communications 52 (6): 1344–1346. doi:10.1107/S0108270196002387.