Chemistry:Propylene chlorohydrin

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Propylene chlorohydrin
(±)-1-Chlor-2-propanol Formula V.1.svg
Names
Preferred IUPAC name
1-Chloropropan-2-ol
Other names
1-Chloro-2-hydroxypropane
Identifiers
3D model (JSmol)
ChemSpider
EC Number
  • 204-819-6

    2.3.5UN Number New Window

    2611 CHEBI:76260

    CHEMBL1361129
UNII
Properties
C3H7ClO
Molar mass 94.54
Appearance colorless liquid
Density 1.1154 g/mL
Boiling point 127°C
Hazards
GHS pictograms GHS02: FlammableGHS07: Harmful
GHS Signal word Warning
H226, H302, H315, H319, H332, H335
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+312, P302+352, P303+361+353, P304+312, P304+340, P305+351+338, P312, P321, P330, P332+313, P337+313, P362, P370+378, P403+233
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Propylene chlorohydrin usually refers to the organic compound with the formula CH3CH(OH)CH2Cl. A related compound, an isomer, is CH3CH(Cl)CH2OH. Both isomers are colorless liquids that are soluble in organic solvents. They are classified as chlorohydrins. Both are generated on a large scale as intermediates in the production of propylene oxide.[1]

The reaction of aqueous solution of chlorine with propene gives a 10:1 ratio of CH3CH(OH)CH2Cl and CH3CH(Cl)CH2OH. These compounds are treated with lime to give propylene oxide, which is useful in the production of plastics and other polymers.

References

  1. Gordon Y. T. Liu, W. Frank Richey, Joanne E. Betso, Brian Hughes, Joanna Klapacz, and Joerg Lindner "Chlorohydrins" in Ullmann's Encyclopedia of Industrial Chemistry, 2014, Wiley-VCH, Weinheim. doi:10.1002/14356007.a06_565.pub2