Chemistry:Stephanite

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Stephanite
Stephanite-oldeuro-119a.jpg
General
CategorySulfosalt mineral
Formula
(repeating unit)
Ag5SbS4
Strunz classification2.GB.10
Dana classification03.02.04.01
Crystal systemOrthorhombic
Crystal classPyramidal (mm2)
H-M symbol: (mm2)
Space groupCmc21
Identification
ColourLead grey to black
Crystal habitTabular, pseudo-hexagonal crystals; massive
TwinningCommon on [110] repeated, forms pseudohexagonal groupings
CleavageImperfect on {010}, poor on {021}
FractureSubconchoidal
TenacityBrittle
Mohs scale hardness2.0–2.5
Metallic|re|er}}Metallic
StreakIron black
DiaphaneityOpaque
Specific gravity6.26
Optical propertiesAnisotropic in polished section
PleochroismVery weak – white to pale pink
References[1][2][3]

Stephanite is a silver antimony sulfosalt mineral with formula: Ag5SbS4. It is composed of 68.8% silver, and sometimes is of importance as an ore of this metal.[5]

History

Under the name Schwarzerz it was mentioned by Georgius Agricola in 1546, and it has been variously known as "black silver ore" (German Schwarzgultigerz), brittle silver-ore (Sprödglanzerz), etc. The name stephanite was proposed by W Haidinger in 1845 in honour of the Archduke of Austria Stephan Franz Victor of Habsburg-Lorena (1817–1867). French authors use F. S. Beudant's name psaturose (from the Greek ψαθυρός, fragile).[5]

Properties

It frequently occurs as well-formed crystals, which are orthorhombic and occasionally show indications of hemimorphism: they have the form of six-sided prisms or flat tables terminated by large basal planes and often modified at the edges by numerous pyramid-planes. Twinning on the prism-planes is of frequent occurrence, giving rise to pseudo-hexagonal groups like those of aragonite. The colour is iron-black, and the lustre metallic and brilliant; on exposure to light, however, the crystals soon become dull.[5] Stephanite is an important ore of silver in some mining camps.

Occurrence

Stephanite occurs as a late-stage mineral with other ores of silver in hydrothermal veins.[5] Associated minerals include proustite, acanthite, native silver, tetrahedrite, galena, sphalerite and pyrite.[1] Localities which have yielded good crystallized specimens are Freiberg and Gersdorf near Rosswein in Saxony, Chañarcillo in Chile , and exceptionally Cornwall. In the Comstock lode in Nevada massive stephanite and argentite are important ores of silver.

See also

References

  1. 1.0 1.1 http://rruff.geo.arizona.edu/doclib/hom/stephanite.pdf Handbook of Mineralogy
  2. http://webmineral.com/data/Stephanite.shtml Webmineral data
  3. http://www.mindat.org/min-3764.html Mindat.org
  4. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine 85 (3): 291–320. doi:10.1180/mgm.2021.43. Bibcode2021MinM...85..291W. 
  5. 5.0 5.1 5.2 5.3 Spencer 1911, p. 880.


Attribution