Chemistry:Sewardite

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Sewardite
General
CategoryArsenate minerals
Formula
(repeating unit)
CaFe2+3(AsO4)2(OH)2
Strunz classification8.BH.30
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupCccm
Unit cella = 16.461 Å, b = 7.434 Å,
c = 12.131 Å; Z = 8
Identification
Formula mass464.68 g/mol
ColorDark red, lighter red orange
Crystal habitPlaty aggregates, anhedral grains
Cleavage{100} and {011} imperfect
FractureSplintery – thin elongated fractures
Mohs scale hardness3.5
|re|er}}Vitreous (glassy)
StreakReddish brown
DiaphaneityTranslucent
Specific gravity4.16
Optical propertiesWeak Anistropic
Refractive index1.94 calculated
BirefringenceWeak
PleochroismNone
References[1][2]

Sewardite is a rare arsenate mineral with formula of CaFe3+2(AsO4)2(OH)2.[2] Sewardite was discovered in 1982 and named for the mineralogist, Terry M. Seward (born 1940), a professor of geochemistry in Zürich, Switzerland .[2]

Properties

Sewardite is orthorhombic, which means that it contains three axes of unequal length, a, b, and c, which are all at 90° to one another. Its class structure is mmm (2/m 2/m 2/m) – dipyramidal. Sewardite can form platy-to-compact anhedral-to-subhedral masses up to 0.3 mm in size.[4]

In terms of its optical properties, sewardite is weakly anisotropic, which means the velocity of light varies depending on the direction through the mineral. Its color in plane-polarized light is dark red, and it does not exhibit pleochroism, which means it does not appear to be a different color when observed at different angles under a polarizing petrographic microscope. Sewardite illustrates weak birefringence because it is weakly anisotropic.[5]

Occurrence

Sewardite has only been found at three locations, in the Tsumeb mine in Tsumeb, Namibia, Mina Ojuela, Mapimi, Durango, Mexico, and La Mur, Las Animas mine, Sonora, Mexico.[2] At the site in Durango, Mexico, it occurs as a dark, reddish spherules and rosettes of very thin, flaky crystals.[4]

This newly discovered mineral (confirmed as a species in 1998) has been determined as rare, since only 1–2 mg of it were found in the Tsumeb mine.[4]

References