Chemistry:Strontium azide
From HandWiki
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| Names | |
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| IUPAC name
Strontium azide
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| Other names
Strontium diazide
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| Identifiers | |
3D model (JSmol)
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| ChemSpider | |
PubChem CID
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| Properties | |
| Sr(N 3) 2 | |
| Molar mass | 171.66 g/mol |
| Hazards | |
| GHS pictograms | 
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| GHS Signal word | Danger |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
| Infobox references | |
Strontium azide is an inorganic chemical compound with the formula Sr(N
3)
2. It is composed of the strontium cation (Sr2+) and the azide anions (N−
3).[1]
Properties
Strontium azide crystallizes in an orthorhombic Fddd space group.[2] Unlike the azides of alkali metals which have a linear azide ion formation, strontium azide possesses bent azide ions, which can continue to bend further when under higher pressure.[3]
References
- ↑ Pringle, G. E.; Noakes, D. E. (18 April 1967). "The Crystal Structures of Lithium, Sodium, and Strontium Azides". Acta Crystallographica B24 (2): 262–269. doi:10.1107/S0567740868002062. Bibcode: 1968AcCrB..24..262P. https://scripts.iucr.org/cgi-bin/paper?S0567740868002062. Retrieved 29 October 2023.
- ↑ Zhu, Weihua; Xu, Xiaojuan; Xiao, Heming (8 May 2007). "Electronic structure and optical properties of crystalline strontium azide and barium azide by ab initio pseudopotential plane-wave calculations". Journal of Physics and Chemistry of Solids 68 (9): 1762–1769. doi:10.1016/j.jpcs.2007.05.001. Bibcode: 2007JPCS...68.1762Z. https://www.sciencedirect.com/science/article/pii/S0022369707002120. Retrieved 7 September 2023.
- ↑ Zhu, Hongyang; Han, Xue; Zhu, Peifen; Wu, Xiaoxin; Chen, Yanmei; Li, Miaoran; Li, Xuefeng; Cui, Qiliang (27 May 2016). "Pressure-Induced Amorphization of Strontium Azide". J. Phys. Chem. C 120 (23): 12423–12428. doi:10.1021/acs.jpcc.6b04446. https://pubs.acs.org/doi/10.1021/acs.jpcc.6b04446. Retrieved 29 October 2023.
Salts and covalent derivatives of the azide ion
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| HN3 | He | ||||||||||||||||||
| LiN3 | Be(N3)2 | B(N3)3 | CH3N3, C(N3)4 |
N(N3)3,H2N—N3 | O | FN3 | Ne | ||||||||||||
| NaN3 | Mg(N3)2 | Al(N3)3 | Si(N3)4 | P | SO2(N3)2 | ClN3 | Ar | ||||||||||||
| KN3 | Ca(N3)2 | Sc(N3)3 | Ti(N3)4 | VO(N3)3 | Cr(N3)3, CrO2(N3)2 |
Mn(N3)2 | Fe(N3)3 | Co(N3)2, Co(N3)3 |
Ni(N3)2 | CuN3, Cu(N3)2 |
Zn(N3)2 | Ga(N3)3 | Ge | As | Se(N3)4 | BrN3 | Kr | ||
| RbN3 | Sr(N3)2 | Y | Zr(N3)4 | Nb | Mo | Tc | Ru(N3)63− | Rh(N3)63− | Pd(N3)2 | AgN3 | Cd(N3)2 | In | Sn | Sb | Te | IN3 | Xe(N3)2 | ||
| CsN3 | Ba(N3)2 | Hf | Ta | W | Re | Os | Ir(N3)63− | Pt(N3)62− | Au(N3)4− | Hg2(N3)2, Hg(N3)2 |
TlN3 | Pb(N3)2 | Bi(N3)3 |
Po | At | Rn | |||
| Fr | Ra(N3)2 | Rf | Db | Sg | Bh | Hs | Mt | Ds | Rg | Cn | Nh | Fl | Mc | Lv | Ts | Og | |||
| ↓ | |||||||||||||||||||
| La | Ce(N3)3, Ce(N3)4 |
Pr | Nd | Pm | Sm | Eu | Gd(N3)3 | Tb | Dy | Ho | Er | Tm | Yb | Lu | |||||
| Ac | Th | Pa | UO2(N3)2 | Np | Pu | Am | Cm | Bk | Cf | Es | Fm | Md | No | Lr | |||||
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